Dendrite-Suppressed Lithium Plating from a Liquid Electrolyte via Wetting of Li3N
Abstract
Lithium metal is an ultimate anode material to provide the highest energy density for a given cathode by providing a higher capacity and cell voltage. However, lithium is not used as the anode in commercial lithium-ion batteries because electrochemical dendrite formation and growth during charge can induce a cell short circuit that ignites the flammable liquid electrolyte. Plating of lithium through a bed of Li3N particles is shown to transform dendrite growth into a 3D lithium network formed by wetting the particle surfaces; plating through a Li3N particle is without dendrite nucleation. The Li3N particles create a higher overpotential during Li deposition than that with dendrite growth in galvanostatic charge/discharge tests. The characteristic overpotential increase is correlated with the morphological changes and a more isotropic growth behavior. The Li3N-modified Li electrode shows a stable cycling performance at 0.5 and 1.0 mA cm-2 for more than 100 cycles. In this paper, the origin of the bonding responsible for wetting of the Li3N particles by lithium and for plating through a Li3N particle is discussed.
- Authors:
-
- Univ. of Texas, Austin, TX (United States). Texas Materials Institute
- Publication Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1430485
- Alternate Identifier(s):
- OSTI ID: 1399054
- Grant/Contract Number:
- EE0007762
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 19; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; batteries; dendrite; Li3N; lithium; wetting
Citation Formats
Park, Kyusung, and Goodenough, John B. Dendrite-Suppressed Lithium Plating from a Liquid Electrolyte via Wetting of Li3N. United States: N. p., 2017.
Web. doi:10.1002/aenm.201700732.
Park, Kyusung, & Goodenough, John B. Dendrite-Suppressed Lithium Plating from a Liquid Electrolyte via Wetting of Li3N. United States. https://doi.org/10.1002/aenm.201700732
Park, Kyusung, and Goodenough, John B. Mon .
"Dendrite-Suppressed Lithium Plating from a Liquid Electrolyte via Wetting of Li3N". United States. https://doi.org/10.1002/aenm.201700732. https://www.osti.gov/servlets/purl/1430485.
@article{osti_1430485,
title = {Dendrite-Suppressed Lithium Plating from a Liquid Electrolyte via Wetting of Li3N},
author = {Park, Kyusung and Goodenough, John B.},
abstractNote = {Lithium metal is an ultimate anode material to provide the highest energy density for a given cathode by providing a higher capacity and cell voltage. However, lithium is not used as the anode in commercial lithium-ion batteries because electrochemical dendrite formation and growth during charge can induce a cell short circuit that ignites the flammable liquid electrolyte. Plating of lithium through a bed of Li3N particles is shown to transform dendrite growth into a 3D lithium network formed by wetting the particle surfaces; plating through a Li3N particle is without dendrite nucleation. The Li3N particles create a higher overpotential during Li deposition than that with dendrite growth in galvanostatic charge/discharge tests. The characteristic overpotential increase is correlated with the morphological changes and a more isotropic growth behavior. The Li3N-modified Li electrode shows a stable cycling performance at 0.5 and 1.0 mA cm-2 for more than 100 cycles. In this paper, the origin of the bonding responsible for wetting of the Li3N particles by lithium and for plating through a Li3N particle is discussed.},
doi = {10.1002/aenm.201700732},
journal = {Advanced Energy Materials},
number = 19,
volume = 7,
place = {United States},
year = {Mon Jul 10 00:00:00 EDT 2017},
month = {Mon Jul 10 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Improved Cycle Life and Stability of Lithium Metal Anodes through Ultrathin Atomic Layer Deposition Surface Treatments
journal, September 2015
- Kazyak, Eric; Wood, Kevin N.; Dasgupta, Neil P.
- Chemistry of Materials, Vol. 27, Issue 18
Dendrite-free lithium metal anodes: stable solid electrolyte interphases for high-efficiency batteries
journal, January 2015
- Cheng, Xin-Bing; Zhang, Qiang
- Journal of Materials Chemistry A, Vol. 3, Issue 14
Mechanical Surface Modification of Lithium Metal: Towards Improved Li Metal Anode Performance by Directed Li Plating
journal, December 2014
- Ryou, Myung-Hyun; Lee, Yong Min; Lee, Yunju
- Advanced Functional Materials, Vol. 25, Issue 6
Lithium metal stripping/plating mechanisms studies: A metallurgical approach
journal, October 2006
- Gireaud, L.; Grugeon, S.; Laruelle, S.
- Electrochemistry Communications, Vol. 8, Issue 10, p. 1639-1649
Li dendrite growth and Li+ ionic mass transfer phenomenon
journal, October 2011
- Nishikawa, Kei; Mori, Takeshi; Nishida, Tetsuo
- Journal of Electroanalytical Chemistry, Vol. 661, Issue 1
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Ionic conductivity in Li 3 N single crystals
journal, June 1977
- Alpen, U. v.; Rabenau, A.; Talat, G. H.
- Applied Physics Letters, Vol. 30, Issue 12
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002
- Aurbach, D.
- Solid State Ionics, Vol. 148, Issue 3-4
Dendrite Suppression by Shock Electrodeposition in Charged Porous Media
journal, June 2016
- Han, Ji-Hyung; Wang, Miao; Bai, Peng
- Scientific Reports, Vol. 6, Issue 1
Optical observation of Li dendrite growth in ionic liquid
journal, June 2013
- Nishida, T.; Nishikawa, K.; Rosso, M.
- Electrochimica Acta, Vol. 100
An ex-situ nitridation route to synthesize Li 3 N-modified Li anodes for lithium secondary batteries
journal, March 2015
- Zhang, Y. J.; Wang, W.; Tang, H.
- Journal of Power Sources, Vol. 277
New battery strategies with a polymer/Al2O3 separator
journal, October 2014
- Park, Kyusung; Cho, Joon Hee; Shanmuganathan, Kadhiravan
- Journal of Power Sources, Vol. 263, p. 52-58
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016
- Liang, Zheng; Lin, Dingchang; Zhao, Jie
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015
- Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.
- ACS Nano, Vol. 9, Issue 6
Electrochemical behaviors of a Li3N modified Li metal electrode in secondary lithium batteries
journal, October 2011
- Wu, Meifen; Wen, Zhaoyin; Liu, Yu
- Journal of Power Sources, Vol. 196, Issue 19
Lithium deposit morphology from polymer electrolytes
journal, October 1995
- Matsui, Tooru; Takeyama, Kenichi
- Electrochimica Acta, Vol. 40, Issue 13-14
In situ observation of lithium deposition processes in solid polymer and gel electrolytes
journal, January 1997
- Osaka, Tetsuya; Homma, Takayuki; Momma, Toshiyuki
- Journal of Electroanalytical Chemistry, Vol. 421, Issue 1-2
Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance
journal, June 2016
- Lu, Lei-Lei; Ge, Jin; Yang, Jun-Nan
- Nano Letters, Vol. 16, Issue 7
Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes
journal, May 2016
- Yun, Qinbai; He, Yan-Bing; Lv, Wei
- Advanced Materials, Vol. 28, Issue 32
Inhibition effect of covalently cross-linked gel electrolytes on lithium dendrite formation
journal, January 2001
- Tatsuma, Tetsu; Taguchi, Makoto; Oyama, Noboru
- Electrochimica Acta, Vol. 46, Issue 8
Over-limiting Current and Control of Dendritic Growth by Surface Conduction in Nanopores
journal, November 2014
- Han, Ji-Hyung; Khoo, Edwin; Bai, Peng
- Scientific Reports, Vol. 4, Issue 1
Ionic conductivity of pure and doped Li3N
journal, October 1983
- Lapp, T.
- Solid State Ionics, Vol. 11, Issue 2
Mechanisms of dendritic growth investigated by in situ light microscopy during electrodeposition and dissolution of lithium
journal, September 2014
- Steiger, Jens; Kramer, Dominik; Mönig, Reiner
- Journal of Power Sources, Vol. 261
Oriented TiO2 nanotubes as a lithium metal storage medium
journal, July 2014
- Kim, Jae-Hun; Kang, Hee-Kook; Woo, Sang-Gil
- Journal of Electroanalytical Chemistry, Vol. 726
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013
- Ding, Fei; Xu, Wu; Graff, Gordon L.
- Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016
- Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan
- Nature Energy, Vol. 1, Issue 9
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
journal, February 2016
- Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook
- Nature Energy, Vol. 1, Issue 3, Article No. 16010
The behaviour of lithium electrodes in propylene and ethylene carbonate: Te major factors that influence Li cycling efficiency
journal, November 1992
- Aurbach, Doron; Gofer, Yosef; Ben-Zion, Moshe
- Journal of Electroanalytical Chemistry, Vol. 339, Issue 1-2
Microscopic observations of the formation, growth and shrinkage of lithium moss during electrodeposition and dissolution
journal, August 2014
- Steiger, Jens; Kramer, Dominik; Mönig, Reiner
- Electrochimica Acta, Vol. 136
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy
journal, October 2016
- Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F.
- ACS Central Science, Vol. 2, Issue 11
Dendrite Growth in Lithium/Polymer Systems
journal, January 2003
- Monroe, Charles; Newman, John
- Journal of The Electrochemical Society, Vol. 150, Issue 10
Impedance spectroscopy of lithium electrodes
journal, April 1993
- Aurbach, Doron; Zaban, Arie
- Journal of Electroanalytical Chemistry, Vol. 348, Issue 1-2
Effect of surface modification using various acids on electrodeposition of lithium
journal, June 1995
- Shiraishi, S.; Kanamura, K.; Takehara, Z.
- Journal of Applied Electrochemistry, Vol. 25, Issue 6
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016
- Lin, Dingchang; Liu, Yayuan; Liang, Zheng
- Nature Nanotechnology, Vol. 11, Issue 7
Galvanostatic nucleation and growth under diffusion control
journal, May 2013
- Isaev, Vladimir A.; Grishenkova, Olga V.
- Journal of Solid State Electrochemistry, Vol. 17, Issue 6
Enhancement of Lithium Anode Cyclability in Propylene Carbonate Electrolyte by CO[sub 2] Addition and Its Protective Effect Against H[sub 2]O Impurity
journal, January 1995
- Osaka, Tetsuya
- Journal of The Electrochemical Society, Vol. 142, Issue 4
Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO 2 and Garnet-Li 7 La 3 Zr 2 O 12
journal, October 2016
- Park, Kyusung; Yu, Byeong-Chul; Jung, Ji-Won
- Chemistry of Materials, Vol. 28, Issue 21
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
- Nature Materials, Vol. 13, Issue 10
Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes
text, January 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden
- arXiv
Over-limiting Current and Control of Dendritic Growth by Surface Conduction in Nanopores
text, January 2014
- Han, Ji-Hyung; Khoo, Edwin; Bai, Peng
- arXiv
Works referencing / citing this record:
Long Cycle Life Lithium Metal Batteries Enabled with Upright Lithium Anode
journal, February 2019
- Chen, Yuqing; Yue, Meng; Liu, Cuilian
- Advanced Functional Materials, Vol. 29, Issue 15
Vertically Aligned Carbon Nanofibers on Cu Foil as a 3D Current Collector for Reversible Li Plating/Stripping toward High‐Performance Li–S Batteries
journal, November 2019
- Chen, Yazhou; Elangovan, Ayyappan; Zeng, Danli
- Advanced Functional Materials, Vol. 30, Issue 4
Stabilizing Polymer–Lithium Interface in a Rechargeable Solid Battery
journal, November 2019
- Yan, Min; Liang, Jia‐Yan; Zuo, Tong‐Tong
- Advanced Functional Materials, Vol. 30, Issue 6
The Salt Matters: Enhanced Reversibility of Li-O 2 Batteries with a Li[(CF 3 SO 2 )( n -C 4 F 9 SO 2 )N]-Based Electrolyte
journal, November 2017
- Tong, Bo; Huang, Jun; Zhou, Zhibin
- Advanced Materials, Vol. 30, Issue 1
A 3D Lithiophilic Mo 2 N‐Modified Carbon Nanofiber Architecture for Dendrite‐Free Lithium‐Metal Anodes in a Full Cell
journal, October 2019
- Luo, Liu; Li, Jianyu; Yaghoobnejad Asl, Hooman
- Advanced Materials, Vol. 31, Issue 48
Advances in Interfaces between Li Metal Anode and Electrolyte
journal, December 2017
- Zhang, Xue-Qiang; Cheng, Xin-Bing; Zhang, Qiang
- Advanced Materials Interfaces, Vol. 5, Issue 2
Dendrite-Free Metallic Lithium in Lithiophilic Carbonized Metal-Organic Frameworks
journal, March 2018
- Zhu, Mengqi; Li, Bin; Li, Songmei
- Advanced Energy Materials, Vol. 8, Issue 18
Vertically Grown Edge-Rich Graphene Nanosheets for Spatial Control of Li Nucleation
journal, May 2018
- Song, Qiang; Yan, Huibo; Liu, Kedi
- Advanced Energy Materials, Vol. 8, Issue 22
Efficient Li‐Ion‐Conductive Layer for the Realization of Highly Stable High‐Voltage and High‐Capacity Lithium Metal Batteries
journal, February 2019
- Lee, Jung‐In; Shin, Myungsoo; Hong, Dongki
- Advanced Energy Materials, Vol. 9, Issue 13
Interfacial Incompatibility and Internal Stresses in All‐Solid‐State Lithium Ion Batteries
journal, August 2019
- He, Yanming; Lu, Chuanyang; Liu, Shan
- Advanced Energy Materials, Vol. 9, Issue 36
SnO 2 as Advanced Anode of Alkali‐Ion Batteries: Inhibiting Sn Coarsening by Crafting Robust Physical Barriers, Void Boundaries, and Heterophase Interfaces for Superior Electrochemical Reaction Reversibility
journal, December 2019
- Zhao, Shiqiang; Sewell, Christopher D.; Liu, Ruiping
- Advanced Energy Materials, Vol. 10, Issue 6
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie, Vol. 132, Issue 9
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie International Edition, Vol. 59, Issue 9
Dual Roles of Li 3 N as an Electrode Additive for Li-Excess Layered Cathode Materials: A Li-Ion Sacrificial Salt and Electrode-Stabilizing Agent
journal, August 2018
- Bian, Xiaofei; Pang, Qiang; Wei, Yingjing
- Chemistry - A European Journal, Vol. 24, Issue 52
Assembling All-Solid-State Lithium-Sulfur Batteries with Li 3 N-Protected Anodes
journal, February 2019
- Kızılaslan, Abdulkadir; Akbulut, Hatem
- ChemPlusChem, Vol. 84, Issue 2
Lithiophilic montmorillonite serves as lithium ion reservoir to facilitate uniform lithium deposition
journal, October 2019
- Chen, Wei; Hu, Yin; Lv, Weiqiang
- Nature Communications, Vol. 10, Issue 1
In situ formation of a multicomponent inorganic-rich SEI layer provides a fast charging and high specific energy Li-metal battery
journal, January 2019
- Sun, Ho-Hyun; Dolocan, Andrei; Weeks, Jason A.
- Journal of Materials Chemistry A, Vol. 7, Issue 30
Review—Li Metal Anode in Working Lithium-Sulfur Batteries
journal, June 2017
- Cheng, Xin-Bing; Huang, Jia-Qi; Zhang, Qiang
- Journal of The Electrochemical Society, Vol. 165, Issue 1
Spatiotemporal Quantification of Lithium both in Electrode and in Electrolyte with Atomic Precision via Operando Neutron Absorption
journal, August 2019
- Harks, Peter-Paul R. M. L.; Verhallen, Tomas W.; George, Chandramohan
- Journal of the American Chemical Society, Vol. 141, Issue 36
Lithiophilic montmorillonite serves as lithium ion reservoir to facilitate uniform lithium deposition
journal, October 2019
- Chen, Wei; Hu, Yin; Lv, Weiqiang
- Nature Communications, Vol. 10, Issue 1