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Title: 2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage

Abstract

In the quest to develop energy storage with both high power and high energy densities, and while maintaining high volumetric capacity, recent results show that a variety of 2D and layered materials exhibit rapid kinetics of ion transport by the incorporation of nanoconfined fluids.

Authors:
 [1];  [2]
  1. North Carolina State Univ., Raleigh, NC (United States). Dept. of Materials Science and Engineering
  2. Drexel Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering, A. J. Drexel Nanomaterials Inst.
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1399369
Grant/Contract Number:  
AC05-00OR22725; 1653827
Resource Type:
Accepted Manuscript
Journal Name:
Joule
Additional Journal Information:
Journal Volume: 1; Journal Issue: 3; Journal ID: ISSN 2542-4351
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 2D; layered material; nanoconfined fluid; batteries; electrochemical capacitors; energy storage

Citation Formats

Augustyn, Veronica, and Gogotsi, Yury. 2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage. United States: N. p., 2017. Web. doi:10.1016/j.joule.2017.09.008.
Augustyn, Veronica, & Gogotsi, Yury. 2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage. United States. https://doi.org/10.1016/j.joule.2017.09.008
Augustyn, Veronica, and Gogotsi, Yury. Wed . "2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage". United States. https://doi.org/10.1016/j.joule.2017.09.008. https://www.osti.gov/servlets/purl/1399369.
@article{osti_1399369,
title = {2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage},
author = {Augustyn, Veronica and Gogotsi, Yury},
abstractNote = {In the quest to develop energy storage with both high power and high energy densities, and while maintaining high volumetric capacity, recent results show that a variety of 2D and layered materials exhibit rapid kinetics of ion transport by the incorporation of nanoconfined fluids.},
doi = {10.1016/j.joule.2017.09.008},
journal = {Joule},
number = 3,
volume = 1,
place = {United States},
year = {2017},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 70 works
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Works referenced in this record:

Perspective: The energy-storage revolution
journal, October 2015


Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014

  • Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
  • Energy & Environmental Science, Vol. 7, Issue 5
  • DOI: 10.1039/c3ee44164d

A review of conduction phenomena in Li-ion batteries
journal, December 2010


Conveying Advanced Li-ion Battery Materials into Practice The Impact of Electrode Slurry Preparation Skills
journal, July 2016

  • Kraytsberg, Alexander; Ein-Eli, Yair
  • Advanced Energy Materials, Vol. 6, Issue 21
  • DOI: 10.1002/aenm.201600655

2D metal carbides and nitrides (MXenes) for energy storage
journal, January 2017


Nanomaterials for Electrochemical Energy Storage: the Good and the Bad
journal, September 2016


A review of advanced and practical lithium battery materials
journal, January 2011

  • Marom, Rotem; Amalraj, S. Francis; Leifer, Nicole
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c0jm04225k

Liquid Exfoliation of Layered Materials
journal, June 2013

  • Nicolosi, V.; Chhowalla, M.; Kanatzidis, M. G.
  • Science, Vol. 340, Issue 6139, p. 1226419
  • DOI: 10.1126/science.1226419

Nonaqueous Production of Nanostructured Anatase with High-Energy Facets
journal, December 2008

  • Wu, Binghui; Guo, Changyou; Zheng, Nanfeng
  • Journal of the American Chemical Society, Vol. 130, Issue 51
  • DOI: 10.1021/ja8069715

Two-Dimensional Materials for Beyond-Lithium-Ion Batteries
journal, March 2016


Interlayer Nanoarchitectonics of Two-Dimensional Transition-Metal Dichalcogenides Nanosheets for Energy Storage and Conversion Applications
journal, June 2017

  • Xu, Jun; Zhang, Junjun; Zhang, Wenjun
  • Advanced Energy Materials, Vol. 7, Issue 23
  • DOI: 10.1002/aenm.201700571

Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008

  • Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
  • Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
  • DOI: 10.1002/anie.200702505

Structure of V 2 O 5 · n H 2 O Xerogel Solved by the Atomic Pair Distribution Function Technique
journal, August 2002

  • Petkov, Valeri; Trikalitis, Pantelis N.; Bozin, Emil S.
  • Journal of the American Chemical Society, Vol. 124, Issue 34
  • DOI: 10.1021/ja026143y

Sol-gel chemistry and electrochemical properties of vanadium oxide gels
journal, July 1996


Mechanism of Zn Insertion into Nanostructured δ-MnO 2 : A Nonaqueous Rechargeable Zn Metal Battery
journal, May 2017


Change in the Dehydration and Crystallization Processes of V2O5 Xerogel due to Mechanical Pretreatment
journal, November 1993


Water in the interlayer region of birnessite: Importance in cation exchange and structural stability
journal, April 2006


Topotactic redox reactions and ion exchange of layered MoO3 bronzes
journal, January 1976


Effect of Metal Ion Intercalation on the Structure of MXene and Water Dynamics on its Internal Surfaces
journal, March 2016

  • Osti, Naresh C.; Naguib, Michael; Ostadhossein, Alireza
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 14
  • DOI: 10.1021/acsami.6b01490

Role of the water content on the electrochromic properties of WO3, thin films
journal, July 1989


Electrochemical Insertion of Magnesium into Hydrated Vanadium Bronzes
journal, January 1995

  • Novák, Petr; Scheifele, Werner; Joho, Felix
  • Journal of The Electrochemical Society, Vol. 142, Issue 8, p. 2544-2550
  • DOI: 10.1149/1.2050051

Nickel hydroxides and related materials: a review of their structures, synthesis and properties
journal, February 2015

  • Hall, David S.; Lockwood, David J.; Bock, Christina
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 471, Issue 2174
  • DOI: 10.1098/rspa.2014.0792

Nickel Hydroxide as an Active Material for the Positive Electrode in Rechargeable Alkaline Batteries
journal, January 1999

  • Chen, J.
  • Journal of The Electrochemical Society, Vol. 146, Issue 10
  • DOI: 10.1149/1.1392522

Electrochemically Imprenated Aluminum-Stabilized α-Nickel Hydroxide Electrodes
journal, January 1999

  • Dixit, Mridula
  • Electrochemical and Solid-State Letters, Vol. 2, Issue 4
  • DOI: 10.1149/1.1390772

Transition from Battery to Pseudocapacitor Behavior via Structural Water in Tungsten Oxide
journal, April 2017


The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)
journal, January 2016

  • Mashtalir, O.; Lukatskaya, M. R.; Kolesnikov, A. I.
  • Nanoscale, Vol. 8, Issue 17
  • DOI: 10.1039/C6NR01462C

Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides
journal, July 2017


Nanostructured Layered Cathode for Rechargeable Mg-Ion Batteries
journal, July 2015


Role of Structural H 2 O in Intercalation Electrodes: The Case of Mg in Nanocrystalline Xerogel-V 2 O 5
journal, March 2016

  • Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele; Richards, William Davidson
  • Nano Letters, Vol. 16, Issue 4
  • DOI: 10.1021/acs.nanolett.5b05273

The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries
journal, May 2015


A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016


A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery
journal, August 2016

  • Senguttuvan, Premkumar; Han, Sang-Don; Kim, Soojeong
  • Advanced Energy Materials, Vol. 6, Issue 24
  • DOI: 10.1002/aenm.201600826

Ultrafast Solvent-Assisted Sodium Ion Intercalation into Highly Crystalline Few-Layered Graphene
journal, December 2015


Exploiting Lithium-Ether Co-Intercalation in Graphite for High-Power Lithium-Ion Batteries
journal, June 2017

  • Kim, Haegyeom; Lim, Kyungmi; Yoon, Gabin
  • Advanced Energy Materials, Vol. 7, Issue 19
  • DOI: 10.1002/aenm.201700418

The mechanism of electrointercalation
journal, January 1992


Solvated Li-Ion Transfer at Interface Between Graphite and Electrolyte
journal, January 2004

  • Abe, Takeshi; Fukuda, Hideo; Iriyama, Yasutoshi
  • Journal of The Electrochemical Society, Vol. 151, Issue 8
  • DOI: 10.1149/1.1763141

Li + -solvation/desolvation dictates interphasial processes on graphitic anode in Li ion cells
journal, August 2012

  • Xu, Kang; von Wald Cresce, Arthur
  • Journal of Materials Research, Vol. 27, Issue 18
  • DOI: 10.1557/jmr.2012.104

Solvation structure and energetics of electrolytes for multivalent energy storage
journal, January 2014

  • Lapidus, Saul H.; Rajput, Nav Nidhi; Qu, Xiaohui
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 40
  • DOI: 10.1039/C4CP03015J

Frustrated Solvation Structures Can Enhance Electron Transfer Rates
journal, November 2015

  • Remsing, Richard C.; McKendry, Ian G.; Strongin, Daniel R.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 23
  • DOI: 10.1021/acs.jpclett.5b02277

Nickel Confined in the Interlayer Region of Birnessite: an Active Electrocatalyst for Water Oxidation
journal, May 2016

  • Thenuwara, Akila C.; Cerkez, Elizabeth B.; Shumlas, Samantha L.
  • Angewandte Chemie International Edition, Vol. 55, Issue 35
  • DOI: 10.1002/anie.201601935

Intercalation of Cobalt into the Interlayer of Birnessite Improves Oxygen Evolution Catalysis
journal, October 2016

  • Thenuwara, Akila C.; Shumlas, Samantha L.; Attanayake, Nuwan H.
  • ACS Catalysis, Vol. 6, Issue 11
  • DOI: 10.1021/acscatal.6b01980

Lithium diffusion mechanisms in layered intercalation compounds
journal, July 2001


On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials
journal, February 2010

  • Levi, E.; Gofer, Y.; Aurbach, D.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm9016497

Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores
journal, September 2017

  • Futamura, Ryusuke; Iiyama, Taku; Takasaki, Yuma
  • Nature Materials, Vol. 16, Issue 12
  • DOI: 10.1038/nmat4974

Hydrogen motion in oxides: from insulators to bronzes
journal, March 2004


From Layered Molybdic Acid to Lower-Dimensional Nanostructures by Intercalation of Amines under Ambient Conditions
journal, April 2006

  • Shukoor, Mohammed Ibrahim; Therese, Helen Annal; Gorgishvili, Lela
  • Chemistry of Materials, Vol. 18, Issue 8
  • DOI: 10.1021/cm051685a

The critical role of point defects in improving the specific capacitance of δ-MnO2 nanosheets
journal, February 2017

  • Gao, Peng; Metz, Peter; Hey, Trevyn
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14559

In situ NMR and electrochemical quartz crystal microbalance techniques reveal the structure of the electrical double layer in supercapacitors
journal, June 2015

  • Griffin, John M.; Forse, Alexander C.; Tsai, Wan-Yu
  • Nature Materials, Vol. 14, Issue 8
  • DOI: 10.1038/nmat4318

Nickel-based rechargeable batteries
journal, November 2001


Nanoconfinement effects on hydrated excess protons in layered materials
journal, August 2013

  • Muñoz-Santiburcio, Daniel; Wittekindt, Carsten; Marx, Dominik
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3349

Two-dimensional heterostructures for energy storage
journal, June 2017


Works referencing / citing this record:

Anomalously low activation energy of nanoconfined MgCO 3 precipitation
journal, January 2019

  • Miller, Quin R. S.; Kaszuba, John P.; Schaef, Herbert T.
  • Chemical Communications, Vol. 55, Issue 48
  • DOI: 10.1039/c9cc01337g

Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries
journal, January 2019


Hydrated Intercalation for High‐Performance Aqueous Zinc Ion Batteries
journal, February 2019

  • Shin, Jaeho; Choi, Dong Shin; Lee, Hyeon Jeong
  • Advanced Energy Materials, Vol. 9, Issue 14
  • DOI: 10.1002/aenm.201900083

Energy storage: The future enabled by nanomaterials
journal, November 2019

  • Pomerantseva, Ekaterina; Bonaccorso, Francesco; Feng, Xinliang
  • Science, Vol. 366, Issue 6468
  • DOI: 10.1126/science.aan8285

Dual-phase nanostructuring of layered metal oxides for high-performance aqueous rechargeable potassium ion microbatteries
journal, September 2019


The Road Towards Planar Microbatteries and Micro‐Supercapacitors: From 2D to 3D Device Geometries
journal, June 2019


Ultrafast Intercalation Enabled by Strong Solvent-Host Interactions: Understanding Solvent Effect at the Atomic Level
journal, October 2019

  • Zhu, Yue; Ji, Yujin; Ju, Zhengyu
  • Angewandte Chemie International Edition, Vol. 58, Issue 48
  • DOI: 10.1002/anie.201908982

High-rate lithium ion energy storage to facilitate increased penetration of photovoltaic systems in electricity grids
journal, January 2019

  • Lennon, Alison; Jiang, Yu; Hall, Charles
  • MRS Energy & Sustainability, Vol. 6
  • DOI: 10.1557/mre.2019.4

Ultrafast Intercalation Enabled by Strong Solvent–Host Interactions: Understanding Solvent Effect at the Atomic Level
journal, November 2019


MXene‐Based Composites: Synthesis and Applications in Rechargeable Batteries and Supercapacitors
journal, February 2019

  • Yang, Jian; Bao, Weizhai; Jaumaux, Pauline
  • Advanced Materials Interfaces, Vol. 6, Issue 8
  • DOI: 10.1002/admi.201802004

Solvation‐Involved Nanoionics: New Opportunities from 2D Nanomaterial Laminar Membranes
journal, December 2019


Confined Catalysis: Progress and Prospects in Energy Conversion
journal, September 2019

  • Shifa, Tofik Ahmed; Vomiero, Alberto
  • Advanced Energy Materials, Vol. 9, Issue 40
  • DOI: 10.1002/aenm.201902307

Activation-free fabrication of high-surface-area porous carbon nanosheets from conjugated copolymers
journal, January 2018

  • Tang, Youchen; Liu, Shaohong; Zheng, Bingna
  • Chemical Communications, Vol. 54, Issue 81
  • DOI: 10.1039/c8cc05703f

Pseudocapacitive layered birnessite sodium manganese dioxide for high-rate non-aqueous sodium ion capacitors
journal, January 2018

  • Jiang, Yalong; Tan, Shuangshuang; Wei, Qiulong
  • Journal of Materials Chemistry A, Vol. 6, Issue 26
  • DOI: 10.1039/c8ta02516a

High-rate lithium ion energy storage to facilitate increased penetration of photovoltaic systems in electricity grids
text, January 2019

  • Lennon, Alison; Jiang, Yu; Hall, Charles
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.70661

High-rate lithium ion energy storage to facilitate increased penetration of photovoltaic systems in electricity grids
text, January 2020

  • Lennon, Alison; Jiang, Yu; Hall, Charles
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.57869

High-rate lithium ion energy storage to facilitate increased penetration of photovoltaic systems in electricity grids
text, January 2019

  • Lennon, Alison; Jiang, Yu; Hall, Charles
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.62489

Dual-phase nanostructuring of layered metal oxides for high-performance aqueous rechargeable potassium ion microbatteries
journal, September 2019