Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures

Papandrew, A; Elgammal, Ramez A.; Tian, Mengkun; Tennyson, Wesley D.; Rouleau, Christopher; Puretzky, Alexander; Veith, Gabriel; Geohegan, David; Zawodzinski, Thomas

doi:10.1016/j.jpowsour.2016.10.093

Title: Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures

Authors:

Papandrew, A ^[1]; Elgammal, Ramez A. ^[2];

^[2];

^[3];

^[3]; Zawodzinski, Thomas ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Thu Nov 03 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1607314

Alternate Identifier(s):: OSTI ID: 1397390

Grant/Contract Number:: AC05-00OR22725; AR0000499

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Volume: 337; Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; CsH2PO4; carbon nanotubes; carbon nanohorns; fuel cells

Citation Formats


                    Papandrew, A, Elgammal, Ramez A., Tian, Mengkun, Tennyson, Wesley D., Rouleau, Christopher, Puretzky, Alexander, Veith, Gabriel, Geohegan, David, and Zawodzinski, Thomas. Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures.  United States: N. p., 2016. 
Web.  doi:10.1016/j.jpowsour.2016.10.093.

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                    Papandrew, A, Elgammal, Ramez A., Tian, Mengkun, Tennyson, Wesley D., Rouleau, Christopher, Puretzky, Alexander, Veith, Gabriel, Geohegan, David, & Zawodzinski, Thomas. Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures.  United States.  https://doi.org/10.1016/j.jpowsour.2016.10.093

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                    Papandrew, A, Elgammal, Ramez A., Tian, Mengkun, Tennyson, Wesley D., Rouleau, Christopher, Puretzky, Alexander, Veith, Gabriel, Geohegan, David, and Zawodzinski, Thomas. Thu .  
"Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures".  United States.  https://doi.org/10.1016/j.jpowsour.2016.10.093.  https://www.osti.gov/servlets/purl/1607314.

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@article{osti_1607314,

  title        = {Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures},

  author       = {Papandrew, A and Elgammal, Ramez A. and Tian, Mengkun and Tennyson, Wesley D. and Rouleau, Christopher and Puretzky, Alexander and Veith, Gabriel and Geohegan, David and Zawodzinski, Thomas},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2016.10.093},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 337,

  place        = {United States},

  year         = {Thu Nov 03 00:00:00 EDT 2016},

  month        = {Thu Nov 03 00:00:00 EDT 2016}

}

Copy to clipboard

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https://doi.org/10.1016/j.jpowsour.2016.10.093

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Works referenced in this record:

Solid acid proton conductors: from laboratory curiosities to fuel cell electrolytes
journal, January 2007

Haile, Sossina M.; Chisholm, Calum R. I.; Sasaki, Kenji
Faraday Discuss., Vol. 134
DOI: 10.1039/B604311A

High-Performance Solid Acid Fuel Cells Through Humidity Stabilization
journal, January 2004

Boysen, D. A.
Science, Vol. 303, Issue 5654
DOI: 10.1126/science.1090920

From Laboratory Breakthrough to Technological Realization: The Development Path for Solid Acid Fuel Cells
journal, September 2009

Boysen, Dane A.; Cha, Sukyal; Chisholm, Calum R. I.
The Electrochemical Society Interface, Vol. 18, Issue 3
DOI: 10.1149/2.F06093IF

Electrochemical Hydrogen Separation via Solid Acid Membranes
journal, January 2014

Papandrew, Alexander B.; Wilson, David L.; M. Cantillo, Nelly
Journal of The Electrochemical Society, Vol. 161, Issue 5
DOI: 10.1149/2.078405jes

Ruthenium as a CO-tolerant hydrogen oxidation catalyst for solid acid fuel cells
journal, January 2015

Papandrew, Alexander B.; Atkinson III, Robert W.; Unocic, Raymond R.
Journal of Materials Chemistry A, Vol. 3, Issue 7
DOI: 10.1039/C4TA06451H

Advanced Electrodes for Solid Acid Fuel Cells by Platinum Deposition on CsH ₂ PO ₄
journal, April 2011

Papandrew, Alexander B.; Chisholm, Calum R. I.; Elgammal, Ramez A.
Chemistry of Materials, Vol. 23, Issue 7
DOI: 10.1021/cm101147y

Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells
journal, December 2012

Papandrew, Alexander B.; Chisholm, Calum R. I.; Zecevic, Strahinja K.
Journal of The Electrochemical Society, Vol. 160, Issue 2
DOI: 10.1149/2.002303jes

Electrochemical oxidation of carbon black in concentrated phosphoric acid at 135°C
journal, June 1973

Kinoshita, K.; Bett, J.
Carbon, Vol. 11, Issue 3
DOI: 10.1016/0008-6223(73)90026-2

Carbon supports for phosphoric acid fuel cell electrocatalysts: alternative materials and methods of evaluation
journal, November 1981

McBreen, J.; Olender, H.; Srinivasan, S.
Journal of Applied Electrochemistry, Vol. 11, Issue 6
DOI: 10.1007/BF00615184

Carbon substrates for phosphoric acid fuel cell cathodes
journal, January 1984

Stonehart, P.
Carbon, Vol. 22, Issue 4-5
DOI: 10.1016/0008-6223(84)90015-0

Electrochemical corrosion behavior of carbon black in phosphoric acid
journal, January 1988

Antonucci, P. L.; Romeo, F.; Minutoli, M.
Carbon, Vol. 26, Issue 2
DOI: 10.1016/0008-6223(88)90037-1

The influence of Pt on the electrooxidation behaviour of carbon in phosphoric acid
journal, December 1992

Passalacqua, E.; Antonucci, P. L.; Vivaldi, M.
Electrochimica Acta, Vol. 37, Issue 15
DOI: 10.1016/0013-4686(92)85199-U

Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes
journal, January 2004

Roen, L. M.; Paik, C. H.; Jarvi, T. D.
Electrochemical and Solid-State Letters, Vol. 7, Issue 1
DOI: 10.1149/1.1630412

Carbon support oxidation in PEM fuel cell cathodes
journal, February 2008

Maass, S.; Finsterwalder, F.; Frank, G.
Journal of Power Sources, Vol. 176, Issue 2
DOI: 10.1016/j.jpowsour.2007.08.053

Electrochemical carbon corrosion in high temperature proton exchange membrane fuel cells
journal, July 2012

Oh, Hyung-Suk; Lee, Jin-Hee; Kim, Hansung
International Journal of Hydrogen Energy, Vol. 37, Issue 14
DOI: 10.1016/j.ijhydene.2012.04.095

Microstructure effects on the electrochemical corrosion of carbon materials and carbon-supported Pt catalysts
journal, December 2010

Cherstiouk, O. V.; Simonov, A. N.; Moseva, N. S.
Electrochimica Acta, Vol. 55, Issue 28
DOI: 10.1016/j.electacta.2010.07.047

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: From Model Experiments to Real-Life Operation in Membrane Electrode Assemblies
journal, May 2014

Castanheira, Luis; Dubau, Laetitia; Mermoux, Michel
ACS Catalysis, Vol. 4, Issue 7
DOI: 10.1021/cs500449q

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: Effect of the Carbon Structure, the Degradation Protocol, and the Gas Atmosphere
journal, March 2015

Castanheira, Luis; Silva, Wanderson O.; Lima, Fabio H. B.
ACS Catalysis, Vol. 5, Issue 4
DOI: 10.1021/cs501973j

Durability investigation of carbon nanotube as catalyst support for proton exchange membrane fuel cell
journal, July 2006

Wang, Xin; Li, Wenzhen; Chen, Zhongwei
Journal of Power Sources, Vol. 158, Issue 1
DOI: 10.1016/j.jpowsour.2005.09.039

Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis
journal, March 2006

Lee, Kunchan; Zhang, Jiujun; Wang, Haijiang
Journal of Applied Electrochemistry, Vol. 36, Issue 5
DOI: 10.1007/s10800-006-9120-4

Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
journal, October 2007

Borup, Rod; Meyers, Jeremy; Pivovar, Bryan
Chemical Reviews, Vol. 107, Issue 10
DOI: 10.1021/cr050182l

Fuel cell electrodes using carbon nanostructures
journal, May 2009

Lebert, M.; Kaempgen, M.; Soehn, M.
Catalysis Today, Vol. 143, Issue 1-2
DOI: 10.1016/j.cattod.2008.10.043

Carbon supports for low-temperature fuel cell catalysts
journal, April 2009

Antolini, Ermete
Applied Catalysis B: Environmental, Vol. 88, Issue 1-2
DOI: 10.1016/j.apcatb.2008.09.030

Novel catalyst support materials for PEM fuel cells: current status and future prospects
journal, January 2009

Shao, Yuyan; Liu, Jun; Wang, Yong
Journal of Materials Chemistry, Vol. 19, Issue 1, p. 46-59
DOI: 10.1039/B808370C

Single-Wall Nanohorns as Electrocatalyst Support for High Temperature PEM Fuel Cells
journal, January 2011

Boaventura, M.; Brandão, L.; Mendes, A.
Journal of The Electrochemical Society, Vol. 158, Issue 4
DOI: 10.1149/1.3551495

Use of single wall carbon nanohorns in polymeric electrolyte fuel cells
journal, November 2011

Brandão, Lúcia; Passeira, Carolina; Mirabile Gattia, Daniele
Journal of Materials Science, Vol. 46, Issue 22
DOI: 10.1007/s10853-010-4638-6

Nanostructured catalysts in fuel cells
journal, January 2011

Qiao, Yan; Li, Chang Ming
J. Mater. Chem., Vol. 21, Issue 12
DOI: 10.1039/C0JM02871A

Composite nanostructured solid-acid fuel-cell electrodes via electrospray deposition
journal, January 2010

Varga, Áron; Brunelli, Nicholas A.; Louie, Mary W.
Journal of Materials Chemistry, Vol. 20, Issue 30
DOI: 10.1039/c0jm00216j

Carbon nanotubes as electronic interconnects in solid acid fuel cell electrodes
journal, January 2013

Varga, Áron; Pfohl, Moritz; Brunelli, Nicholas A.
Physical Chemistry Chemical Physics, Vol. 15, Issue 37
DOI: 10.1039/c3cp52586d

Dynamics of single-wall carbon nanotube synthesis by laser vaporization
journal, February 2000

Puretzky, A. A.; Geohegan, D. B.; Fan, X.
Applied Physics A: Materials Science & Processing, Vol. 70, Issue 2
DOI: 10.1007/s003390050027

Cumulative and continuous laser vaporization synthesis of single wall carbon nanotubes and nanohorns
journal, December 2008

Puretzky, A. A.; Styers-Barnett, D. J.; Rouleau, C. M.
Applied Physics A, Vol. 93, Issue 4
DOI: 10.1007/s00339-008-4744-3

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns
journal, November 2012

Liu, Yun; Brown, Craig M.; Neumann, Dan A.
Carbon, Vol. 50, Issue 13
DOI: 10.1016/j.carbon.2012.06.028

Ruthenium-Alloy Electrocatalysts with Tunable Hydrogen Oxidation Kinetics in Alkaline Electrolyte
journal, June 2015

St. John, Samuel; Atkinson, Robert W.; Unocic, Raymond R.
The Journal of Physical Chemistry C, Vol. 119, Issue 24
DOI: 10.1021/acs.jpcc.5b03284

Interlayer spacing anomaly of single-wall carbon nanohorn aggregate
journal, May 2000

Bandow, S.; Kokai, F.; Takahashi, K.
Chemical Physics Letters, Vol. 321, Issue 5-6
DOI: 10.1016/S0009-2614(00)00353-5

Interlayer spacings in carbon nanotubes
journal, July 1993

Saito, Yahachi; Yoshikawa, Tadanobu; Bandow, Shunji
Physical Review B, Vol. 48, Issue 3
DOI: 10.1103/PhysRevB.48.1907

Single-Wall Nanostructured Carbon for Methane Storage
journal, May 2003

Bekyarova, Elena; Murata, Katsuyuki; Yudasaka, Masako
The Journal of Physical Chemistry B, Vol. 107, Issue 20
DOI: 10.1021/jp0278263

Pt Nanoparticle Binding on Functionalized Multiwalled Carbon Nanotubes
journal, March 2006

Hull, Robert V.; Li, Liang; Xing, Yangchuan
Chemistry of Materials, Vol. 18, Issue 7
DOI: 10.1021/cm0518978

Purity assessment of multiwalled carbon nanotubes by Raman spectroscopy
journal, March 2007

DiLeo, Roberta A.; Landi, Brian J.; Raffaelle, Ryne P.
Journal of Applied Physics, Vol. 101, Issue 6
DOI: 10.1063/1.2712152

Characterizing the Structural Degradation in a PEMFC Cathode Catalyst Layer: Carbon Corrosion
journal, January 2009

Young, A. P.; Stumper, J.; Gyenge, E.
Journal of The Electrochemical Society, Vol. 156, Issue 8
DOI: 10.1149/1.3139963

Corrosion resistance and sintering effect of carbon supports in polymer electrolyte membrane fuel cells
journal, November 2009

Oh, Hyung-Suk; Lim, Katie Heeyum; Roh, Bumwook
Electrochimica Acta, Vol. 54, Issue 26, p. 6515-6521
DOI: 10.1016/j.electacta.2009.06.028

Investigation of the corrosion of carbon supports in polymer electrolyte fuel cells using simulated start-up/shutdown cycling
journal, February 2013

Park, Young-Chul; Kakinuma, Katsuyoshi; Uchida, Makoto
Electrochimica Acta, Vol. 91
DOI: 10.1016/j.electacta.2012.12.082

Kinetic Model of Platinum Dissolution in PEMFCs
journal, January 2003

Darling, Robert M.; Meyers, Jeremy P.
Journal of The Electrochemical Society, Vol. 150, Issue 11
DOI: 10.1149/1.1613669

Electrocorrosion properties of multiwall carbon nanotubes: Electrocorrosion properties of multiwall carbon nanotubes
journal, September 2010

Cherstiouk, O. V.; Kuznetsov, V. L.; Simonov, A. N.
physica status solidi (b), Vol. 247, Issue 11-12
DOI: 10.1002/pssb.201000352

Structure-to-property relationships in fuel cell catalyst supports: Correlation of surface chemistry and morphology with oxidation resistance of carbon blacks
journal, September 2012

Artyushkova, Kateryna; Pylypenko, Svitlana; Dowlapalli, Madhu
Journal of Power Sources, Vol. 214
DOI: 10.1016/j.jpowsour.2012.04.095

Direct Evidence on C−C Single Bonding in Single-Wall Carbon Nanohorn Aggregates
journal, April 2007

Utsumi, Shigenori; Honda, Hiroaki; Hattori, Yoshiyuki
The Journal of Physical Chemistry C, Vol. 111, Issue 15
DOI: 10.1021/jp071273k

A Reverse-Current Decay Mechanism for Fuel Cells
journal, January 2005

Reiser, Carl A.; Bregoli, Lawrence; Patterson, Timothy W.
Electrochemical and Solid-State Letters, Vol. 8, Issue 6
DOI: 10.1149/1.1896466

Dehydration behavior of the superprotonic conductor CsH2PO4 at moderate temperatures: 230 to 260 °C
journal, January 2007

Taninouchi, Yu-ki; Uda, Tetsuya; Awakura, Yasuhiro
Journal of Materials Chemistry, Vol. 17, Issue 30
DOI: 10.1039/b704558c

Dehydration of CsH2PO4 at temperatures higher than 260 °C and the ionic conductivity of liquid product
journal, January 2008

Taninouchi, Yu-ki; Uda, Tetsuya; Awakura, Yasuhiro
Solid State Ionics, Vol. 178, Issue 31-32
DOI: 10.1016/j.ssi.2007.10.017

Works referencing / citing this record:

In situ determination of the electrochemically active platinum surface area: key to improvement of solid acid fuel cells
journal, January 2018

Lohmann-Richters, Felix P.; Abel, Bernd; Varga, Áron
Journal of Materials Chemistry A, Vol. 6, Issue 6
DOI: 10.1039/c7ta10110d

Facile and scalable synthesis of sub-micrometer electrolyte particles for solid acid fuel cells
journal, January 2018

Lohmann-Richters, F. P.; Odenwald, C.; Kickelbick, G.
RSC Advances, Vol. 8, Issue 39
DOI: 10.1039/c8ra03293a

Mechanism of ion conductivity through polymer-stabilized CsH ₂ PO ₄ nanoparticular layers from experiment and theory
journal, January 2019

Wagner, Maximilian; Dreßler, Christian; Lohmann-Richters, Felix P.
Journal of Materials Chemistry A, Vol. 7, Issue 48
DOI: 10.1039/c9ta04275j

Facile and scalable synthesis of sub-micrometer electrolyte particles for solid acid fuel cells
collection, January 2018

Lohmann-Richters, Felix Paul; Odenwald, C.; Kickelbick, Guido
Universität des Saarlandes
DOI: 10.22028/d291-30326

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Citation Formats

Solid acid proton conductors: from laboratory curiosities to fuel cell electrolytes journal, January 2007

High-Performance Solid Acid Fuel Cells Through Humidity Stabilization journal, January 2004

From Laboratory Breakthrough to Technological Realization: The Development Path for Solid Acid Fuel Cells journal, September 2009

Electrochemical Hydrogen Separation via Solid Acid Membranes journal, January 2014

Ruthenium as a CO-tolerant hydrogen oxidation catalyst for solid acid fuel cells journal, January 2015

Advanced Electrodes for Solid Acid Fuel Cells by Platinum Deposition on CsH 2 PO 4 journal, April 2011

Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells journal, December 2012

Electrochemical oxidation of carbon black in concentrated phosphoric acid at 135°C journal, June 1973

Carbon supports for phosphoric acid fuel cell electrocatalysts: alternative materials and methods of evaluation journal, November 1981

Carbon substrates for phosphoric acid fuel cell cathodes journal, January 1984

Electrochemical corrosion behavior of carbon black in phosphoric acid journal, January 1988

The influence of Pt on the electrooxidation behaviour of carbon in phosphoric acid journal, December 1992

Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes journal, January 2004

Carbon support oxidation in PEM fuel cell cathodes journal, February 2008

Electrochemical carbon corrosion in high temperature proton exchange membrane fuel cells journal, July 2012

Microstructure effects on the electrochemical corrosion of carbon materials and carbon-supported Pt catalysts journal, December 2010

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: From Model Experiments to Real-Life Operation in Membrane Electrode Assemblies journal, May 2014

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: Effect of the Carbon Structure, the Degradation Protocol, and the Gas Atmosphere journal, March 2015

Durability investigation of carbon nanotube as catalyst support for proton exchange membrane fuel cell journal, July 2006

Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis journal, March 2006

Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation journal, October 2007

Fuel cell electrodes using carbon nanostructures journal, May 2009

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Single-Wall Nanohorns as Electrocatalyst Support for High Temperature PEM Fuel Cells journal, January 2011

Use of single wall carbon nanohorns in polymeric electrolyte fuel cells journal, November 2011

Nanostructured catalysts in fuel cells journal, January 2011

Composite nanostructured solid-acid fuel-cell electrodes via electrospray deposition journal, January 2010

Carbon nanotubes as electronic interconnects in solid acid fuel cell electrodes journal, January 2013

Dynamics of single-wall carbon nanotube synthesis by laser vaporization journal, February 2000

Cumulative and continuous laser vaporization synthesis of single wall carbon nanotubes and nanohorns journal, December 2008

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns journal, November 2012

Ruthenium-Alloy Electrocatalysts with Tunable Hydrogen Oxidation Kinetics in Alkaline Electrolyte journal, June 2015

Interlayer spacing anomaly of single-wall carbon nanohorn aggregate journal, May 2000

Interlayer spacings in carbon nanotubes journal, July 1993

Single-Wall Nanostructured Carbon for Methane Storage journal, May 2003

Pt Nanoparticle Binding on Functionalized Multiwalled Carbon Nanotubes journal, March 2006

Purity assessment of multiwalled carbon nanotubes by Raman spectroscopy journal, March 2007

Characterizing the Structural Degradation in a PEMFC Cathode Catalyst Layer: Carbon Corrosion journal, January 2009

Corrosion resistance and sintering effect of carbon supports in polymer electrolyte membrane fuel cells journal, November 2009

Investigation of the corrosion of carbon supports in polymer electrolyte fuel cells using simulated start-up/shutdown cycling journal, February 2013

Kinetic Model of Platinum Dissolution in PEMFCs journal, January 2003

Electrocorrosion properties of multiwall carbon nanotubes: Electrocorrosion properties of multiwall carbon nanotubes journal, September 2010

Structure-to-property relationships in fuel cell catalyst supports: Correlation of surface chemistry and morphology with oxidation resistance of carbon blacks journal, September 2012

Direct Evidence on C−C Single Bonding in Single-Wall Carbon Nanohorn Aggregates journal, April 2007

A Reverse-Current Decay Mechanism for Fuel Cells journal, January 2005

Dehydration behavior of the superprotonic conductor CsH2PO4 at moderate temperatures: 230 to 260 °C journal, January 2007

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In situ determination of the electrochemically active platinum surface area: key to improvement of solid acid fuel cells journal, January 2018

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Facile and scalable synthesis of sub-micrometer electrolyte particles for solid acid fuel cells collection, January 2018

Solid acid proton conductors: from laboratory curiosities to fuel cell electrolytes
journal, January 2007

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journal, January 2004

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journal, September 2009

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journal, January 2014

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journal, January 2015

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journal, April 2011

Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells
journal, December 2012

Electrochemical oxidation of carbon black in concentrated phosphoric acid at 135°C
journal, June 1973

Carbon supports for phosphoric acid fuel cell electrocatalysts: alternative materials and methods of evaluation
journal, November 1981

Carbon substrates for phosphoric acid fuel cell cathodes
journal, January 1984

Electrochemical corrosion behavior of carbon black in phosphoric acid
journal, January 1988

The influence of Pt on the electrooxidation behaviour of carbon in phosphoric acid
journal, December 1992

Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes
journal, January 2004

Carbon support oxidation in PEM fuel cell cathodes
journal, February 2008

Electrochemical carbon corrosion in high temperature proton exchange membrane fuel cells
journal, July 2012

Microstructure effects on the electrochemical corrosion of carbon materials and carbon-supported Pt catalysts
journal, December 2010

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: From Model Experiments to Real-Life Operation in Membrane Electrode Assemblies
journal, May 2014

Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: Effect of the Carbon Structure, the Degradation Protocol, and the Gas Atmosphere
journal, March 2015

Durability investigation of carbon nanotube as catalyst support for proton exchange membrane fuel cell
journal, July 2006

Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis
journal, March 2006

Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
journal, October 2007

Fuel cell electrodes using carbon nanostructures
journal, May 2009

Carbon supports for low-temperature fuel cell catalysts
journal, April 2009

Novel catalyst support materials for PEM fuel cells: current status and future prospects
journal, January 2009

Single-Wall Nanohorns as Electrocatalyst Support for High Temperature PEM Fuel Cells
journal, January 2011

Use of single wall carbon nanohorns in polymeric electrolyte fuel cells
journal, November 2011

Nanostructured catalysts in fuel cells
journal, January 2011

Composite nanostructured solid-acid fuel-cell electrodes via electrospray deposition
journal, January 2010

Carbon nanotubes as electronic interconnects in solid acid fuel cell electrodes
journal, January 2013

Dynamics of single-wall carbon nanotube synthesis by laser vaporization
journal, February 2000

Cumulative and continuous laser vaporization synthesis of single wall carbon nanotubes and nanohorns
journal, December 2008

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns
journal, November 2012

Ruthenium-Alloy Electrocatalysts with Tunable Hydrogen Oxidation Kinetics in Alkaline Electrolyte
journal, June 2015

Interlayer spacing anomaly of single-wall carbon nanohorn aggregate
journal, May 2000

Interlayer spacings in carbon nanotubes
journal, July 1993

Single-Wall Nanostructured Carbon for Methane Storage
journal, May 2003

Pt Nanoparticle Binding on Functionalized Multiwalled Carbon Nanotubes
journal, March 2006

Purity assessment of multiwalled carbon nanotubes by Raman spectroscopy
journal, March 2007

Characterizing the Structural Degradation in a PEMFC Cathode Catalyst Layer: Carbon Corrosion
journal, January 2009

Corrosion resistance and sintering effect of carbon supports in polymer electrolyte membrane fuel cells
journal, November 2009

Investigation of the corrosion of carbon supports in polymer electrolyte fuel cells using simulated start-up/shutdown cycling
journal, February 2013

Kinetic Model of Platinum Dissolution in PEMFCs
journal, January 2003

Electrocorrosion properties of multiwall carbon nanotubes: Electrocorrosion properties of multiwall carbon nanotubes
journal, September 2010

Structure-to-property relationships in fuel cell catalyst supports: Correlation of surface chemistry and morphology with oxidation resistance of carbon blacks
journal, September 2012

Direct Evidence on C−C Single Bonding in Single-Wall Carbon Nanohorn Aggregates
journal, April 2007

A Reverse-Current Decay Mechanism for Fuel Cells
journal, January 2005

Dehydration behavior of the superprotonic conductor CsH2PO4 at moderate temperatures: 230 to 260 °C
journal, January 2007

Dehydration of CsH2PO4 at temperatures higher than 260 °C and the ionic conductivity of liquid product
journal, January 2008

In situ determination of the electrochemically active platinum surface area: key to improvement of solid acid fuel cells
journal, January 2018

Facile and scalable synthesis of sub-micrometer electrolyte particles for solid acid fuel cells
journal, January 2018

Mechanism of ion conductivity through polymer-stabilized CsH ₂ PO ₄ nanoparticular layers from experiment and theory
journal, January 2019

Facile and scalable synthesis of sub-micrometer electrolyte particles for solid acid fuel cells
collection, January 2018