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Title: Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry

Abstract

ABSTRACT Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO 2 /N 2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53 , 1548–1557

Authors:
 [1];  [1];  [2];  [3];  [1];  [1];  [1];  [1];  [3];  [2];  [2];  [1];  [4]
+ Show Author Affiliations
  1. U.S. Department of Energy, National Energy Technology Laboratory 626 Cochrans Mill Rd. Pittsburgh Pennsylvania 15236
  2. Institute for Complex Engineered Systems Carnegie Mellon University 4400 Fifth Avenue Pittsburgh Pennsylvania 15213
  3. Department of Chemical Engineering Carnegie Mellon University 5000 Forbes Avenue Pittsburgh Pennsylvania 15213
  4. U.S. Department of Energy, National Energy Technology Laboratory 626 Cochrans Mill Rd. Pittsburgh Pennsylvania 15236, Department of Chemistry Carnegie Mellon University 4400 Fifth Avenue Pittsburgh Pennsylvania 15213
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1400510
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part A, Polymer Chemistry
Additional Journal Information:
Journal Name: Journal of Polymer Science. Part A, Polymer Chemistry Journal Volume: 53 Journal Issue: 13; Journal ID: ISSN 0887-624X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Kusuma, Victor A., Roth, Elliot A., Clafshenkel, William P., Klara, Steven S., Zhou, Xu, Venna, Surendar R., Albenze, Erik, Luebke, David R., Mauter, Meagan S., Koepsel, Richard R., Russell, Alan J., Hopkinson, David, and Nulwala, Hunaid B. Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry. United States: N. p., 2015. Web. doi:10.1002/pola.27594.
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Kusuma, Victor A., Roth, Elliot A., Clafshenkel, William P., Klara, Steven S., Zhou, Xu, Venna, Surendar R., Albenze, Erik, Luebke, David R., Mauter, Meagan S., Koepsel, Richard R., Russell, Alan J., Hopkinson, David, & Nulwala, Hunaid B. Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry. United States. https://doi.org/10.1002/pola.27594
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Kusuma, Victor A., Roth, Elliot A., Clafshenkel, William P., Klara, Steven S., Zhou, Xu, Venna, Surendar R., Albenze, Erik, Luebke, David R., Mauter, Meagan S., Koepsel, Richard R., Russell, Alan J., Hopkinson, David, and Nulwala, Hunaid B. Mon . "Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry". United States. https://doi.org/10.1002/pola.27594.
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@article{osti_1400510,
title = {Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry},
author = {Kusuma, Victor A. and Roth, Elliot A. and Clafshenkel, William P. and Klara, Steven S. and Zhou, Xu and Venna, Surendar R. and Albenze, Erik and Luebke, David R. and Mauter, Meagan S. and Koepsel, Richard R. and Russell, Alan J. and Hopkinson, David and Nulwala, Hunaid B.},
abstractNote = {ABSTRACT Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO 2 /N 2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53 , 1548–1557},
doi = {10.1002/pola.27594},
journal = {Journal of Polymer Science. Part A, Polymer Chemistry},
number = 13,
volume = 53,
place = {United States},
year = {Mon Mar 16 00:00:00 EDT 2015},
month = {Mon Mar 16 00:00:00 EDT 2015}
}
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https://doi.org/10.1002/pola.27594
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