Magnetism out of antisite disorder in the J=0 compound Ba2YIrO6

Chen, Qiang; Svoboda, Chris; Zheng, Qiang; Sales, Brian C.; Mandrus, David G.; Zhou, H. D.; Zhou, J. -S.; McComb, David W.; Randeria, Mohit; Trivedi, Nandini; Yan, J. -Q.

doi:10.1103/PhysRevB.96.144423

Title: Magnetism out of antisite disorder in the $J = 0$ compound ${Ba}_{2} {YIrO}_{6}$

Abstract

Here, we systematically investigate the magnetic properties and local structure of Ba₂YIrO₆ to demonstrate that Y and Ir lattice defects in the form of antiphase boundary or clusters of antisite disorder affect the magnetism observed in this 5d⁴ compound. The experimental investigation involved comparison of the magnetic properties and atomic imaging of (1) a slow-cooled crystal, (2) a crystal quenched from 900°C after growth, and (3) a crystal grown using a faster cooling rate during growth than the slow-cooled one. Atomic-scale imaging by scanning transmission electron microscopy (STEM) shows that quenching from 900°C introduces Ir-rich antiphase boundaries in the crystals, and a faster cooling rate during crystal growth leads to clusters of Y and Ir antisite disorder. Compared to the slow-cooled crystals, Ba₂YIrO₆ crystals with clusters of antisite defects have a larger effective moment and a larger saturation moment, while quenched crystals with Ir-rich antiphase boundary show a slightly suppressed moment. Our DFT and model magnetic Hamiltonian calculations suggest magnetic condensation is unlikely, as the energy to be gained from superexchange is small compared to the spin-orbit gap. However, once Y is replaced by Ir in the antisite disordered region, the picture of local nonmagnetic singlets breaks down and magnetismmore »« less

Authors:

Chen, Qiang ^[1]; Svoboda, Chris ^[2];

^[3];

^[3]; Mandrus, David G. ^[4]; Zhou, H. D. ^[1]; Zhou, J. -S. ^[5]; McComb, David W. ^[2]; Randeria, Mohit ^[2]; Trivedi, Nandini ^[2];

^[3]

Univ. of Tennessee, Knoxville, TN (United States)
The Ohio State Univ., Columbus, OH (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Texas at Austin, Austin, TX (United States)

Publication Date:: 2017-10-18

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1399964

Alternate Identifier(s):: OSTI ID: 1400010

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 96; Journal Issue: 14; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Chen, Qiang, Svoboda, Chris, Zheng, Qiang, Sales, Brian C., Mandrus, David G., Zhou, H. D., Zhou, J. -S., McComb, David W., Randeria, Mohit, Trivedi, Nandini, and Yan, J. -Q. Magnetism out of antisite disorder in the J=0 compound Ba2YIrO6.  United States: N. p., 2017. 
Web.  doi:10.1103/PhysRevB.96.144423.

Copy to clipboard


                    Chen, Qiang, Svoboda, Chris, Zheng, Qiang, Sales, Brian C., Mandrus, David G., Zhou, H. D., Zhou, J. -S., McComb, David W., Randeria, Mohit, Trivedi, Nandini, & Yan, J. -Q. Magnetism out of antisite disorder in the J=0 compound Ba2YIrO6.  United States.  https://doi.org/10.1103/PhysRevB.96.144423

Copy to clipboard


                    Chen, Qiang, Svoboda, Chris, Zheng, Qiang, Sales, Brian C., Mandrus, David G., Zhou, H. D., Zhou, J. -S., McComb, David W., Randeria, Mohit, Trivedi, Nandini, and Yan, J. -Q. Wed .  
"Magnetism out of antisite disorder in the J=0 compound Ba2YIrO6".  United States.  https://doi.org/10.1103/PhysRevB.96.144423.  https://www.osti.gov/servlets/purl/1399964.

Copy to clipboard


                    
@article{osti_1399964,

  title        = {Magnetism out of antisite disorder in the J=0 compound Ba2YIrO6},

  author       = {Chen, Qiang and Svoboda, Chris and Zheng, Qiang and Sales, Brian C. and Mandrus, David G. and Zhou, H. D. and Zhou, J. -S. and McComb, David W. and Randeria, Mohit and Trivedi, Nandini and Yan, J. -Q.},

  abstractNote = {Here, we systematically investigate the magnetic properties and local structure of Ba2YIrO6 to demonstrate that Y and Ir lattice defects in the form of antiphase boundary or clusters of antisite disorder affect the magnetism observed in this 5d4 compound. The experimental investigation involved comparison of the magnetic properties and atomic imaging of (1) a slow-cooled crystal, (2) a crystal quenched from 900°C after growth, and (3) a crystal grown using a faster cooling rate during growth than the slow-cooled one. Atomic-scale imaging by scanning transmission electron microscopy (STEM) shows that quenching from 900°C introduces Ir-rich antiphase boundaries in the crystals, and a faster cooling rate during crystal growth leads to clusters of Y and Ir antisite disorder. Compared to the slow-cooled crystals, Ba2YIrO6 crystals with clusters of antisite defects have a larger effective moment and a larger saturation moment, while quenched crystals with Ir-rich antiphase boundary show a slightly suppressed moment. Our DFT and model magnetic Hamiltonian calculations suggest magnetic condensation is unlikely, as the energy to be gained from superexchange is small compared to the spin-orbit gap. However, once Y is replaced by Ir in the antisite disordered region, the picture of local nonmagnetic singlets breaks down and magnetism can be induced. This is because of (a) enhanced interactions due to increased orbital overlap and (b) increased number of orbitals mediating the interactions. Our work highlights the importance of lattice defects in understanding the experimentally observed magnetism in Ba2YIrO6 and other J = 0 systems.},

  doi          = {10.1103/PhysRevB.96.144423},

  journal      = {Physical Review B},

  number       = 14,

  volume       = 96,

  place        = {United States},

  year         = {2017},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.96.144423

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds
journal, June 2015

Laguna-Marco, M. A.; Kayser, P.; Alonso, J. A.
Physical Review B, Vol. 91, Issue 21
DOI: 10.1103/PhysRevB.91.214433

Magnetic and Transport Properties of the System La_1-xSr_xCoO_3-δ (0 < x ≤ 0.50)
journal, September 1995

Senarı́s-Rodrıiguez, M.; Goodenough, J.
Journal of Solid State Chemistry, Vol. 118, Issue 2, p. 323-336
DOI: 10.1006/jssc.1995.1351

Influence of structural distortions on the Ir magnetism in Ba2−xSrxYIrO6 double perovskites
journal, June 2016

Phelan, Brendan F.; Seibel, Elizabeth M.; Badoe, Daniel
Solid State Communications, Vol. 236
DOI: 10.1016/j.ssc.2016.03.017

Cascade of Magnetic Field Induced Spin Transitions in ${LaCoO}_{3}$
journal, July 2012

Altarawneh, M. M.; Chern, G. -W.; Harrison, N.
Physical Review Letters, Vol. 109, Issue 3
DOI: 10.1103/PhysRevLett.109.037201

On the possibility of excitonic magnetism in Ir double perovskites
journal, January 2016

Pajskr, K.; Novák, P.; Pokorný, V.
Physical Review B, Vol. 93, Issue 3
DOI: 10.1103/PhysRevB.93.035129

An updated version of wannier90: A tool for obtaining maximally-localised Wannier functions
journal, August 2014

Mostofi, Arash A.; Yates, Jonathan R.; Pizzi, Giovanni
Computer Physics Communications, Vol. 185, Issue 8
DOI: 10.1016/j.cpc.2014.05.003

Diluted paramagnetic impurities in nonmagnetic ${Ba}_{2} {YIrO}_{6}$
journal, October 2017

Hammerath, F.; Sarkar, R.; Kamusella, S.
Physical Review B, Vol. 96, Issue 16
DOI: 10.1103/PhysRevB.96.165108

Novel Magnetism of ${Ir}^{5 +} (5 d^{4})$ Ions in the Double Perovskite ${Sr}_{2} {YIrO}_{6}$
journal, February 2014

Cao, G.; Qi, T. F.; Li, L.
Physical Review Letters, Vol. 112, Issue 5
DOI: 10.1103/PhysRevLett.112.056402

601. The magnetic properties of some d 4-complexes
journal, January 1961

Earnshaw, A.; Figgis, B. N.; Lewis, J.
Journal of the Chemical Society (Resumed)
DOI: 10.1039/jr9610003132

Lattice-tuned magnetism of ${Ru}^{4 +} (4 d^{4})$ ions in single crystals of the layered honeycomb ruthenates ${Li}_{2} {RuO}_{3}$ and ${Na}_{2} {RuO}_{3}$
journal, October 2014

Wang, J. C.; Terzic, J.; Qi, T. F.
Physical Review B, Vol. 90, Issue 16
DOI: 10.1103/PhysRevB.90.161110

Observation of magnetic excitons in LaCoO ₃
journal, June 2005

Giblin, S. R.; Terry, I.; Clark, S. J.
Europhysics Letters (EPL), Vol. 70, Issue 5
DOI: 10.1209/epl/i2004-10519-4

Novel magnetic state in $d^{4}$ Mott insulators
journal, February 2015

Meetei, O. Nganba; Cole, William S.; Randeria, Mohit
Physical Review B, Vol. 91, Issue 5
DOI: 10.1103/PhysRevB.91.054412

Structural and Magnetic Properties of the Iridium Double Perovskites Ba _{2– x} Sr _x YIrO ₆
journal, October 2015

Ranjbar, Ben; Reynolds, Emily; Kayser, Paula
Inorganic Chemistry, Vol. 54, Issue 21
DOI: 10.1021/acs.inorgchem.5b01905

Low temperature Schottky anomalies in the specific heat of LaCoO3: Defect-stabilized finite spin states
journal, March 2009

He, C.; Zheng, H.; Mitchell, J. F.
Applied Physics Letters, Vol. 94, Issue 10
DOI: 10.1063/1.3098374

Evidence for a low-temperature magnetic ground state in double-perovskite iridates with $I r^{5 +} (5 d^{4})$ ions
journal, August 2017

Terzic, J.; Zheng, H.; Ye, Feng
Physical Review B, Vol. 96, Issue 6
DOI: 10.1103/PhysRevB.96.064436

Excitonic magnetism in $d^{6}$ perovskites
journal, March 2017

Afonso, J. Fernández; Kuneš, J.
Physical Review B, Vol. 95, Issue 11
DOI: 10.1103/PhysRevB.95.115131

Excitonic Magnetism in Van Vleck–type $d^{4}$ Mott Insulators
journal, November 2013

Khaliullin, Giniyat
Physical Review Letters, Vol. 111, Issue 19
DOI: 10.1103/PhysRevLett.111.197201

Bond-length fluctuations and the spin-state transition in $L {CoO}_{3}$ $(L = La,$ Pr, and Nd)
journal, April 2004

Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B.
Physical Review B, Vol. 69, Issue 13
DOI: 10.1103/PhysRevB.69.134409

Insights into cationic ordering in Re-based double perovskite oxides
journal, January 2016

Lim, Tae-Won; Kim, Sung-Dae; Sung, Kil-Dong
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep19746

Cationic ordering control of magnetization in Sr2FeMoO6 double perovskite
journal, February 2001

Balcells, Ll.; Navarro, J.; Bibes, M.
Applied Physics Letters, Vol. 78, Issue 6
DOI: 10.1063/1.1346624

${Ba}_{2} {YIrO}_{6}$ : A cubic double perovskite material with ${Ir}^{5 +}$ ions
journal, January 2016

Dey, T.; Maljuk, A.; Efremov, D. V.
Physical Review B, Vol. 93, Issue 1
DOI: 10.1103/PhysRevB.93.014434

Breakdown of $J = 0$ nonmagnetic state in $d^{4}$ iridate double perovskites: A first-principles study
journal, September 2015

Bhowal, Sayantika; Baidya, Santu; Dasgupta, Indra
Physical Review B, Vol. 92, Issue 12
DOI: 10.1103/PhysRevB.92.121113

Electronic structure and spin-orbit driven magnetism in $d^{4.5}$ insulator ${Ba}_{3} {YIr}_{2} O_{9}$
journal, November 2015

Panda, S. K.; Bhowal, S.; Li, Ying
Physical Review B, Vol. 92, Issue 18
DOI: 10.1103/PhysRevB.92.180403

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling
journal, October 2016

Cui, Q.; Cheng, J. -G.; Fan, W.
Physical Review Letters, Vol. 117, Issue 17
DOI: 10.1103/PhysRevLett.117.176603

Possible spin-orbit driven spin-liquid ground state in the double perovskite phase of Ba $_{3}$ YIr $_{2}$ O $_{9}$
journal, October 2013

Dey, Tusharkanti; Mahajan, A. V.; Kumar, R.
Physical Review B, Vol. 88, Issue 13
DOI: 10.1103/PhysRevB.88.134425

An electron microscope for the aberration-corrected era
journal, February 2008

Krivanek, O. L.; Corbin, G. J.; Dellby, N.
Ultramicroscopy, Vol. 108, Issue 3
DOI: 10.1016/j.ultramic.2007.07.010

Ferromagnetism in $La Co O_{3}$
journal, July 2004

Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B.
Physical Review B, Vol. 70, Issue 1
DOI: 10.1103/PhysRevB.70.014402

Ferromagnetic order in epitaxially strained $La Co O_{3}$ thin films
journal, April 2007

Fuchs, D.; Pinta, C.; Schwarz, T.
Physical Review B, Vol. 75, Issue 14
DOI: 10.1103/PhysRevB.75.144402

Quantitative STEM Imaging of Order-Disorder Phenomena in Double Perovskite Thin Films
journal, October 2016

Esser, B. D.; Hauser, A. J.; Williams, R. E. A.
Physical Review Letters, Vol. 117, Issue 17
DOI: 10.1103/PhysRevLett.117.176101

Ferromagnetism in $La Co O_{3}$ nanoparticles
journal, November 2007

Zhou, Shiming; Shi, Lei; Zhao, Jiyin
Physical Review B, Vol. 76, Issue 17
DOI: 10.1103/PhysRevB.76.172407

Spin state ordering of strongly correlating ${LaCoO}_{3}$ induced at ultrahigh magnetic fields
journal, June 2016

Ikeda, Akihiko; Nomura, Toshihiro; Matsuda, Yasuhiro H.
Physical Review B, Vol. 93, Issue 22
DOI: 10.1103/PhysRevB.93.220401

Fragile singlet ground-state magnetism in the pyrochlore osmates $R_{2} {Os}_{2} O_{7}$ ( $R = Y$ and Ho)
journal, April 2016

Zhao, Z. Y.; Calder, S.; Aczel, A. A.
Physical Review B, Vol. 93, Issue 13
DOI: 10.1103/PhysRevB.93.134426

Ferromagnetism at the surface of a $La Co O_{3}$ single crystal observed using scanning SQUID microscopy
journal, May 2007

Harada, A.; Taniyama, T.; Takeuchi, Y.
Physical Review B, Vol. 75, Issue 18
DOI: 10.1103/PhysRevB.75.184426

Iridium double perovskite ${Sr}_{2} {YIrO}_{6}$ : A combined structural and specific heat study
journal, February 2017

Corredor, L. T.; Aslan-Cansever, G.; Sturza, M.
Physical Review B, Vol. 95, Issue 6
DOI: 10.1103/PhysRevB.95.064418

Strain-Induced Ferromagnetism and Magnetoresistance in Epitaxial Thin Films of LaCoO ₃ Prepared by Polymer-Assisted Deposition
journal, December 2012

Rivadulla, Francisco; Bi, Zhenxing; Bauer, Eve
Chemistry of Materials, Vol. 25, Issue 1
DOI: 10.1021/cm3031472

Excitonic magnetism in $d^6$ perovskites
text, January 2016

Afonso, J. Fernandez; Kunes, J.
arXiv
DOI: 10.48550/arxiv.1612.07576

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling
text, January 2017

Cui, Q.; Cheng, J. -G.; Fan, W.
arXiv
DOI: 10.48550/arxiv.1710.00304

Works referencing / citing this record:

On J _eff =0 Ground State Iridates(V): Tracking Residual Paramagnetism in New Bi ₂ NaIrO ₆
journal, October 2018

Prasad, Beluvalli E.; Doert, Thomas; Felser, Claudia
Chemistry - A European Journal, Vol. 24, Issue 63
DOI: 10.1002/chem.201804226

Structural and magnetic studies of KOsO ₄ , a 5d ¹ quantum magnet oxide
journal, January 2019

Injac, Sean; Yuen, Alexander K. L.; Avdeev, Maxim
Physical Chemistry Chemical Physics, Vol. 21, Issue 14
DOI: 10.1039/c9cp00448c

Spin-orbit coupled systems in the "atomic" limit: rhenates, osmates, iridates
text, January 2018

Paramekanti, Arun; Singh, David J.; Yuan, Bo
arXiv
DOI: 10.48550/arxiv.1804.02006

Octupolar order in d-orbital Mott insulators
text, January 2019

Paramekanti, Arun; Maharaj, Dalini D.; Gaulin, Bruce D.
arXiv
DOI: 10.48550/arxiv.1909.03089

Similar Records in DOE PAGES and OSTI.GOV collections:

Magnetism of ${Ir}^{5 +}$ -based double perovskites: Unraveling its nature and the influence of structure

Journal Article Laguna-Marco, M. A. ; Arias-Egido, E. ; Piquer, C. ; ... - Physical Review B

A combination of x-ray-diffraction, x-ray absorption, x-ray magnetic circular dichroism, macroscopic magnetization, and muon-spin relaxation measurements is used to investigate the interplay between structure (both crystallography and microstructure) and magnetism in Sr₂ YIrO₆ as a function of both chemical (Ca-doping) and physical (hydrostatic) pressure. X-ray absorption spectroscopy clearly shows that the physical pressure is more effective in modifying the structure. On the other hand, the dichroic measurements evidence a constant magnetic signal with physical pressure and strong differences with Ca-doping. Muon-spin relaxation reveals the presence of magnetic order, even when this is hidden in the magnetization data. From the combinedmore »« less
Cited by 7
https://doi.org/10.1103/PhysRevB.101.014449

Full Text Available
Evidence for a low-temperature magnetic ground state in double-perovskite iridates with $I r^{5 +} (5 d^{4})$ ions

Journal Article Terzic, Jasminka ; Zheng, Hao ; Ye, Feng ; ... - Physical Review B

Here, we report an unusual magnetic ground state in single-crystal, double-perovskite Ba₂YIrO₆ and Sr-doped Ba₂YIrO₆ with Ir⁵⁺ (5d⁴) ions. Long-range magnetic order below 1.7 K is confirmed by dc magnetization, ac magnetic susceptibility, and heat-capacity measurements. The observed magnetic order is extraordinarily delicate and cannot be explained in terms of either a low-spin S=1 state, or a singlet J_eff=0 state imposed by the spin-orbit interactions (SOI). Alternatively, the magnetic ground state appears consistent with a SOI that competes with comparable Hund's rule coupling and inherently large electron hopping, which cannot stabilize the singlet J_eff=0 ground state. However, this picture ismore »« less
Cited by 40
https://doi.org/10.1103/PhysRevB.96.064436

Full Text Available
Frustrated spin- $\frac{1}{2}$ molecular magnetism in the mixed-valence antiferromagnets ${Ba}_{3} M {Ru}_{2} O_{9} (M = In$ , Y, Lu)

Journal Article Ziat, D. ; Aczel, Adam A. ; Sinclair, R. ; ... - Physical Review B

We have performed magnetic susceptibility, heat capacity, muon spin relaxation, and neutron-scattering measurements on three members of the family Ba₃MRu₂O₉, where M=In, Y, and Lu. These systems consist of mixed-valence Ru dimers on a triangular lattice with antiferromagnetic interdimer exchange. Although previous work has argued that charge order within the dimers or intradimer double exchange plays an important role in determining the magnetic properties, our results suggest that the dimers are better described as molecular units due to significant orbital hybridization, resulting in one spin-1/2 moment distributed equally over the two Ru sites. These molecular building blocks form a frustrated,more »« less
Cited by 24
https://doi.org/10.1103/PhysRevB.95.184424

Full Text Available
Single-ion properties of the $S_{eff}$ = $\frac{1}{2}$ XY antiferromagnetic pyrochlores $Na A^{'} {Co}_{2} F_{7}$ ( $A^{'} = {Ca}^{2 +}, {Sr}^{2 +}$ )

Journal Article Ross, Kathryn A. ; Brown, J. M. ; Cava, R. J. ; ... - Physical Review B

The antiferromagnetic pyrochlore material NaCaCo₂F₇ is a thermal spin liquid over a broad temperature range (≈140 K down to T_F=2.4 K), in which magnetic correlations between Co²⁺ dipole moments explore a continuous manifold of antiferromagnetic XY states. The thermal spin liquid is interrupted by spin freezing at a temperature that is ~2% of the mean-field interaction strength, leading to short-range static XY clusters with distinctive relaxation dynamics. Here we report the low-energy inelastic neutron scattering response from the related compound NaSrCo₂F₇, confirming that it hosts the same static and dynamic spin correlations as NaCaCo₂F₇. We then present the single-ion levelsmore »« less
Cited by 37
https://doi.org/10.1103/PhysRevB.95.144414

Full Text Available
Physical properties and thermal stability of ${Fe}_{5 - x} {GeTe}_{2}$ single crystals

Journal Article May, Andrew F. ; Bridges, Craig A. ; McGuire, Michael A. - Physical Review Materials

The magnetic and transport properties of Fe-deficient Fe₅GeTe₂ single crystals (Fe_5-xGeTe₂ with x≈0.3) were studied and the impact of thermal processing was explored in this work. Quenching crystals from the growth temperature has been previously shown to produce a metastable state that undergoes a strongly hysteretic first-order transition upon cooling below ≈100 K. The first-order transition impacts the magnetic properties, yielding an enhancement in the Curie temperaturemore »« less
Cited by 49
https://doi.org/10.1103/PhysRevMaterials.3.104401

Full Text Available

Similar Records

Title: Magnetism out of antisite disorder in the J = 0 compound Ba 2 YIrO 6

Abstract

Citation Formats

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds journal, June 2015

Magnetic and Transport Properties of the System La1-xSrxCoO3-δ (0 < x ≤ 0.50) journal, September 1995

Influence of structural distortions on the Ir magnetism in Ba2−xSrxYIrO6 double perovskites journal, June 2016

Cascade of Magnetic Field Induced Spin Transitions in LaCoO 3 journal, July 2012

On the possibility of excitonic magnetism in Ir double perovskites journal, January 2016

An updated version of wannier90: A tool for obtaining maximally-localised Wannier functions journal, August 2014

Diluted paramagnetic impurities in nonmagnetic Ba 2 YIrO 6 journal, October 2017

Novel Magnetism of Ir 5 + ( 5 d 4 ) Ions in the Double Perovskite Sr 2 YIrO 6 journal, February 2014

601. The magnetic properties of some d 4-complexes journal, January 1961

Lattice-tuned magnetism of Ru 4 + ( 4 d 4 ) ions in single crystals of the layered honeycomb ruthenates Li 2 RuO 3 and Na 2 RuO 3 journal, October 2014

Observation of magnetic excitons in LaCoO 3 journal, June 2005

Novel magnetic state in d 4 Mott insulators journal, February 2015

Structural and Magnetic Properties of the Iridium Double Perovskites Ba 2– x Sr x YIrO 6 journal, October 2015

Low temperature Schottky anomalies in the specific heat of LaCoO3: Defect-stabilized finite spin states journal, March 2009

Evidence for a low-temperature magnetic ground state in double-perovskite iridates with I r 5 + ( 5 d 4 ) ions journal, August 2017

Excitonic magnetism in d 6 perovskites journal, March 2017

Excitonic Magnetism in Van Vleck–type d 4 Mott Insulators journal, November 2013

Bond-length fluctuations and the spin-state transition in L CoO 3 ( L = La , Pr, and Nd) journal, April 2004

Insights into cationic ordering in Re-based double perovskite oxides journal, January 2016

Cationic ordering control of magnetization in Sr2FeMoO6 double perovskite journal, February 2001

Ba 2 YIrO 6 : A cubic double perovskite material with Ir 5 + ions journal, January 2016

Breakdown of J = 0 nonmagnetic state in d 4 iridate double perovskites: A first-principles study journal, September 2015

Electronic structure and spin-orbit driven magnetism in d 4.5 insulator Ba 3 YIr 2 O 9 journal, November 2015

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling journal, October 2016

Possible spin-orbit driven spin-liquid ground state in the double perovskite phase of Ba 3 YIr 2 O 9 journal, October 2013

An electron microscope for the aberration-corrected era journal, February 2008

Ferromagnetism in La Co O 3 journal, July 2004

Ferromagnetic order in epitaxially strained La Co O 3 thin films journal, April 2007

Quantitative STEM Imaging of Order-Disorder Phenomena in Double Perovskite Thin Films journal, October 2016

Ferromagnetism in La Co O 3 nanoparticles journal, November 2007

Spin state ordering of strongly correlating LaCoO 3 induced at ultrahigh magnetic fields journal, June 2016

Fragile singlet ground-state magnetism in the pyrochlore osmates R 2 Os 2 O 7 ( R = Y and Ho) journal, April 2016

Ferromagnetism at the surface of a La Co O 3 single crystal observed using scanning SQUID microscopy journal, May 2007

Iridium double perovskite Sr 2 YIrO 6 : A combined structural and specific heat study journal, February 2017

Strain-Induced Ferromagnetism and Magnetoresistance in Epitaxial Thin Films of LaCoO 3 Prepared by Polymer-Assisted Deposition journal, December 2012

Excitonic magnetism in $d^6$ perovskites text, January 2016

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling text, January 2017

On J eff =0 Ground State Iridates(V): Tracking Residual Paramagnetism in New Bi 2 NaIrO 6 journal, October 2018

Structural and magnetic studies of KOsO 4 , a 5d 1 quantum magnet oxide journal, January 2019

Spin-orbit coupled systems in the "atomic" limit: rhenates, osmates, iridates text, January 2018

Octupolar order in d-orbital Mott insulators text, January 2019

Title: Magnetism out of antisite disorder in the $J = 0$ compound ${Ba}_{2} {YIrO}_{6}$

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds
journal, June 2015

Magnetic and Transport Properties of the System La_1-xSr_xCoO_3-δ (0 < x ≤ 0.50)
journal, September 1995

Influence of structural distortions on the Ir magnetism in Ba2−xSrxYIrO6 double perovskites
journal, June 2016

Cascade of Magnetic Field Induced Spin Transitions in ${LaCoO}_{3}$
journal, July 2012

On the possibility of excitonic magnetism in Ir double perovskites
journal, January 2016

An updated version of wannier90: A tool for obtaining maximally-localised Wannier functions
journal, August 2014

Diluted paramagnetic impurities in nonmagnetic ${Ba}_{2} {YIrO}_{6}$
journal, October 2017

Novel Magnetism of ${Ir}^{5 +} (5 d^{4})$ Ions in the Double Perovskite ${Sr}_{2} {YIrO}_{6}$
journal, February 2014

601. The magnetic properties of some d 4-complexes
journal, January 1961

Lattice-tuned magnetism of ${Ru}^{4 +} (4 d^{4})$ ions in single crystals of the layered honeycomb ruthenates ${Li}_{2} {RuO}_{3}$ and ${Na}_{2} {RuO}_{3}$
journal, October 2014

Observation of magnetic excitons in LaCoO ₃
journal, June 2005

Novel magnetic state in $d^{4}$ Mott insulators
journal, February 2015

Structural and Magnetic Properties of the Iridium Double Perovskites Ba _{2– x} Sr _x YIrO ₆
journal, October 2015

Low temperature Schottky anomalies in the specific heat of LaCoO3: Defect-stabilized finite spin states
journal, March 2009

Evidence for a low-temperature magnetic ground state in double-perovskite iridates with $I r^{5 +} (5 d^{4})$ ions
journal, August 2017

Excitonic magnetism in $d^{6}$ perovskites
journal, March 2017

Excitonic Magnetism in Van Vleck–type $d^{4}$ Mott Insulators
journal, November 2013

Bond-length fluctuations and the spin-state transition in $L {CoO}_{3}$ $(L = La,$ Pr, and Nd)
journal, April 2004

Insights into cationic ordering in Re-based double perovskite oxides
journal, January 2016

Cationic ordering control of magnetization in Sr2FeMoO6 double perovskite
journal, February 2001

${Ba}_{2} {YIrO}_{6}$ : A cubic double perovskite material with ${Ir}^{5 +}$ ions
journal, January 2016

Breakdown of $J = 0$ nonmagnetic state in $d^{4}$ iridate double perovskites: A first-principles study
journal, September 2015

Electronic structure and spin-orbit driven magnetism in $d^{4.5}$ insulator ${Ba}_{3} {YIr}_{2} O_{9}$
journal, November 2015

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling
journal, October 2016

Possible spin-orbit driven spin-liquid ground state in the double perovskite phase of Ba $_{3}$ YIr $_{2}$ O $_{9}$
journal, October 2013

An electron microscope for the aberration-corrected era
journal, February 2008

Ferromagnetism in $La Co O_{3}$
journal, July 2004

Ferromagnetic order in epitaxially strained $La Co O_{3}$ thin films
journal, April 2007

Quantitative STEM Imaging of Order-Disorder Phenomena in Double Perovskite Thin Films
journal, October 2016

Ferromagnetism in $La Co O_{3}$ nanoparticles
journal, November 2007

Spin state ordering of strongly correlating ${LaCoO}_{3}$ induced at ultrahigh magnetic fields
journal, June 2016

Fragile singlet ground-state magnetism in the pyrochlore osmates $R_{2} {Os}_{2} O_{7}$ ( $R = Y$ and Ho)
journal, April 2016

Ferromagnetism at the surface of a $La Co O_{3}$ single crystal observed using scanning SQUID microscopy
journal, May 2007

Iridium double perovskite ${Sr}_{2} {YIrO}_{6}$ : A combined structural and specific heat study
journal, February 2017

Strain-Induced Ferromagnetism and Magnetoresistance in Epitaxial Thin Films of LaCoO ₃ Prepared by Polymer-Assisted Deposition
journal, December 2012

Excitonic magnetism in $d^6$ perovskites
text, January 2016

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling
text, January 2017

On J _eff =0 Ground State Iridates(V): Tracking Residual Paramagnetism in New Bi ₂ NaIrO ₆
journal, October 2018

Structural and magnetic studies of KOsO ₄ , a 5d ¹ quantum magnet oxide
journal, January 2019

Spin-orbit coupled systems in the "atomic" limit: rhenates, osmates, iridates
text, January 2018

Octupolar order in d-orbital Mott insulators
text, January 2019