Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles

Venna, Surendar R.; Spore, Alex; Tian, Zhicheng; Marti, Anne M.; Albenze, Erik J.; Nulwala, Hunaid B.; Rosi, Nathaniel L.; Luebke, David R.; Hopkinson, David P.; Allcock, Harry R.

doi:10.1016/j.memsci.2017.04.033

Title: Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles

Abstract

Phosphazene-based polymers were synthesized by using different pendant groups such as trifluoroethoxy (TFE), phenoxy (PHO) and octafluoropentoxy (OFP). High performance methoxyethoxyethoxy/cyclohexoxy (MEE/CH) based polyphosphazene was developed for the first time in literature using a mixed-substitution method. The structural, chemical, and thermal properties of these polymers were analyzed using several techniques such as Gel Permeation Chromatography (GPC), Thermal Gravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), and Nuclear Magnetic Resonance (NMR). Significant differences in gas transport properties of gases have been observed between these pendant groups because of their differences in glass transition temperature and physical interaction with CO₂. For the first time, we report on the high performance of TFE polyphophazene based mixed matrix membranes (MMMs) using a SIFSIX-Cu-2i (SIFSIX) metal organic framework (MOF) as the filler particles. These MMMs showed a significant improvement in both CO₂ permeability and CO₂/N₂ selectivity compared to pure TFE polyphosphazene membranes. As a result, the excellent gas transport properties of these membranes make them very promising material for carbon capture applications.

Authors:

Venna, Surendar R. ^[1]; Spore, Alex ^[2]; Tian, Zhicheng ^[3]; Marti, Anne M. ^[4]; Albenze, Erik J. ^[4]; Nulwala, Hunaid B. ^[5]; Rosi, Nathaniel L. ^[2]; Luebke, David R. ^[4]; Hopkinson, David P. ^[4]; Allcock, Harry R. ^[3]

DOE National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); AECOM, Pittsburgh, PA (United States)
Univ. of Pittsburgh, Pittsburgh, PA (United States)
Pennsylvania State Univ., University Park, PA (United States)
DOE National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
DOE National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States)

Publication Date:: Wed Apr 19 00:00:00 EDT 2017

Research Org.:: National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1415616

Alternate Identifier(s):: OSTI ID: 1397078

Report Number(s):: A-CONTR-PUB-056
Journal ID: ISSN 0376-7388; PII: S0376738817303101; TRN: US1800843

Grant/Contract Number:: FE0004000

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Membrane Science

Additional Journal Information:: Journal Volume: 535; Journal Issue: C; Journal ID: ISSN 0376-7388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Polyphosphazene; Metal organic frameworks; Mixed matrix membranes; CO2 capture

Citation Formats


                    Venna, Surendar R., Spore, Alex, Tian, Zhicheng, Marti, Anne M., Albenze, Erik J., Nulwala, Hunaid B., Rosi, Nathaniel L., Luebke, David R., Hopkinson, David P., and Allcock, Harry R. Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles.  United States: N. p., 2017. 
Web.  doi:10.1016/j.memsci.2017.04.033.

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                    Venna, Surendar R., Spore, Alex, Tian, Zhicheng, Marti, Anne M., Albenze, Erik J., Nulwala, Hunaid B., Rosi, Nathaniel L., Luebke, David R., Hopkinson, David P., & Allcock, Harry R. Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles.  United States.  https://doi.org/10.1016/j.memsci.2017.04.033

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                    Venna, Surendar R., Spore, Alex, Tian, Zhicheng, Marti, Anne M., Albenze, Erik J., Nulwala, Hunaid B., Rosi, Nathaniel L., Luebke, David R., Hopkinson, David P., and Allcock, Harry R. Wed .  
"Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles".  United States.  https://doi.org/10.1016/j.memsci.2017.04.033.  https://www.osti.gov/servlets/purl/1415616.

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@article{osti_1415616,

  title        = {Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles},

  author       = {Venna, Surendar R. and Spore, Alex and Tian, Zhicheng and Marti, Anne M. and Albenze, Erik J. and Nulwala, Hunaid B. and Rosi, Nathaniel L. and Luebke, David R. and Hopkinson, David P. and Allcock, Harry R.},

  abstractNote = {Phosphazene-based polymers were synthesized by using different pendant groups such as trifluoroethoxy (TFE), phenoxy (PHO) and octafluoropentoxy (OFP). High performance methoxyethoxyethoxy/cyclohexoxy (MEE/CH) based polyphosphazene was developed for the first time in literature using a mixed-substitution method. The structural, chemical, and thermal properties of these polymers were analyzed using several techniques such as Gel Permeation Chromatography (GPC), Thermal Gravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), and Nuclear Magnetic Resonance (NMR). Significant differences in gas transport properties of gases have been observed between these pendant groups because of their differences in glass transition temperature and physical interaction with CO2. For the first time, we report on the high performance of TFE polyphophazene based mixed matrix membranes (MMMs) using a SIFSIX-Cu-2i (SIFSIX) metal organic framework (MOF) as the filler particles. These MMMs showed a significant improvement in both CO2 permeability and CO2/N2 selectivity compared to pure TFE polyphosphazene membranes. As a result, the excellent gas transport properties of these membranes make them very promising material for carbon capture applications.},

  doi          = {10.1016/j.memsci.2017.04.033},

  journal      = {Journal of Membrane Science},

  number       = C,

  volume       = 535,

  place        = {United States},

  year         = {Wed Apr 19 00:00:00 EDT 2017},

  month        = {Wed Apr 19 00:00:00 EDT 2017}

}

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https://doi.org/10.1016/j.memsci.2017.04.033

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Title: Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles

Abstract

Citation Formats

Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program journal, January 2008

Opportunities and challenges in carbon dioxide capture journal, June 2013

Synthesis, characterization, and gas permeability of a series of 4-phenylphenoxy/phenoxy substituted polyphosphazene membranes journal, May 2009

Gas permeability in rubbery polyphosphazene membranes journal, September 2006

Mixed gas hydrogen sulfide permeability and separation using supported polyphosphazene membranes journal, May 2005

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Polyphosphazene membranes with phenoxyls for enhanced desulfurization journal, January 2012

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Poly[(amino acid ester)phosphazenes]: Synthesis, Crystallinity, and Hydrolytic Sensitivity in Solution and the Solid State journal, February 1994

Effects of organic side group structures on the properties of poly(organophosphazenes) journal, February 1988

Polyphosphazene polymers for tissue engineering: an analysis of material synthesis, characterization and applications journal, January 2010

Synthesis of High Polymeric Alkoxy- and Aryloxyphosphonitriles journal, September 1965

Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Superhydrophobic Nanofibers journal, December 2005

Influence of Terminal Phenyl Groups on the Side Chains of Phosphazene Polymers: Structure−Property Relationships and Polymer Electrolyte Behavior journal, January 2007

Novel Highly Fluorinated Perfluorocyclobutane-Based Phosphazene Polymers for Photonic Applications journal, November 2007

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Characterization of Substituted Polyphosphazene Membranes − Pure and Mixed Gas Results journal, August 2006

Membrane-based gas separation journal, August 1993

Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes journal, January 1999

Mixed matrix membranes using carbon molecular sieves journal, January 2003

Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation journal, April 2007

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Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials journal, June 2000

Asymmetric Matrimid®/[Cu3(BTC)2] mixed-matrix membranes for gas separations journal, October 2010

Modulated UiO-66-Based Mixed-Matrix Membranes for CO 2 Separation journal, November 2015

Functionalized metal organic framework-polyimide mixed matrix membranes for CO2/CH4 separation journal, September 2012

Molecular sieving realized with ZIF-8/Matrimid® mixed-matrix membranes journal, September 2010

Mixed-matrix membranes containing MOF-5 for gas separations journal, February 2009

Mechanical properties of low nano-silica filled high density polyethylene composites journal, February 2003

Structure–property relationships of irradiation grafted nano-inorganic particle filled polypropylene composites journal, January 2001

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation journal, January 2012

Sorption and diffusion of organic vapors in poly[bis(trifluoroethoxy) phosphazene] and poly[bis(phenoxy)phosphazene] membranes journal, October 1997

Polyphosphazenes: Synthesis?properties?applications journal, May 1975

Ultrapermeable, Reverse-Selective Nanocomposite Membranes journal, April 2002

Silica-Treated Ceramic Substrates for Formation of Polymer-Ceramic Composite Membranes journal, January 1995

Polymeric mixed matrix membranes containing zeolites as a filler for gas separation applications: A review journal, March 2013

An automated lab-scale flue gas permeation membrane testing system at the National Carbon Capture Center journal, July 2017

High-throughput computational prediction of the cost of carbon capture using mixed matrix membranes journal, January 2019

Microporous polymeric composite membranes with advanced film properties: pore intercalation yields excellent CO 2 separation performance journal, January 2018

Development of ethanolamine-based ionic liquid membranes for efficient CO 2 /CH 4 separation journal, July 2017

Advances in CO₂ capture technology—The U.S. Department of Energy's Carbon Sequestration Program
journal, January 2008

Opportunities and challenges in carbon dioxide capture
journal, June 2013

Synthesis, characterization, and gas permeability of a series of 4-phenylphenoxy/phenoxy substituted polyphosphazene membranes
journal, May 2009

Gas permeability in rubbery polyphosphazene membranes
journal, September 2006

Mixed gas hydrogen sulfide permeability and separation using supported polyphosphazene membranes
journal, May 2005

Characterization of gas transport in selected rubbery amorphous polyphosphazene membranes
journal, May 2001

Polyphosphazene membranes with phenoxyls for enhanced desulfurization
journal, January 2012

Phosphonitrilic Compounds. VI. High Molecular Weight Poly(alkoxy- and aryloxyphosphazenes)
journal, October 1966

Poly[(amino acid ester)phosphazenes]: Synthesis, Crystallinity, and Hydrolytic Sensitivity in Solution and the Solid State
journal, February 1994

Effects of organic side group structures on the properties of poly(organophosphazenes)
journal, February 1988

Polyphosphazene polymers for tissue engineering: an analysis of material synthesis, characterization and applications
journal, January 2010

Synthesis of High Polymeric Alkoxy- and Aryloxyphosphonitriles
journal, September 1965

Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Superhydrophobic Nanofibers
journal, December 2005

Influence of Terminal Phenyl Groups on the Side Chains of Phosphazene Polymers: Structure−Property Relationships and Polymer Electrolyte Behavior
journal, January 2007

Novel Highly Fluorinated Perfluorocyclobutane-Based Phosphazene Polymers for Photonic Applications
journal, November 2007

Gas permeability of poly(bis-trifluoroethoxyphosphazene) and blends with adamantane amino/trifluoroethoxy (50/50) polyphosphazene
journal, July 2000

Characterization of Substituted Polyphosphazene Membranes − Pure and Mixed Gas Results
journal, August 2006

Membrane-based gas separation
journal, August 1993

Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes
journal, January 1999

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation
journal, April 2007

Non-ideal effects in organic–inorganic materials for gas separation membranes
journal, April 2005

Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles
journal, January 2015

Metal–Organic Frameworks for Separations
journal, September 2011

Metal–organic frameworks—prospective industrial applications
journal, January 2006

Knudsen diffusion through ZIF-8 membranes synthesized by secondary seeded growth
journal, December 2013

Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO ₂ /CH ₄ Separation
journal, January 2010

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture
journal, June 2014

Porous materials with optimal adsorption thermodynamics and kinetics for CO₂ separation
journal, February 2013

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?
journal, July 2016

Effect of the structural constituents of metal organic frameworks on carbon dioxide capture
journal, January 2016

Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials
journal, June 2000

Asymmetric Matrimid®/[Cu3(BTC)2] mixed-matrix membranes for gas separations
journal, October 2010

Modulated UiO-66-Based Mixed-Matrix Membranes for CO ₂ Separation
journal, November 2015

Functionalized metal organic framework-polyimide mixed matrix membranes for CO2/CH4 separation
journal, September 2012

Molecular sieving realized with ZIF-8/Matrimid^® mixed-matrix membranes
journal, September 2010

Mixed-matrix membranes containing MOF-5 for gas separations
journal, February 2009

Mechanical properties of low nano-silica filled high density polyethylene composites
journal, February 2003

Structure–property relationships of irradiation grafted nano-inorganic particle filled polypropylene composites
journal, January 2001

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
journal, January 2012

Sorption and diffusion of organic vapors in poly[bis(trifluoroethoxy) phosphazene] and poly[bis(phenoxy)phosphazene] membranes
journal, October 1997

Polyphosphazenes: Synthesis?properties?applications
journal, May 1975

Ultrapermeable, Reverse-Selective Nanocomposite Membranes
journal, April 2002

Silica-Treated Ceramic Substrates for Formation of Polymer-Ceramic Composite Membranes
journal, January 1995

Polymeric mixed matrix membranes containing zeolites as a filler for gas separation applications: A review
journal, March 2013

An automated lab-scale flue gas permeation membrane testing system at the National Carbon Capture Center
journal, July 2017

High-throughput computational prediction of the cost of carbon capture using mixed matrix membranes
journal, January 2019

Microporous polymeric composite membranes with advanced film properties: pore intercalation yields excellent CO ₂ separation performance
journal, January 2018

Development of ethanolamine-based ionic liquid membranes for efficient CO ₂ /CH ₄ separation
journal, July 2017