Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage

Ni, Jiangfeng; Bi, Xuanxuan; Jiang, Yu; Li, Liang; Lu, Jun

doi:10.1016/j.nanoen.2017.02.041

Title: Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage

Full Record
Other Related Research

Authors:: Ni, Jiangfeng; Bi, Xuanxuan; Jiang, Yu; Li, Liang; Lu, Jun

Publication Date:: Sat Apr 01 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1396399

Grant/Contract Number:: AC0206CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Nano Energy

Additional Journal Information:: Journal Name: Nano Energy Journal Volume: 34 Journal Issue: C; Journal ID: ISSN 2211-2855

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Ni, Jiangfeng, Bi, Xuanxuan, Jiang, Yu, Li, Liang, and Lu, Jun. Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage.  Netherlands: N. p., 2017. 
Web.  doi:10.1016/j.nanoen.2017.02.041.

Copy to clipboard


                    Ni, Jiangfeng, Bi, Xuanxuan, Jiang, Yu, Li, Liang, & Lu, Jun. Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage.  Netherlands.  https://doi.org/10.1016/j.nanoen.2017.02.041

Copy to clipboard


                    Ni, Jiangfeng, Bi, Xuanxuan, Jiang, Yu, Li, Liang, and Lu, Jun. Sat .  
"Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage".  Netherlands.  https://doi.org/10.1016/j.nanoen.2017.02.041.

Copy to clipboard


                    
@article{osti_1396399,

  title        = {Bismuth chalcogenide compounds Bi2×3 (X=O, S, Se): Applications in electrochemical energy storage},

  author       = {Ni, Jiangfeng and Bi, Xuanxuan and Jiang, Yu and Li, Liang and Lu, Jun},

  abstractNote = {},

  doi          = {10.1016/j.nanoen.2017.02.041},

  journal      = {Nano Energy},

  number       = C,

  volume       = 34,

  place        = {Netherlands},

  year         = {Sat Apr 01 00:00:00 EDT 2017},

  month        = {Sat Apr 01 00:00:00 EDT 2017}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.nanoen.2017.02.041

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 133 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Bismuth chalcogenide compounds Bi 2 × 3 (X=O, S, Se): Applications in electrochemical energy storage

Journal Article Ni, Jiangfeng ; Bi, Xuanxuan ; Jiang, Yu ; ... - Nano Energy

Bismuth chalcogenides Bi2×3 (X=O, S, Se) represent a unique type of materials in diverse polymorphs and configurations. Multiple intrinsic features of Bi2×3 such as narrow bandgap, ion conductivity, and environmental friendliness, have render them attractive materials for a wide array of energy applications. In particular, their rich structural voids and the alloying capability of Bi enable the chalcogenides to be alternative electrodes for energy storage such as hydrogen (H), lithium (Li), sodium (Na) storage and supercapacitors. However, the low conductivity and poor electrochemical cycling are two key challenges for the practical utilization of Bi2×3 electrodes. Great efforts have been devotedmore »« less
https://doi.org/10.1016/j.nanoen.2017.02.041
Ternary bismuth chalcogenides for thermoelectric applications. Synthesis and charge transport properties of new compounds in the K-Bi-S system

Book Kanatzidis, M G ; McCarthy, T J ; Tanzer, T A ; ...

Group 15 chalcogenide compounds have received considerable attention, due to their potential application as thermoelectric cooling materials. KBi{sub 6.33}S{sub 10} and K{sub 2}Bi{sub 8}S{sub 13} were synthesized by the direct combination of K{sub 2}S/Bi{sub 2}S{sub 3} at high temperature (> 700 C). The reaction of K{sub 2}S/3.3Bi{sub 2}S{sub 3} at 800 C revealed the presence of a new ternary sulfide KBi{sub 6.33}S{sub 10} (1) (92% yield). The structure consists of blocks of Bi{sub 2}Te{sub 3} and CdI{sub 2}-type units that are connected to form a three-dimensional network with K{sup +} ions located in the channels that run along the b-axis.more »« less
Crystal chemistry, magnetic, and electrical properties of hexagonal plutonium oxide chalcogenides: Pu/sub 2/O/sub 2/X, X = O, S, Se

Journal Article Costantini, J M ; Novion, C H ; Blaise, A ; ... - J. Solid State Chem.; (United States)

A study was made of the influence of the chalcogen X on the magnetic and electrical properties of Pu/sub 2/O/sub 2/X (X=O,S,Se) compounds and on bonding in these hexagonal compounds, isostructural with the corresponding rare-earth compounds. The comparison of the cell volumes of Nd/sub 2/O/sub 2/X and Pu/sub 2/O/sub 2/X compounds showed that the Pu/sup 3 +/ crystal radius decreased from ..beta..-Pu/sub 2/O/sub 3/ to Pu/sub 2/O/sub 2/Se as ''5f delocalization'' and 5f-p overlap increased. These plutonium compounds were all found to be antiferromagnetic. This was caused by superexchange coupling interactions via p orbitals of the oxygen and chalcogen ions.more »« less
https://doi.org/10.1016/0022-4596(83)90009-9
Topotactic redox reactions of the channel type chalcogenides Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/. [Formation of ternary phases A/sub x/Mo/sub 3/X/sub 4/, where A is transition or main group element]

Journal Article Schoellhorn, R ; Kuempers, M ; Besenhard, J O - Mater. Res. Bull.; (United States)

Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/ were found to undergo topotactic electron-ion exchange reactions at ambient temperatures in aqueous and nonaqueous electrolytes containing transition or main group cations. The products of cathodic reduction are ternary phases A/sub x/Mo/sub 3/X/sub 4/. Mobilities of the exchangeable cations are rather high inside the solid and are responsible for high reaction rates. Cathodic reduction of Mo/sub 3/S/sub 4/ and Mo/sub 3/Se/sub 4/ represents a suitable method for the preparation of both stoichiometric and nonstoichiometric ternary phases which are of interest with respect to the superconducting properties of these chalcogenides.
Phase transitions in quasi-one-dimensional chalcogenides of BaNb{sub x}S{sub 3} and BaTa{sub x}Se{sub 3}

Journal Article Ohtani, T ; Sawada, H ; Chikamori, M - Materials Research Bulletin

BaNbS{sub 3} phase was found to be stable in the composition range between x=0.85 and 0.97 for BaNb{sub x}S{sub 3}. The conduction nature was varied from semiconductive to metallic with increasing Nb content. Semiconductor-to-metal (S-M) transition was observed at {approx}170 and {approx}250 K in BaNb{sub 0.95}S{sub 3} and BaNb{sub 0.97}S{sub 3}, respectively. BaTaSe{sub 3} phase was stable in the range between x=0.90 and 0.95 for BaTa{sub x}Se{sub 3}. BaTa{sub x}Se{sub 3} with x=0.90 and 0.95 showed a semiconductor-to-semiconductor transition at {approx}140 K, which is characterized by a large jump of the resistivity from {approx}10{sup 6} to {approx}10{sup 12} {omega} cm.more »« less
https://doi.org/10.1016/j.materresbull.2003.12.015

Similar Records