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Title: Beyond native block copolymer morphologies

Block copolymers self-assemble into a range of canonical morphologies. Here, we review a broad range of techniques for inducing these materials to form structures beyond the ‘native’ morphologies seen in the bulk equilibrium phase diagram. Methods that exploit intrinsic encoding (molecular design) and external enforcement (directed assembly) are compared.
Authors:
ORCiD logo [1] ; ORCiD logo [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
Publication Date:
Report Number(s):
BNL-114375-2017-JA
Journal ID: ISSN 2058-9689; MSDEBG; KC0403020
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
Molecular Systems Design & Engineering
Additional Journal Information:
Journal Volume: 2; Journal Issue: 5; Journal ID: ISSN 2058-9689
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; block copolymer; self-assembly; Center for Functional Nanomaterials
OSTI Identifier:
1399668

Doerk, Gregory S., and Yager, Kevin G.. Beyond native block copolymer morphologies. United States: N. p., Web. doi:10.1039/c7me00069c.
Doerk, Gregory S., & Yager, Kevin G.. Beyond native block copolymer morphologies. United States. doi:10.1039/c7me00069c.
Doerk, Gregory S., and Yager, Kevin G.. 2017. "Beyond native block copolymer morphologies". United States. doi:10.1039/c7me00069c. https://www.osti.gov/servlets/purl/1399668.
@article{osti_1399668,
title = {Beyond native block copolymer morphologies},
author = {Doerk, Gregory S. and Yager, Kevin G.},
abstractNote = {Block copolymers self-assemble into a range of canonical morphologies. Here, we review a broad range of techniques for inducing these materials to form structures beyond the ‘native’ morphologies seen in the bulk equilibrium phase diagram. Methods that exploit intrinsic encoding (molecular design) and external enforcement (directed assembly) are compared.},
doi = {10.1039/c7me00069c},
journal = {Molecular Systems Design & Engineering},
number = 5,
volume = 2,
place = {United States},
year = {2017},
month = {9}
}