Controlled relative humidity storage for high toughness and strength of binderless green pellets

Cannon, W. Roger; Hoggan, Rita E.; Erickson, Arnold; Forsmann, Bryan; O'Brien, Robert C.; Lessing, Paul A.

doi:10.1111/jace.14982

Title: Controlled relative humidity storage for high toughness and strength of binderless green pellets

Abstract

Here, an equation was developed to predict fracture toughness of green powder compacts. The model combines crack tip toughness predicted by Kendall's model with crack tip shielding due to bridging of moisture meniscuses across the crack. The model predicts that crack tip shielding due to moisture should be dominant. Fracture tests on ceria green pellets verified that storing pellets at a high relative humidity (98% RH) for an extended period of time led to fracture strength more than double those stored at lower RH. However, at lower RH there is no significant increase in fracture strength with increased RH as predicted by the model. The lower strength at low RH is due to insufficient capillary and surface forces but may also be related to the lack of sufficient adsorbed moisture to form bridging meniscuses. The high green strengths achieved by storing pellets at a high RH suggest a method of strengthening green parts without adding binder.

Authors:

^[1]; Hoggan, Rita E. ^[1]; Erickson, Arnold ^[1]; Forsmann, Bryan ^[2]; O'Brien, Robert C. ^[1]; Lessing, Paul A. ^[1]

Idaho National Lab. (INL), Idaho Falls, ID (United States)
Boise State Univ., ID (United States). Center for Advanced Energy Studies

Publication Date:: Thu May 18 00:00:00 EDT 2017

Research Org.:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE)

OSTI Identifier:: 1398255

Report Number(s):: INL/JOU-14-33000
Journal ID: ISSN 0002-7820

Grant/Contract Number:: AC07-05ID14517

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the American Ceramic Society

Additional Journal Information:: Journal Volume: 100; Journal Issue: 10; Journal ID: ISSN 0002-7820

Publisher:: American Ceramic Society

Country of Publication:: United States

Language:: English

Subject:: 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; 36 MATERIALS SCIENCE; Fracture toughness; green powder compacts; surrogate nuclear fuel; absorption/absorbents; green body; pressing; strength; toughness

Citation Formats


                    Cannon, W. Roger, Hoggan, Rita E., Erickson, Arnold, Forsmann, Bryan, O'Brien, Robert C., and Lessing, Paul A. Controlled relative humidity storage for high toughness and strength of binderless green pellets.  United States: N. p., 2017. 
Web.  doi:10.1111/jace.14982.

Copy to clipboard


                    Cannon, W. Roger, Hoggan, Rita E., Erickson, Arnold, Forsmann, Bryan, O'Brien, Robert C., & Lessing, Paul A. Controlled relative humidity storage for high toughness and strength of binderless green pellets.  United States.  https://doi.org/10.1111/jace.14982

Copy to clipboard


                    Cannon, W. Roger, Hoggan, Rita E., Erickson, Arnold, Forsmann, Bryan, O'Brien, Robert C., and Lessing, Paul A. Thu .  
"Controlled relative humidity storage for high toughness and strength of binderless green pellets".  United States.  https://doi.org/10.1111/jace.14982.  https://www.osti.gov/servlets/purl/1398255.

Copy to clipboard


                    
@article{osti_1398255,

  title        = {Controlled relative humidity storage for high toughness and strength of binderless green pellets},

  author       = {Cannon, W. Roger and Hoggan, Rita E. and Erickson, Arnold and Forsmann, Bryan and O'Brien, Robert C. and Lessing, Paul A.},

  abstractNote = {Here, an equation was developed to predict fracture toughness of green powder compacts. The model combines crack tip toughness predicted by Kendall's model with crack tip shielding due to bridging of moisture meniscuses across the crack. The model predicts that crack tip shielding due to moisture should be dominant. Fracture tests on ceria green pellets verified that storing pellets at a high relative humidity (98% RH) for an extended period of time led to fracture strength more than double those stored at lower RH. However, at lower RH there is no significant increase in fracture strength with increased RH as predicted by the model. The lower strength at low RH is due to insufficient capillary and surface forces but may also be related to the lack of sufficient adsorbed moisture to form bridging meniscuses. The high green strengths achieved by storing pellets at a high RH suggest a method of strengthening green parts without adding binder.},

  doi          = {10.1111/jace.14982},

  journal      = {Journal of the American Ceramic Society},

  number       = 10,

  volume       = 100,

  place        = {United States},

  year         = {Thu May 18 00:00:00 EDT 2017},

  month        = {Thu May 18 00:00:00 EDT 2017}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1111/jace.14982

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Crack Model for Toughness of Green Parts with Moisture or a Fluid Binder
journal, July 2012

Cannon, W. Roger; Lessing, Paul A.; Zuck, Larry D.
Journal of the American Ceramic Society, Vol. 95, Issue 9
DOI: 10.1111/j.1551-2916.2012.05369.x

Effect of Moisture on the Structure and Fracture Strength of Ceramic Green Bodies
journal, December 1994

Tanaka, Hiroshi; Fukai, Seiki; Uchida, Nozomu
Journal of the American Ceramic Society, Vol. 77, Issue 12
DOI: 10.1111/j.1151-2916.1994.tb04551.x

A Theoretical Study of the Liquid Bridge Forces between Two Rigid Spherical Bodies
journal, November 1993

Lian, Guoping; Thornton, Colin; Adams, Michael J.
Journal of Colloid and Interface Science, Vol. 161, Issue 1
DOI: 10.1006/jcis.1993.1452

Fracture mechanics of green products
journal, January 1993

Bortzmeyer, D.; Langguth, G.; Orange, G.
Journal of the European Ceramic Society, Vol. 11, Issue 1
DOI: 10.1016/0955-2219(93)90053-T

Dry bag isostatic pressing for improved green strength of surrogate nuclear fuel pellets
journal, November 2010

Egeland, G. W.; Zuck, L. D.; Cannon, W. R.
Journal of Nuclear Materials, Vol. 406, Issue 2
DOI: 10.1016/j.jnucmat.2010.08.022

Formation mechanisms of processing defects and their relevance to the strength in alumina ceramics made by powder compaction process
journal, January 1999

Shinohara, N.; Okumiya, M.; Hotta, T.
Journal of Materials Science, Vol. 34, Issue 17, p. 4271-4277
DOI: 10.1023/A:1004611105281

Green strength testing of pressed compacts: An analysis of the different methods
journal, January 2008

Amorós, J. L.; Cantavella, V.; Jarque, J. C.
Journal of the European Ceramic Society, Vol. 28, Issue 4
DOI: 10.1016/j.jeurceramsoc.2007.09.040

Green strength of binder-free ceramics
journal, May 2013

Pizette, Patrick; Martin, Christophe L.; Delette, Gérard
Journal of the European Ceramic Society, Vol. 33, Issue 5
DOI: 10.1016/j.jeurceramsoc.2012.11.018

Mechanical Properties of Dry-Pressed Ceramic Green Products: The Effect of the Binder
journal, August 1997

Baklouti, Samir; Chartier, Thierry; Baumard, Jean François
Journal of the American Ceramic Society, Vol. 80, Issue 8
DOI: 10.1111/j.1151-2916.1997.tb03082.x

Effect of Relative Humidity on the Viscoelastic and Mechanical Properties of Spray-Dried Powder Compacts
journal, April 2006

Uppalapati, Maruti; Green, David J.
Journal of the American Ceramic Society, Vol. 89, Issue 4
DOI: 10.1111/j.1551-2916.2005.00875.x

Strength of Green Ceramics with Low Binder Content
journal, December 2001

Uhland, Scott A.; Holman, Richard K.; Morissette, Sherry
Journal of the American Ceramic Society, Vol. 84, Issue 12
DOI: 10.1111/j.1151-2916.2001.tb01098.x

Modeling Time-Dependent Forces on Liquid Bridge Interactions Between Dissimilar Particles
journal, January 2008

Gopalkrishnana, P.; Manas-Zloczower, I.; Feke, D. L.
Advanced Powder Technology, Vol. 19, Issue 3
DOI: 10.1163/156855208X294636

Mechanical Properties of Dry-Pressed Powder Compacts: Case Study on Alumina Nanoparticles
journal, August 2006

Kounga Njiwa, A. B.; Aulbach, E.; Rodel, J.
Journal of the American Ceramic Society, Vol. 89, Issue 8
DOI: 10.1111/j.1551-2916.2006.01088.x

Similar Records in DOE PAGES and OSTI.GOV collections:

Crack model for toughness of green parts with moisture or a fluid binder

Journal Article Cannon, W Roger ; Lessing, Paul A ; Zuck, Larry D - Journal of American Ceramic Society

A model is presented to predict the toughness, KIC, of green ceramics based on the binding forces of meniscuses formed between particles near the tip of the critical flaw. The model considers capillary pressure, surface tension and the viscous flow of binder. Calculations were determined for moisture only but the model can also be applied to binder meniscuses. Capillary pressure is highest at low moisture content. By using well established force distance relationships for the meniscus between single particles, toughness was determined as a function of moisture content. For non-agglomerated particles, KIC increases with moisture content and decreases with contactmore »« less
https://doi.org/10.1111/j.1551-2916.2012.05369.x
On the fracture toughness of advanced materials

Journal Article Launey, Maximilien E ; Ritchie, Robert O - Advanced Materials

Few engineering materials are limited by their strength; rather they are limited by their resistance to fracture or fracture toughness. It is not by accident that most critical structures, such as bridges, ships, nuclear pressure vessels and so forth, are manufactured from materials that are comparatively low in strength but high in toughness. Indeed, in many classes of materials, strength and toughness are almost mutually exclusive. In the first instance, such resistance to fracture is a function of bonding and crystal structure (or lack thereof), but can be developed through the design of appropriate nano/microstructures. However, the creation of toughmore »« less
Full Text Available
Simulating Dynamic Fracture in Oxide Fuel Pellets Using Cohesive Zone Models

Conference Williamson, R L

It is well known that oxide fuels crack during the first rise to power, with continued fracture occurring during steady operation and especially during power ramps or accidental transients. Fractures have a very strong influence on the stress state in the fuel which, in turn, drives critical phenomena such as fission gas release, fuel creep, and eventual fuel/clad mechanical interaction. Recently, interest has been expressed in discrete fracture methods, such as the cohesive zone approach. Such models are attractive from a mechanistic and physical standpoint, since they reflect the localized nature of cracking. The precise locations where fractures initiate, asmore »« less
Full Text Available
Elevated temperature fracture toughness of Al-Cu-Mg-Ag sheet: Characterization and modeling

Journal Article Haynes, M J ; Gangloff, R P - Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science

The plane-strain initiation fracture toughness (K{sub JlCi}) and plane-stress crack growth resistance of two Al-Cu-Mg-Ag alloy sheets are characterized as a function of temperature by a J-integral method. For AA2519 + Mg + Ag, K{sub JlCi} decreases from 32.5 MPa {radical}m at 250 C to 28.5 MPa {radical}m at 175 C, while K{sub JlCi} for a lower Cu variant increases from 34.2 MPa {radical}m at 25 C to 36.0 Mpa {radical}m at 150 C. Crack-tip damage in AA2519 + Mg + Ag evolves by nucleation and growth of voids from large undissolved Al{sub 2}Cu particles, but fracture resistance is controlledmore »« less
https://doi.org/10.1007/s11661-997-0112-8
Fracture toughness evaluations for spent nuclear fuel dry storage canister welds and spent nuclear fuel clad-pellet structures

Technical Report Wang, Jy-An John ; Bevard, Bruce Balkcom ; Scaglione, John M. ; ...

Integrity of spent nuclear fuel (SNF) interim storage canisters is very important to the safety of the back-end nuclear fuel cycle. Stress corrosion cracking (SCC) potential of interim storage canister has been considered as a high priority. Because no post-weld heat treatment was required for forming these canisters, the high tensile residual stress existed within these canister welds. This can change the fracture resistance capacity significantly as well as increase SCC potential. Due to relative thin shell thickness of a canister weldment, the spiral notch torsion test (SNTT) method was used to estimate the canister weldment fracture toughness. SNTT was developed to measure the intrinsic fracture toughness of structural materials using small specimens. The SNTT method has been applied to a wide variety of structural materials, such as low-alloy steels, stainless steel, aluminum alloy, ceramics, concrete, and composites. The SNTT system operates by applying pure torsion to cylindrical specimens with a notch line that spirals around the specimen at a 45° pitch. In order to carry out pure torsion load mode, biaxial tension/torsion tester was developed accordingly to perform SNTT protocol. Moreover, applying fracture mechanics approach to SNF system reliability investigation is warranted due to the inherent flaws and hydride structures existed in a SNF system after nuclear reactor operation. However, none of the existing fracture toughness data deal with fuel cladding specific geometry or spent fuel material conditions, such as cladding structure with the pellet-inserts and the associated pellet clad mechanical interactions induced mixed-mode damage mechanisms. Thus, the development of an intrinsic fracture mechanics approach that is suitable for SNF materials is needed. Furthermore, due to thin wall and small dimension of clad tubing structure, the SNTT method was used to estimate the clad tubing structure fracture toughness. Fracture testing were performed on the received stainless steel canister weldment, most SNTT weld samples fracture initiation sites are at heat-affected zone (HAZ) regions. The estimated fracture toughness J_Q’ for the baseline SS304 steel is at 283 kJ/m². The estimated JQ’ for the SS304/308 weld and baseline metals are 148 kJ/m² and 459 kJ/m², respectively. Out of cell fracture testing for spent fuel structure were carried out on the surrogate rods made of Zr-4 clad and alumina inserts, the estimated fracture toughness values for baseline Zr-4 cladding with alumina-pellet inserts are: (1) For SNTT samples with a short or medium crack length, between 5.4-mm and 8-mm, the estimate J_IQ upon fracture initiation for the baseline Zr-4 cladding is at 50 kJ/m² with 2-sigma uncertainty of 3.26 kJ/m², and the associated K_IQ is at 67.46 MPamore »« less
https://doi.org/10.2172/1782033

Full Text Available

Similar Records

Title: Controlled relative humidity storage for high toughness and strength of binderless green pellets

Abstract

Citation Formats

Crack Model for Toughness of Green Parts with Moisture or a Fluid Binder journal, July 2012

Effect of Moisture on the Structure and Fracture Strength of Ceramic Green Bodies journal, December 1994

A Theoretical Study of the Liquid Bridge Forces between Two Rigid Spherical Bodies journal, November 1993

Fracture mechanics of green products journal, January 1993

Dry bag isostatic pressing for improved green strength of surrogate nuclear fuel pellets journal, November 2010

Formation mechanisms of processing defects and their relevance to the strength in alumina ceramics made by powder compaction process journal, January 1999

Green strength testing of pressed compacts: An analysis of the different methods journal, January 2008

Green strength of binder-free ceramics journal, May 2013

Mechanical Properties of Dry-Pressed Ceramic Green Products: The Effect of the Binder journal, August 1997

Effect of Relative Humidity on the Viscoelastic and Mechanical Properties of Spray-Dried Powder Compacts journal, April 2006

Strength of Green Ceramics with Low Binder Content journal, December 2001

Modeling Time-Dependent Forces on Liquid Bridge Interactions Between Dissimilar Particles journal, January 2008

Mechanical Properties of Dry-Pressed Powder Compacts: Case Study on Alumina Nanoparticles journal, August 2006

Crack Model for Toughness of Green Parts with Moisture or a Fluid Binder
journal, July 2012

Effect of Moisture on the Structure and Fracture Strength of Ceramic Green Bodies
journal, December 1994

A Theoretical Study of the Liquid Bridge Forces between Two Rigid Spherical Bodies
journal, November 1993

Fracture mechanics of green products
journal, January 1993

Dry bag isostatic pressing for improved green strength of surrogate nuclear fuel pellets
journal, November 2010

Formation mechanisms of processing defects and their relevance to the strength in alumina ceramics made by powder compaction process
journal, January 1999

Green strength testing of pressed compacts: An analysis of the different methods
journal, January 2008

Green strength of binder-free ceramics
journal, May 2013

Mechanical Properties of Dry-Pressed Ceramic Green Products: The Effect of the Binder
journal, August 1997

Effect of Relative Humidity on the Viscoelastic and Mechanical Properties of Spray-Dried Powder Compacts
journal, April 2006

Strength of Green Ceramics with Low Binder Content
journal, December 2001

Modeling Time-Dependent Forces on Liquid Bridge Interactions Between Dissimilar Particles
journal, January 2008

Mechanical Properties of Dry-Pressed Powder Compacts: Case Study on Alumina Nanoparticles
journal, August 2006