An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs
Abstract
Abstract Chemically highly stable MOFs incorporating multiple functionalities are of great interest for applications under harsh environments. Herein, we presented a facile one‐pot synthetic strategy to incorporate multiple functionalities into stable Zr‐MOFs from mixed ligands of different geometry and connectivity. Via our strategy, tetratopic tetrakis(4‐carboxyphenyl)porphyrin (TCPP) ligands were successfully integrated into UiO‐66 while maintaining the crystal structure, morphology, and ultrahigh chemical stability of UiO‐66. The amount of incorporated TCPP is controllable. Through various combinations of BDC derivatives and TCPP, 49 MOFs with multiple functionalities were obtained. Among them, MOFs modified with FeTCPPCl were demonstrated to be catalytically active for the oxidation of ABTS. We anticipate our strategy to provide a facile route to introduce multiple functionalities into stable Zr‐MOFs for a wide variety of potential applications.
- Authors:
-
[1]
- Department of Chemistry Texas A&,M University College Station TX 77843 USA
- Guangxi Key Laboratory of Information Materials, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Material Science &, Engineering Guilin University of Electronic Technology Guilin Guangxi 541004 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1400753
- Grant/Contract Number:
- SC0001015
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 55 Journal Issue: 22; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Sun, Yujia, Sun, Lixian, Feng, Dawei, and Zhou, Hong‐Cai. An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs. Germany: N. p., 2016.
Web. doi:10.1002/anie.201602274.
Sun, Yujia, Sun, Lixian, Feng, Dawei, & Zhou, Hong‐Cai. An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs. Germany. https://doi.org/10.1002/anie.201602274
Sun, Yujia, Sun, Lixian, Feng, Dawei, and Zhou, Hong‐Cai. Thu .
"An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs". Germany. https://doi.org/10.1002/anie.201602274.
@article{osti_1400753,
title = {An In Situ One‐Pot Synthetic Approach towards Multivariate Zirconium MOFs},
author = {Sun, Yujia and Sun, Lixian and Feng, Dawei and Zhou, Hong‐Cai},
abstractNote = {Abstract Chemically highly stable MOFs incorporating multiple functionalities are of great interest for applications under harsh environments. Herein, we presented a facile one‐pot synthetic strategy to incorporate multiple functionalities into stable Zr‐MOFs from mixed ligands of different geometry and connectivity. Via our strategy, tetratopic tetrakis(4‐carboxyphenyl)porphyrin (TCPP) ligands were successfully integrated into UiO‐66 while maintaining the crystal structure, morphology, and ultrahigh chemical stability of UiO‐66. The amount of incorporated TCPP is controllable. Through various combinations of BDC derivatives and TCPP, 49 MOFs with multiple functionalities were obtained. Among them, MOFs modified with FeTCPPCl were demonstrated to be catalytically active for the oxidation of ABTS. We anticipate our strategy to provide a facile route to introduce multiple functionalities into stable Zr‐MOFs for a wide variety of potential applications.},
doi = {10.1002/anie.201602274},
journal = {Angewandte Chemie (International Edition)},
number = 22,
volume = 55,
place = {Germany},
year = {Thu Apr 21 00:00:00 EDT 2016},
month = {Thu Apr 21 00:00:00 EDT 2016}
}
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