Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides
Abstract
Abstract This crystallographic and computational study describes an unusual potassium silanide structure. A contact ion pair is expected in the solid state between potassium and silicon, yet the potassium cation binds an aromatic ring and the anionic silanide interacts with CH bonds on neighboring crown ether molecules. These structure‐bonding phenomena are attributed to strong soft–soft interactions.
- Authors:
-
[1]
- Department of Chemistry Johns Hopkins University 3400 N. Charles St Baltimore MD 21218 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1399800
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Name: Chemistry - A European Journal Journal Volume: 23 Journal Issue: 62; Journal ID: ISSN 0947-6539
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Marro, Eric A., Press, Eric M., Purkait, Tapas K., Jimenez, Daniel, Siegler, Maxime A., and Klausen, Rebekka S.. Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides. Germany: N. p., 2017.
Web. doi:10.1002/chem.201704217.
Marro, Eric A., Press, Eric M., Purkait, Tapas K., Jimenez, Daniel, Siegler, Maxime A., & Klausen, Rebekka S.. Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides. Germany. https://doi.org/10.1002/chem.201704217
Marro, Eric A., Press, Eric M., Purkait, Tapas K., Jimenez, Daniel, Siegler, Maxime A., and Klausen, Rebekka S.. Tue .
"Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides". Germany. https://doi.org/10.1002/chem.201704217.
@article{osti_1399800,
title = {Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides},
author = {Marro, Eric A. and Press, Eric M. and Purkait, Tapas K. and Jimenez, Daniel and Siegler, Maxime A. and Klausen, Rebekka S.},
abstractNote = {Abstract This crystallographic and computational study describes an unusual potassium silanide structure. A contact ion pair is expected in the solid state between potassium and silicon, yet the potassium cation binds an aromatic ring and the anionic silanide interacts with CH bonds on neighboring crown ether molecules. These structure‐bonding phenomena are attributed to strong soft–soft interactions.},
doi = {10.1002/chem.201704217},
journal = {Chemistry - A European Journal},
number = 62,
volume = 23,
place = {Germany},
year = {2017},
month = {10}
}
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https://doi.org/10.1002/chem.201704217
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