Neutron diffraction and μSR studies of two polymorphs of nickel niobate NiNb2O6

Munsie, T. J.  S.; Wilson, M. N.; Millington, A.; Thompson, C. M.; Flacau, R.; Ding, C.; Guo, S.; Gong, Z.; Aczel, A. A.; Cao, H. B.; Williams, T. J.; Dabkowska, H. A.; Ning, F.; Greedan, J. E.; Luke, G. M.

doi:10.1103/PhysRevB.96.144417

Title: Neutron diffraction and $μ SR$ studies of two polymorphs of nickel niobate ${NiNb}_{2} O_{6}$

Abstract

Neutron diffraction and muon spin relaxation (μSR) studies are presented in this paper for the newly characterized polymorph of NiNb₂O₆ (β-NiNb₂O₆) with space group P4₂/n and μSR data only for the previously known columbite structure polymorph with space group Pbcn. The magnetic structure of the P4₂/n form was determined from neutron diffraction using both powder and single-crystal data. Powder neutron diffraction determined an ordering wave vector ^→k=(¹/₂,¹/₂,¹/₂). Single-crystal data confirmed the same ^→k vector and showed that the correct magnetic structure consists of antiferromagnetically coupled chains running along the a or b axis in adjacent Ni²⁺ layers perpendicular to the c axis, which is consistent with the expected exchange interaction hierarchy in this system. The refined magnetic structure is compared with the known magnetic structures of the closely related trirutile phases, NiSb₂O₆ and NiTa₂O₆. μSR data finds a transition temperature of T_N~15K for this system, while the columbite polymorph exhibits a lower T_N=5.7(3) K. Our μSR measurements also allowed us to estimate the critical exponent of the order parameter β for each polymorph. We found β =0.25(3) and 0.16(2) for the β and columbite polymorphs, respectively. The single-crystal neutron scattering data give a value for the critical exponent β =0.28(3)more »« less

Authors:

Munsie, T. J. S. ^[1]; Wilson, M. N. ^[1]; Millington, A. ^[1]; Thompson, C. M. ^[2]; Flacau, R. ^[3]; Ding, C. ^[4]; Guo, S. ^[4]; Gong, Z. ^[5]; Aczel, A. A. ^[6]; Cao, H. B. ^[6]; Williams, T. J. ^[6]; Dabkowska, H. A. ^[7]; Ning, F. ^[4]; Greedan, J. E. ^[8]; Luke, G. M. ^[9]

McMaster Univ., Hamilton, ON (Canada). Dept. of Physics and Astronomy
Purdue Univ., West Lafayette, IN (United States). Dept. of Chemistry
Canadian Neutron Beam Centre, Chalk River, ON (Canada)
Zhejiang Univ., Hangzhou (China). Dept. of Physics
Columbia Univ., New York, NY (United States). Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division. Neutron Sciences Directorate
McMaster Univ., Hamilton, ON (Canada). Brockhouse Inst. for Materials Research
McMaster Univ., Hamilton, ON (Canada). Brockhouse Inst. for Materials Research. Dept. of Chemistry
McMaster Univ., Hamilton, ON (Canada). Dept. of Physics and Astronomy. Brockhouse Inst. for Materials Research; Canadian Inst. for Advanced Research, Toronto, ON (Canada)

Publication Date:: Fri Oct 13 00:00:00 EDT 2017

Research Org.:: McMaster Univ., Hamilton, ON (Canada); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Ontario Graduate Scholarship (OGS) (Canada); Natural Sciences and Engineering Research Council of Canada (NSERC)

OSTI Identifier:: 1423057

Alternate Identifier(s):: OSTI ID: 1399284

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 96; Journal Issue: 14; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; antiferromagnetism; crystal growth; frustrated magnetism; magnetic interactions; magnetic order parameter; magnetic phase transitions; order parameters; antiferromagnets; magnetic systems; muon spin relaxation & rotation; neutron diffraction; condensed matter & materials physics

Citation Formats


                    Munsie, T. J.  S., Wilson, M. N., Millington, A., Thompson, C. M., Flacau, R., Ding, C., Guo, S., Gong, Z., Aczel, A. A., Cao, H. B., Williams, T. J., Dabkowska, H. A., Ning, F., Greedan, J. E., and Luke, G. M. Neutron diffraction and μSR studies of two polymorphs of nickel niobate NiNb2O6.  United States: N. p., 2017. 
Web.  doi:10.1103/PhysRevB.96.144417.

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                    Munsie, T. J.  S., Wilson, M. N., Millington, A., Thompson, C. M., Flacau, R., Ding, C., Guo, S., Gong, Z., Aczel, A. A., Cao, H. B., Williams, T. J., Dabkowska, H. A., Ning, F., Greedan, J. E., & Luke, G. M. Neutron diffraction and μSR studies of two polymorphs of nickel niobate NiNb2O6.  United States.  https://doi.org/10.1103/PhysRevB.96.144417

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                    Munsie, T. J.  S., Wilson, M. N., Millington, A., Thompson, C. M., Flacau, R., Ding, C., Guo, S., Gong, Z., Aczel, A. A., Cao, H. B., Williams, T. J., Dabkowska, H. A., Ning, F., Greedan, J. E., and Luke, G. M. Fri .  
"Neutron diffraction and μSR studies of two polymorphs of nickel niobate NiNb2O6".  United States.  https://doi.org/10.1103/PhysRevB.96.144417.  https://www.osti.gov/servlets/purl/1423057.

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@article{osti_1423057,

  title        = {Neutron diffraction and μSR studies of two polymorphs of nickel niobate NiNb2O6},

  author       = {Munsie, T. J.  S. and Wilson, M. N. and Millington, A. and Thompson, C. M. and Flacau, R. and Ding, C. and Guo, S. and Gong, Z. and Aczel, A. A. and Cao, H. B. and Williams, T. J. and Dabkowska, H. A. and Ning, F. and Greedan, J. E. and Luke, G. M.},

  abstractNote = {Neutron diffraction and muon spin relaxation (μSR) studies are presented in this paper for the newly characterized polymorph of NiNb2O6 (β-NiNb2O6) with space group P42/n and μSR data only for the previously known columbite structure polymorph with space group Pbcn. The magnetic structure of the P42/n form was determined from neutron diffraction using both powder and single-crystal data. Powder neutron diffraction determined an ordering wave vector →k=(1/2,1/2,1/2). Single-crystal data confirmed the same →k vector and showed that the correct magnetic structure consists of antiferromagnetically coupled chains running along the a or b axis in adjacent Ni2+ layers perpendicular to the c axis, which is consistent with the expected exchange interaction hierarchy in this system. The refined magnetic structure is compared with the known magnetic structures of the closely related trirutile phases, NiSb2O6 and NiTa2O6. μSR data finds a transition temperature of TN~15K for this system, while the columbite polymorph exhibits a lower TN=5.7(3) K. Our μSR measurements also allowed us to estimate the critical exponent of the order parameter β for each polymorph. We found β =0.25(3) and 0.16(2) for the β and columbite polymorphs, respectively. The single-crystal neutron scattering data give a value for the critical exponent β =0.28(3) for β-NiNb2O6, in agreement with the μSR value. While both systems have β values less than 0.3, which is indicative of reduced dimensionality, this effect appears to be much stronger for the columbite system. Finally, in other words, although both systems appear to be well described by S=1 spin chains, the interchain interactions in the β polymorph are likely much larger.},

  doi          = {10.1103/PhysRevB.96.144417},

  journal      = {Physical Review B},

  number       = 14,

  volume       = 96,

  place        = {United States},

  year         = {Fri Oct 13 00:00:00 EDT 2017},

  month        = {Fri Oct 13 00:00:00 EDT 2017}

}

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Title: Neutron diffraction and μ SR studies of two polymorphs of nickel niobate NiNb 2 O 6

Abstract

Citation Formats

Noncentrosymmetric Oxides journal, October 1998

Strongly correlated one-dimensional magnetic behavior of NiTa 2 O 6 journal, January 2014

Heat capacity peak at the quantum critical point of the transverse Ising magnet CoNb2O6 journal, July 2015

Three-dimensional magnetic ordering in the quasi-one-dimensional Ising magnet CoNb 2 O 6 with partially released geometrical frustration journal, August 1999

Hierarchy of Bound States in the One-Dimensional Ferromagnetic Ising Chain CoNb 2 O 6 Investigated by High-Resolution Time-Domain Terahertz Spectroscopy journal, April 2014

Crystal growth and magnetic characterization of a tetragonal polymorph of NiNb2O6 journal, April 2016

New investigation of the magnetic structure of CoNb 2 O 6 columbite journal, April 2011

Magnetic properties of MTa2O6 (M = Fe, Co or Ni) journal, June 1970

Kristallstrukturverfeinerung von Wolframiten und Columbiten journal, January 1976

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Synthese und Untersuchung von NiNb2O6-Einkristallen mit Columbit- und Rutilstruktur journal, August 1983

Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor journal, May 2011

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Quantum Criticality in an Ising Chain: Experimental Evidence for Emergent E 8 Symmetry journal, January 2010

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Magnetic structures of the tri-rutiles NiTa2O6 and NiSb2O6 journal, April 1998

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Submillimeter Wave ESR Study of Magnetic Excitations in the Ising Ferromagnetic Chain CoNb 2 O 6 journal, May 1999

Synthesis, structural characterization, and two-dimensional antiferromagnetic ordering for the oxides Ti3(1−x)NixSb2xO6 (1.0 ≥ x ≥ 0.6) journal, March 1991

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Magnetization studies in transition-metal niobates: I. Ni Nb 2 O 6 journal, February 1977

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Excitations in the quantum paramagnetic phase of the quasi-one-dimensional Ising magnet CoNb 2 O 6 in a transverse field: Geometric frustration and quantum renormalization effects journal, July 2014

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Title: Neutron diffraction and $μ SR$ studies of two polymorphs of nickel niobate ${NiNb}_{2} O_{6}$

Noncentrosymmetric Oxides
journal, October 1998

Strongly correlated one-dimensional magnetic behavior of ${NiTa}_{2}$ $O_{6}$
journal, January 2014

Heat capacity peak at the quantum critical point of the transverse Ising magnet CoNb2O6
journal, July 2015

Three-dimensional magnetic ordering in the quasi-one-dimensional Ising magnet ${CoNb}_{2} O_{6}$ with partially released geometrical frustration
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Hierarchy of Bound States in the One-Dimensional Ferromagnetic Ising Chain ${CoNb}_{2} O_{6}$ Investigated by High-Resolution Time-Domain Terahertz Spectroscopy
journal, April 2014

Crystal growth and magnetic characterization of a tetragonal polymorph of NiNb2O6
journal, April 2016

New investigation of the magnetic structure of CoNb ₂ O ₆ columbite
journal, April 2011

Magnetic properties of MTa2O6 (M = Fe, Co or Ni)
journal, June 1970

Kristallstrukturverfeinerung von Wolframiten und Columbiten
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Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Synthese und Untersuchung von NiNb2O6-Einkristallen mit Columbit- und Rutilstruktur
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Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor
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VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
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Quantum Criticality in an Ising Chain: Experimental Evidence for Emergent E ₈ Symmetry
journal, January 2010

Musrfit: A Free Platform-Independent Framework for μSR Data Analysis
journal, January 2012

Magnetic structures of the tri-rutiles NiTa2O6 and NiSb2O6
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A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh)
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Submillimeter Wave ESR Study of Magnetic Excitations in the Ising Ferromagnetic Chain CoNb ₂ O ₆
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Synthesis, structural characterization, and two-dimensional antiferromagnetic ordering for the oxides Ti3(1−x)NixSb2xO6 (1.0 ≥ x ≥ 0.6)
journal, March 1991

SPECIFIC HEAT OF MTa ₂ O ₆ (M = Co, Ni, Fe, Mg) EVIDENCE FOR LOW DIMENSIONAL MAGNETISM
journal, December 1988

Magnetization studies in transition-metal niobates: I. Ni ${Nb}_{2}$ $O_{6}$
journal, February 1977

One-dimensional antiferromagnetic ordering for a novel nickel-antimony oxide
journal, September 1992

Excitations in the quantum paramagnetic phase of the quasi-one-dimensional Ising magnet ${CoNb}_{2}$ $O_{6}$ in a transverse field: Geometric frustration and quantum renormalization effects
journal, July 2014

Magnetism in and
journal, December 1996

A stochastic theory of spin relaxation
journal, January 1981

Preparation of large single crystals of ANb2O6 (A=Ni, Co, Fe, Mn) by the floating-zone method
journal, March 2003

Evolution of Quantum Fluctuations Near the Quantum Critical Point of the Transverse Field Ising Chain System ${CoNb}_{2} O_{6}$
journal, July 2014

A study on AB ₂ O ₆ compounds, Part II: the branches of the hcp family
journal, December 2012

Lead palladium titanate: A room temperature nanoscale multiferroic thin film
journal, February 2020

Kristallstrukturverfeinerung von Wolframiten und Columbiten
journal, January 1976

Musrfit: a free platform-independent framework for μSR data analysis
text, January 2012

Excitations in the quantum paramagnetic phase of the quasi-one-dimensional Ising magnet CoNb$_2$O$_6$ in a transverse field: Geometric frustration and quantum renormalization effects
text, January 2014