Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures

Ishmael, Mitchell P. E.; Lukawski, Maciej Z.; Tester, Jefferson W.

doi:10.1016/j.supflu.2016.05.016

Title: Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures

Authors:

Ishmael, Mitchell P. E.;

; Tester, Jefferson W.

Publication Date:: Tue Nov 01 00:00:00 EDT 2016

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1397449

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Supercritical Fluids

Additional Journal Information:: Journal Name: Journal of Supercritical Fluids Journal Volume: 117 Journal Issue: C; Journal ID: ISSN 0896-8446

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Ishmael, Mitchell P. E., Lukawski, Maciej Z., and Tester, Jefferson W. Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures.  United States: N. p., 2016. 
Web.  doi:10.1016/j.supflu.2016.05.016.

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                    Ishmael, Mitchell P. E., Lukawski, Maciej Z., & Tester, Jefferson W. Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures.  United States.  https://doi.org/10.1016/j.supflu.2016.05.016

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                    Ishmael, Mitchell P. E., Lukawski, Maciej Z., and Tester, Jefferson W. Tue .  
"Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures".  United States.  https://doi.org/10.1016/j.supflu.2016.05.016.

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@article{osti_1397449,

  title        = {Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures},

  author       = {Ishmael, Mitchell P. E. and Lukawski, Maciej Z. and Tester, Jefferson W.},

  abstractNote = {},

  doi          = {10.1016/j.supflu.2016.05.016},

  journal      = {Journal of Supercritical Fluids},

  number       = C,

  volume       = 117,

  place        = {United States},

  year         = {Tue Nov 01 00:00:00 EDT 2016},

  month        = {Tue Nov 01 00:00:00 EDT 2016}

}

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https://doi.org/10.1016/j.supflu.2016.05.016

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Works referenced in this record:

High-pressure isobaric heat capacities using a new flow calorimeter
journal, October 2008

Segovia, José J.; Vega-Maza, David; Chamorro, César R.
The Journal of Supercritical Fluids, Vol. 46, Issue 3
DOI: 10.1016/j.supflu.2008.01.011

Measurements of isobaric heat capacities of gases from 323.15 to 573.15 K up to 30 MPa
journal, October 1994

Dordain, L.; Coxam, J. -Y.; Grolier, J. -P. E.
Review of Scientific Instruments, Vol. 65, Issue 10
DOI: 10.1063/1.1144560

A new high-pressure recycle-flow calorimeter and results of determinations with ethane
journal, February 1980

Miyazaki, T.; Hejmadi, A. V.; Powers, J. E.
The Journal of Chemical Thermodynamics, Vol. 12, Issue 2
DOI: 10.1016/0021-9614(80)90122-6

Measurement of the isobaric heat capacity of liquids and certain mixtures above the normal boiling point
journal, October 1976

San Jose, Juan L.; Mellinger, Gary; Reid, Robert C.
Journal of Chemical & Engineering Data, Vol. 21, Issue 4
DOI: 10.1021/je60071a022

Heat capacity of aqueous sodium chloride from 320 to 600 K measured with a new flow calorimeter
journal, November 1981

Smith-Magowan, David; Wood, Robert H.
The Journal of Chemical Thermodynamics, Vol. 13, Issue 11
DOI: 10.1016/0021-9614(81)90004-5

A new apparatus for the measurement of the isobaric heat capacity of liquid refrigerants
journal, May 1989

Saitoh, A.; Sato, H.; Watanabe, K.
International Journal of Thermophysics, Vol. 10, Issue 3
DOI: 10.1007/BF00507986

The Joule—Thomson effect and the specific heat at constant pressure of carbon dioxide
journal, May 1948

de Groot, S. R.; Michels, A.
Physica, Vol. 14, Issue 4
DOI: 10.1016/0031-8914(48)90039-1

The Zeno (Z = 1) Behavior of Equations of State: An Interpretation across Scales from Macroscopic to Molecular
journal, September 2000

Kutney, Michael C.; Reagan, Matthew T.; Smith, Kenneth A.
The Journal of Physical Chemistry B, Vol. 104, Issue 40
DOI: 10.1021/jp001344e

A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa
journal, November 1996

Span, Roland; Wagner, Wolfgang
Journal of Physical and Chemical Reference Data, Vol. 25, Issue 6
DOI: 10.1063/1.555991

Supercritical and near-critical CO2 in green chemical synthesis and processing
journal, March 2004

Beckman, Eric J.
The Journal of Supercritical Fluids, Vol. 28, Issue 2-3
DOI: 10.1016/S0896-8446(03)00029-9

Flow calorimeter for the accurate determination of the isobaric heat capacity at high pressures; results for carbon dioxide
journal, January 1989

Ernst, G.; Maurer, G.; Wiederuh, E.
The Journal of Chemical Thermodynamics, Vol. 21, Issue 1
DOI: 10.1016/0021-9614(89)90007-4

Heat loss corrections for heat capacity flow calorimeters
journal, August 1988

White, D. Rod; Downes, Colin J.
Journal of Solution Chemistry, Vol. 17, Issue 8
DOI: 10.1007/BF00647419

The constant pressure heat capacity of supercritical carbon dioxide-methanol and carbon dioxide-ethanol co-solvent mixtures
journal, November 1993

Boulton, James R.; Stein, Fred P.
Fluid Phase Equilibria, Vol. 91, Issue 1
DOI: 10.1016/0378-3812(93)85086-2

Flow-calorimetric results for the specific heat capacity cp of CO2, of C2H6, and of (0.5CO2 + 0.5C2H6) at high pressures
journal, April 1989

Ernst, G.; Hochberg, U. E.
The Journal of Chemical Thermodynamics, Vol. 21, Issue 4
DOI: 10.1016/0021-9614(89)90141-9

Critical Properties of Carbon Dioxide + Methanol, + Ethanol, + 1-Propanol, and + 1-Butanol
journal, August 2000

Yeo, Sang-Do; Park, Su-Jin; Kim, Jin-Woo
Journal of Chemical & Engineering Data, Vol. 45, Issue 5
DOI: 10.1021/je000104p

Specific Heat Capacity at Constant Pressure of Ethanol by Flow Calorimetry
journal, May 2012

Miyazawa, Taishi; Kondo, Satoshi; Suzuki, Takuya
Journal of Chemical & Engineering Data, Vol. 57, Issue 6
DOI: 10.1021/je2013473

High-temperature thermodynamic properties of aqueous sodium sulfate solutions
journal, October 1981

Rogers, P. S. Z.; Pitzer, Kenneth S.
The Journal of Physical Chemistry, Vol. 85, Issue 20
DOI: 10.1021/j150620a008

Thermodynamic properties of methanol from 288 to 503 K and at 8.3 MPa
journal, October 1988

Boyette, Scott; Criss, Cecil M.
Journal of Chemical & Engineering Data, Vol. 33, Issue 4
DOI: 10.1021/je00054a011

Flow-calorimetric results for the specific heat capacity cp of water at pressures between 20 and 50 MPa and temperatures between 298.15 and 673.15 K
journal, February 1990

Ernst, G.; Philippi, R.
The Journal of Chemical Thermodynamics, Vol. 22, Issue 2
DOI: 10.1016/0021-9614(90)90085-5

Measurement of isobaric heat capacity of pure water up to supercritical conditions
journal, May 2015

He, Maogang; Su, Chao; Liu, Xiangyang
The Journal of Supercritical Fluids, Vol. 100
DOI: 10.1016/j.supflu.2015.02.007

Phase equilibria for supercritical fluid process design
journal, September 1989

Brennecke, Joan F.; Eckert, Charles A.
AIChE Journal, Vol. 35, Issue 9
DOI: 10.1002/aic.690350902

The GERG-2008 Wide-Range Equation of State for Natural Gases and Other Mixtures: An Expansion of GERG-2004
journal, October 2012

Kunz, O.; Wagner, W.
Journal of Chemical & Engineering Data, Vol. 57, Issue 11
DOI: 10.1021/je300655b

Isobaric heat capacity measurements of liquid HFE-7200 and HFE-7500 from 245 to 353K at pressures up to 15MPa
journal, June 2014

Zheng, Yuxin; Gao, Hui; Chen, Qiang
Fluid Phase Equilibria, Vol. 372
DOI: 10.1016/j.fluid.2014.03.017

Flow-calorimetric results for the massic heat capacitycpand the Joule–Thomson coefficient of CH4, of (0.85CH4+0.15C2H6), and of a mixture similar to natural gas
journal, June 2001

Ernst,, G.; Keil,, B.; Wirbser, H.
The Journal of Chemical Thermodynamics, Vol. 33, Issue 6
DOI: 10.1006/jcht.2000.0740

An automated flow calorimeter for the determination of liquid and vapor isobaric heat capacities: Test results for water and n-pentane
journal, February 1992

Sandarusi, Jamal A.; Mulia, Kamarza; Yesavage, Victor F.
Review of Scientific Instruments, Vol. 63, Issue 2
DOI: 10.1063/1.1143342

A new flow calorimeter for the determination of the isobaric heat capacity of vapors
journal, April 1995

Wu, Youting; Yu, Qingsen; Zhong, Hanxing
Thermochimica Acta, Vol. 254
DOI: 10.1016/0040-6031(94)02064-U

Crossing the Widom-line – Supercritical pseudo-boiling
journal, March 2015

Banuti, D. T.
The Journal of Supercritical Fluids, Vol. 98
DOI: 10.1016/j.supflu.2014.12.019

Heat capacities of some organic liquids determined with the Picker flow calorimeter
journal, March 1976

Fortier, Jean-Luc; Benson, George C.; Picker, Patrick
The Journal of Chemical Thermodynamics, Vol. 8, Issue 3
DOI: 10.1016/0021-9614(76)90108-7

Critical Properties of Binary and Ternary Mixtures of Hexane + Methanol, Hexane + Carbon Dioxide, Methanol + Carbon Dioxide, and Hexane + Carbon Dioxide + Methanol
journal, October 2003

Liu, Jianguo; Qin, Zhangfeng; Wang, Guofu
Journal of Chemical & Engineering Data, Vol. 48, Issue 6
DOI: 10.1021/je034127q

Heat capacity of solutions by flow microcalorimetry
journal, September 1971

Picker, Patrick; Leduc, Paul-André; Philip, Patrick R.
The Journal of Chemical Thermodynamics, Vol. 3, Issue 5
DOI: 10.1016/S0021-9614(71)80084-8

Widom Line for the Liquid–Gas Transition in Lennard-Jones System
journal, December 2011

Brazhkin, V. V.; Fomin, Yu. D.; Lyapin, A. G.
The Journal of Physical Chemistry B, Vol. 115, Issue 48
DOI: 10.1021/jp2039898

A New Method of Measuring the Variation of the Specific Heats (cp) of Gases with Pressure
journal, September 1930

Workman, E. J.
Physical Review, Vol. 36, Issue 6
DOI: 10.1103/PhysRev.36.1083

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Similar Records

Title: Isobaric heat capacity (Cp) measurements of supercritical fluids using flow calorimetry: equipment design and experimental validation with carbon dioxide, methanol, and carbon dioxide-methanol mixtures

Citation Formats

High-pressure isobaric heat capacities using a new flow calorimeter journal, October 2008

Measurements of isobaric heat capacities of gases from 323.15 to 573.15 K up to 30 MPa journal, October 1994

A new high-pressure recycle-flow calorimeter and results of determinations with ethane journal, February 1980

Measurement of the isobaric heat capacity of liquids and certain mixtures above the normal boiling point journal, October 1976

Heat capacity of aqueous sodium chloride from 320 to 600 K measured with a new flow calorimeter journal, November 1981

A new apparatus for the measurement of the isobaric heat capacity of liquid refrigerants journal, May 1989

The Joule—Thomson effect and the specific heat at constant pressure of carbon dioxide journal, May 1948

The Zeno (Z = 1) Behavior of Equations of State: An Interpretation across Scales from Macroscopic to Molecular journal, September 2000

A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa journal, November 1996

Supercritical and near-critical CO2 in green chemical synthesis and processing journal, March 2004

Flow calorimeter for the accurate determination of the isobaric heat capacity at high pressures; results for carbon dioxide journal, January 1989

Heat loss corrections for heat capacity flow calorimeters journal, August 1988

The constant pressure heat capacity of supercritical carbon dioxide-methanol and carbon dioxide-ethanol co-solvent mixtures journal, November 1993

Flow-calorimetric results for the specific heat capacity cp of CO2, of C2H6, and of (0.5CO2 + 0.5C2H6) at high pressures journal, April 1989

Critical Properties of Carbon Dioxide + Methanol, + Ethanol, + 1-Propanol, and + 1-Butanol journal, August 2000

Specific Heat Capacity at Constant Pressure of Ethanol by Flow Calorimetry journal, May 2012

High-temperature thermodynamic properties of aqueous sodium sulfate solutions journal, October 1981

Thermodynamic properties of methanol from 288 to 503 K and at 8.3 MPa journal, October 1988

Flow-calorimetric results for the specific heat capacity cp of water at pressures between 20 and 50 MPa and temperatures between 298.15 and 673.15 K journal, February 1990

Measurement of isobaric heat capacity of pure water up to supercritical conditions journal, May 2015

Phase equilibria for supercritical fluid process design journal, September 1989

The GERG-2008 Wide-Range Equation of State for Natural Gases and Other Mixtures: An Expansion of GERG-2004 journal, October 2012

Isobaric heat capacity measurements of liquid HFE-7200 and HFE-7500 from 245 to 353K at pressures up to 15MPa journal, June 2014

Flow-calorimetric results for the massic heat capacitycpand the Joule–Thomson coefficient of CH4, of (0.85CH4+0.15C2H6), and of a mixture similar to natural gas journal, June 2001

An automated flow calorimeter for the determination of liquid and vapor isobaric heat capacities: Test results for water and n-pentane journal, February 1992

A new flow calorimeter for the determination of the isobaric heat capacity of vapors journal, April 1995

Crossing the Widom-line – Supercritical pseudo-boiling journal, March 2015

Heat capacities of some organic liquids determined with the Picker flow calorimeter journal, March 1976

Critical Properties of Binary and Ternary Mixtures of Hexane + Methanol, Hexane + Carbon Dioxide, Methanol + Carbon Dioxide, and Hexane + Carbon Dioxide + Methanol journal, October 2003

Heat capacity of solutions by flow microcalorimetry journal, September 1971

Widom Line for the Liquid–Gas Transition in Lennard-Jones System journal, December 2011

A New Method of Measuring the Variation of the Specific Heats (cp) of Gases with Pressure journal, September 1930

High-pressure isobaric heat capacities using a new flow calorimeter
journal, October 2008

Measurements of isobaric heat capacities of gases from 323.15 to 573.15 K up to 30 MPa
journal, October 1994

A new high-pressure recycle-flow calorimeter and results of determinations with ethane
journal, February 1980

Measurement of the isobaric heat capacity of liquids and certain mixtures above the normal boiling point
journal, October 1976

Heat capacity of aqueous sodium chloride from 320 to 600 K measured with a new flow calorimeter
journal, November 1981

A new apparatus for the measurement of the isobaric heat capacity of liquid refrigerants
journal, May 1989

The Joule—Thomson effect and the specific heat at constant pressure of carbon dioxide
journal, May 1948

The Zeno (Z = 1) Behavior of Equations of State: An Interpretation across Scales from Macroscopic to Molecular
journal, September 2000

A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa
journal, November 1996

Supercritical and near-critical CO2 in green chemical synthesis and processing
journal, March 2004

Flow calorimeter for the accurate determination of the isobaric heat capacity at high pressures; results for carbon dioxide
journal, January 1989

Heat loss corrections for heat capacity flow calorimeters
journal, August 1988

The constant pressure heat capacity of supercritical carbon dioxide-methanol and carbon dioxide-ethanol co-solvent mixtures
journal, November 1993

Flow-calorimetric results for the specific heat capacity cp of CO2, of C2H6, and of (0.5CO2 + 0.5C2H6) at high pressures
journal, April 1989

Critical Properties of Carbon Dioxide + Methanol, + Ethanol, + 1-Propanol, and + 1-Butanol
journal, August 2000

Specific Heat Capacity at Constant Pressure of Ethanol by Flow Calorimetry
journal, May 2012

High-temperature thermodynamic properties of aqueous sodium sulfate solutions
journal, October 1981

Thermodynamic properties of methanol from 288 to 503 K and at 8.3 MPa
journal, October 1988

Flow-calorimetric results for the specific heat capacity cp of water at pressures between 20 and 50 MPa and temperatures between 298.15 and 673.15 K
journal, February 1990

Measurement of isobaric heat capacity of pure water up to supercritical conditions
journal, May 2015

Phase equilibria for supercritical fluid process design
journal, September 1989

The GERG-2008 Wide-Range Equation of State for Natural Gases and Other Mixtures: An Expansion of GERG-2004
journal, October 2012

Isobaric heat capacity measurements of liquid HFE-7200 and HFE-7500 from 245 to 353K at pressures up to 15MPa
journal, June 2014

Flow-calorimetric results for the massic heat capacitycpand the Joule–Thomson coefficient of CH4, of (0.85CH4+0.15C2H6), and of a mixture similar to natural gas
journal, June 2001

An automated flow calorimeter for the determination of liquid and vapor isobaric heat capacities: Test results for water and n-pentane
journal, February 1992

A new flow calorimeter for the determination of the isobaric heat capacity of vapors
journal, April 1995

Crossing the Widom-line – Supercritical pseudo-boiling
journal, March 2015

Heat capacities of some organic liquids determined with the Picker flow calorimeter
journal, March 1976

Critical Properties of Binary and Ternary Mixtures of Hexane + Methanol, Hexane + Carbon Dioxide, Methanol + Carbon Dioxide, and Hexane + Carbon Dioxide + Methanol
journal, October 2003

Heat capacity of solutions by flow microcalorimetry
journal, September 1971

Widom Line for the Liquid–Gas Transition in Lennard-Jones System
journal, December 2011

A New Method of Measuring the Variation of the Specific Heats (cp) of Gases with Pressure
journal, September 1930