Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants
Abstract
Abstract The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. Here, we present a strategy that enables the fine‐tuning of a specific combination of properties by controlling the reduction of dopants. The feasibility of this approach was demonstrated by optimizing the near‐IR photoluminescence of strontium titanate SrTiO 3 :Ni for potential applications in biomedicine for a range of absorbance in the visible/near‐IR region. We discussed how material properties, such as luminescence, conductivity, or photocatalytic properties can be designed by carefully controlling the ratio of dopants in different oxidation states.
- Authors:
-
- Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
- North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1543479
- Alternate Identifier(s):
- OSTI ID: 1400466
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 23; Journal Issue: 13; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; chemistry; biomedicine; dopants; luminescence; multifunctional materials; visible/near-IR absorption
Citation Formats
Barroux, Hugo, Jiang, Tengfei, Paul, Camille, Massuyeau, Florian, Génois, Romain, Gordon, Elijah E., Whangbo, Myung-Hwan, Jobic, Stéphane, and Gautier, Romain. Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants. United States: N. p., 2017.
Web. doi:10.1002/chem.201605707.
Barroux, Hugo, Jiang, Tengfei, Paul, Camille, Massuyeau, Florian, Génois, Romain, Gordon, Elijah E., Whangbo, Myung-Hwan, Jobic, Stéphane, & Gautier, Romain. Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants. United States. https://doi.org/10.1002/chem.201605707
Barroux, Hugo, Jiang, Tengfei, Paul, Camille, Massuyeau, Florian, Génois, Romain, Gordon, Elijah E., Whangbo, Myung-Hwan, Jobic, Stéphane, and Gautier, Romain. Thu .
"Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants". United States. https://doi.org/10.1002/chem.201605707. https://www.osti.gov/servlets/purl/1543479.
@article{osti_1543479,
title = {Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants},
author = {Barroux, Hugo and Jiang, Tengfei and Paul, Camille and Massuyeau, Florian and Génois, Romain and Gordon, Elijah E. and Whangbo, Myung-Hwan and Jobic, Stéphane and Gautier, Romain},
abstractNote = {Abstract The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. Here, we present a strategy that enables the fine‐tuning of a specific combination of properties by controlling the reduction of dopants. The feasibility of this approach was demonstrated by optimizing the near‐IR photoluminescence of strontium titanate SrTiO 3 :Ni for potential applications in biomedicine for a range of absorbance in the visible/near‐IR region. We discussed how material properties, such as luminescence, conductivity, or photocatalytic properties can be designed by carefully controlling the ratio of dopants in different oxidation states.},
doi = {10.1002/chem.201605707},
journal = {Chemistry - A European Journal},
number = 13,
volume = 23,
place = {United States},
year = {Thu Jan 26 00:00:00 EST 2017},
month = {Thu Jan 26 00:00:00 EST 2017}
}
Web of Science
Figures / Tables:
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