Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior
Abstract
Crystalline pure NaTi 2 ( PO 4 ) 3 ( NTP ) powder was synthesized at 700°C using a simple and low energy, hybrid inorganic–organic, steric entrapment method. Sodium nitrite (Na NO 2 ) and ammonium phosphate dibasic (( NH 4 ) 2 HPO 4 ) dissolved in water, whereas titanium ( IV ) isopropoxide (Ti[ OCH ( CH 3 ) 2 ] 4 ) hydrolyzed in water. Ethylene glycol ( HOCH 2 CH 2 OH ) was used as a polymeric entrapper and hydrolysis of the Ti source was hindered by its dissolution in isopropyl alcohol. The resulting NTP powder was characterized by thermogravimetric analysis/differential thermal analysis, X‐ray diffractometry, scanning electron microscopy, specific surface area by Brunauer–Emmett–Teller nitrogen absorption, and particle size analysis. Furthermore, C, H, N were measured by the classical Pregl‐Dumas method. The thermal expansion behavior in all { hkl } pole directions was also determined by in situ high‐temperature X‐ray diffraction using synchrotron radiation and was found to be in agreement with other published studies.
- Authors:
-
- Department of Materials Science and Engineering University of Illinois at Urbana‐Champaign 1304 W. Green St Urbana Illinois
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1400576
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Name: Journal of the American Ceramic Society Journal Volume: 99 Journal Issue: 11; Journal ID: ISSN 0002-7820
- Publisher:
- Wiley-Blackwell
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ribero, Daniel, Seymour, Kevin C., Kriven, Waltraud M., and White, ed., M. A. Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior. United States: N. p., 2016.
Web. doi:10.1111/jace.14420.
Ribero, Daniel, Seymour, Kevin C., Kriven, Waltraud M., & White, ed., M. A. Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior. United States. https://doi.org/10.1111/jace.14420
Ribero, Daniel, Seymour, Kevin C., Kriven, Waltraud M., and White, ed., M. A. Tue .
"Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior". United States. https://doi.org/10.1111/jace.14420.
@article{osti_1400576,
title = {Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior},
author = {Ribero, Daniel and Seymour, Kevin C. and Kriven, Waltraud M. and White, ed., M. A.},
abstractNote = {Crystalline pure NaTi 2 ( PO 4 ) 3 ( NTP ) powder was synthesized at 700°C using a simple and low energy, hybrid inorganic–organic, steric entrapment method. Sodium nitrite (Na NO 2 ) and ammonium phosphate dibasic (( NH 4 ) 2 HPO 4 ) dissolved in water, whereas titanium ( IV ) isopropoxide (Ti[ OCH ( CH 3 ) 2 ] 4 ) hydrolyzed in water. Ethylene glycol ( HOCH 2 CH 2 OH ) was used as a polymeric entrapper and hydrolysis of the Ti source was hindered by its dissolution in isopropyl alcohol. The resulting NTP powder was characterized by thermogravimetric analysis/differential thermal analysis, X‐ray diffractometry, scanning electron microscopy, specific surface area by Brunauer–Emmett–Teller nitrogen absorption, and particle size analysis. Furthermore, C, H, N were measured by the classical Pregl‐Dumas method. The thermal expansion behavior in all { hkl } pole directions was also determined by in situ high‐temperature X‐ray diffraction using synchrotron radiation and was found to be in agreement with other published studies.},
doi = {10.1111/jace.14420},
journal = {Journal of the American Ceramic Society},
number = 11,
volume = 99,
place = {United States},
year = {Tue Aug 02 00:00:00 EDT 2016},
month = {Tue Aug 02 00:00:00 EDT 2016}
}
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