GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice

Manni, S.; Bud'ko, Sergey L.; Canfield, Paul C.

doi:10.1103/PhysRevB.96.054435

Title: GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice

Abstract

In the spirit of searching for Gd-based, frustrated, rare earth magnets, we have found antiferomagnetism (AF) in GdPtPb, which crystallizes in the ZrNiAl-type structure that has a distorted kagome lattice of Gd triangles. Single crystals were grown and investigated using structural, magnetic, transport, and thermodynamic measurements. GdPtPb orders antiferromagnetically at 15.5 K, arguably with a planar, noncollinear structure. The high temperature magnetic susceptibility data reveal an “anti-frustration” behavior having a frustration parameter, |f| = |Θ|/T_N = 0.25, which can be explained by mean field theory within a two-sublattice model. Here, the study of the magnetic phase diagram down to T = 1.8K reveals a change of magnetic structure through a metamagnetic transition at around 20 kOe and the disappearance of the AF ordering near 140 kOe. In total, our work indicates that GdPtPb can serve as an example of a planar, noncollinear AF with a distorted kagome magnetic sublattice.

Authors:

Manni, S. ^[1]; Bud'ko, Sergey L. ^[1]; Canfield, Paul C. ^[1]

Iowa State Univ., Ames, IA (United States)

Publication Date:: Thu Aug 24 00:00:00 EDT 2017

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1396272

Alternate Identifier(s):: OSTI ID: 1376926

Report Number(s):: IS-J-9430
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1702844

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 96; Journal Issue: 5; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Manni, S., Bud'ko, Sergey L., and Canfield, Paul C. GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice.  United States: N. p., 2017. 
Web.  doi:10.1103/PhysRevB.96.054435.

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                    Manni, S., Bud'ko, Sergey L., & Canfield, Paul C. GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice.  United States.  https://doi.org/10.1103/PhysRevB.96.054435

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                    Manni, S., Bud'ko, Sergey L., and Canfield, Paul C. Thu .  
"GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice".  United States.  https://doi.org/10.1103/PhysRevB.96.054435.  https://www.osti.gov/servlets/purl/1396272.

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@article{osti_1396272,

  title        = {GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice},

  author       = {Manni, S. and Bud'ko, Sergey L. and Canfield, Paul C.},

  abstractNote = {In the spirit of searching for Gd-based, frustrated, rare earth magnets, we have found antiferomagnetism (AF) in GdPtPb, which crystallizes in the ZrNiAl-type structure that has a distorted kagome lattice of Gd triangles. Single crystals were grown and investigated using structural, magnetic, transport, and thermodynamic measurements. GdPtPb orders antiferromagnetically at 15.5 K, arguably with a planar, noncollinear structure. The high temperature magnetic susceptibility data reveal an “anti-frustration” behavior having a frustration parameter, |f| = |Θ|/TN = 0.25, which can be explained by mean field theory within a two-sublattice model. Here, the study of the magnetic phase diagram down to T = 1.8K reveals a change of magnetic structure through a metamagnetic transition at around 20 kOe and the disappearance of the AF ordering near 140 kOe. In total, our work indicates that GdPtPb can serve as an example of a planar, noncollinear AF with a distorted kagome magnetic sublattice.},

  doi          = {10.1103/PhysRevB.96.054435},

  journal      = {Physical Review B},

  number       = 5,

  volume       = 96,

  place        = {United States},

  year         = {Thu Aug 24 00:00:00 EDT 2017},

  month        = {Thu Aug 24 00:00:00 EDT 2017}

}

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Works referenced in this record:

Emergent Frustration in Co-doped $β$ -Mn
journal, June 2013

Paddison, Joseph A. M.; Stewart, J. Ross; Manuel, Pascal
Physical Review Letters, Vol. 110, Issue 26
DOI: 10.1103/PhysRevLett.110.267207

Magnetism in CePtPb
journal, March 1996

Movshovich, R.; Lawrence, J. M.; Hundley, M. F.
Physical Review B, Vol. 53, Issue 9
DOI: 10.1103/PhysRevB.53.5465

Spin liquids in frustrated magnets
journal, March 2010

Balents, Leon
Nature, Vol. 464, Issue 7286
DOI: 10.1038/nature08917

Anyons in an exactly solved model and beyond
journal, January 2006

Kitaev, Alexei
Annals of Physics, Vol. 321, Issue 1
DOI: 10.1016/j.aop.2005.10.005

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples
journal, December 2015

Canfield, Paul C.; Kong, Tai; Kaluarachchi, Udhara S.
Philosophical Magazine, Vol. 96, Issue 1
DOI: 10.1080/14786435.2015.1122248

Single crystal growth from separated educts and its application to lithium transition-metal oxides
journal, October 2016

Freund, F.; Williams, S. C.; Johnson, R. D.
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep35362

Origin of modulated phases and magnetic hysteresis in ${TmB}_{4}$
journal, December 2015

Wierschem, Keola; Sunku, Sai Swaroop; Kong, Tai
Physical Review B, Vol. 92, Issue 21
DOI: 10.1103/PhysRevB.92.214433

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Toby, Brian H.
Journal of Applied Crystallography, Vol. 34, Issue 2
DOI: 10.1107/S0021889801002242

Quantum Bicriticality in the Heavy-Fermion Metamagnet YbAgGe
journal, September 2013

Tokiwa, Y.; Garst, M.; Gegenwart, P.
Physical Review Letters, Vol. 111, Issue 11
DOI: 10.1103/PhysRevLett.111.116401

Magnetism and heavy fermion‐like behavior in the RBiPt series
journal, November 1991

Canfield, P. C.; Thompson, J. D.; Beyermann, W. P.
Journal of Applied Physics, Vol. 70, Issue 10
DOI: 10.1063/1.350141

Geometrically frustrated magnetic structures of the heavy-fermion compound CePdAl studied by powder neutron diffraction
journal, December 1996

Dönni, A.; Ehlers, G.; Maletta, H.
Journal of Physics: Condensed Matter, Vol. 8, Issue 50
DOI: 10.1088/0953-8984/8/50/043

Spin Fluctuations in $(Y_{0.97} {Sc}_{0.03}) {Mn}_{2}$ : A Geometrically Frustrated, Nearly Antiferromagnetic, Itinerant Electron System
journal, March 1996

Ballou, R.; Lelièvre-Berna, E.; Fåk, B.
Physical Review Letters, Vol. 76, Issue 12
DOI: 10.1103/PhysRevLett.76.2125

Characteristic signatures of quantum criticality driven by geometrical frustration
journal, April 2015

Tokiwa, Yoshifumi; Stingl, Christian; Kim, Moo-Sung
Science Advances, Vol. 1, Issue 3
DOI: 10.1126/sciadv.1500001

Approaching quantum criticality in a partially geometrically frustrated heavy-fermion metal
journal, February 2014

Fritsch, V.; Bagrets, N.; Goll, G.
Physical Review B, Vol. 89, Issue 5
DOI: 10.1103/PhysRevB.89.054416

Metallic Spin-Liquid Behavior of the Geometrically Frustrated Kondo Lattice $\Pr_{2} {Ir}_{2} O_{7}$
journal, March 2006

Nakatsuji, S.; Machida, Y.; Maeno, Y.
Physical Review Letters, Vol. 96, Issue 8
DOI: 10.1103/PhysRevLett.96.087204

Relevance of the Heisenberg-Kitaev Model for the Honeycomb Lattice Iridates $A_{2} {IrO}_{3}$
journal, March 2012

Singh, Yogesh; Manni, S.; Reuther, J.
Physical Review Letters, Vol. 108, Issue 12
DOI: 10.1103/PhysRevLett.108.127203

Anisotropic magnetization, specific heat and resistivity of RFe2Ge2 single crystals
journal, March 2004

Avila, M. A.; Bud'ko, S. L.; Canfield, P. C.
Journal of Magnetism and Magnetic Materials, Vol. 270, Issue 1-2
DOI: 10.1016/S0304-8853(03)00672-3

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets
journal, February 2015

Johnston, David C.
Physical Review B, Vol. 91, Issue 6
DOI: 10.1103/PhysRevB.91.064427

Specific heat in some gadolinium compounds. I. Experimental
journal, June 1991

Bouvier, M.; Lethuillier, P.; Schmitt, D.
Physical Review B, Vol. 43, Issue 16
DOI: 10.1103/PhysRevB.43.13137

Heavy fermion compounds on the geometrically frustrated Shastry–Sutherland lattice
journal, April 2011

Kim, M. S.; Aronson, M. C.
Journal of Physics: Condensed Matter, Vol. 23, Issue 16
DOI: 10.1088/0953-8984/23/16/164204

Frustration and the Kondo Effect in Heavy Fermion Materials
journal, September 2010

Coleman, Piers; Nevidomskyy, Andriy H.
Journal of Low Temperature Physics, Vol. 161, Issue 1-2
DOI: 10.1007/s10909-010-0213-4

X-Ray diffraction on large single crystals using a powder diffractometer
journal, June 2016

Jesche, A.; Fix, M.; Kreyssig, A.
Philosophical Magazine, Vol. 96, Issue 20
DOI: 10.1080/14786435.2016.1192725

Multiple regions of quantum criticality in YbAgGe
journal, May 2011

Schmiedeshoff, G. M.; Mun, E. D.; Lounsbury, A. W.
Physical Review B, Vol. 83, Issue 18
DOI: 10.1103/PhysRevB.83.180408

Spin Ice State in Frustrated Magnetic Pyrochlore Materials
journal, November 2001

Bramwell, S. T.
Science, Vol. 294, Issue 5546
DOI: 10.1126/science.1064761

${Yb}_{2} {Pt}_{2} Pb$ : Magnetic frustration in the Shastry-Sutherland lattice
journal, April 2008

Kim, M. S.; Bennett, M. C.; Aronson, M. C.
Physical Review B, Vol. 77, Issue 14
DOI: 10.1103/PhysRevB.77.144425

Geometric frustration in Rare Earth antiferromagnetic compounds
journal, July 1998

Ballou, Rafik
Journal of Alloys and Compounds, Vol. 275-277
DOI: 10.1016/S0925-8388(98)00382-X

Strongly Geometrically Frustrated Magnets
journal, August 1994

Ramirez, A. P.
Annual Review of Materials Science, Vol. 24, Issue 1
DOI: 10.1146/annurev.ms.24.080194.002321

Unusual magnetic, thermal, and transport behavior of single-crystalline ${EuRh}_{2} {As}_{2}$
journal, June 2009

Singh, Yogesh; Lee, Y.; Harmon, B. N.
Physical Review B, Vol. 79, Issue 22
DOI: 10.1103/PhysRevB.79.220401

Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model
journal, September 2011

Johnston, D. C.; McQueeney, R. J.; Lake, B.
Physical Review B, Vol. 84, Issue 9
DOI: 10.1103/PhysRevB.84.094445

Crystal structures of new ternary compounds in RE–Pt–Pb and RE–Au–Pb systems (RE=rare earth metal)
journal, July 2012

Melnyk, G.; Gulay, L. D.; Tremel, W.
Journal of Alloys and Compounds, Vol. 528
DOI: 10.1016/j.jallcom.2012.01.063

Specific Heat of Insulating Spin-Glasses, (Eu,Sr)S, near the Onset of Ferromagnetism
journal, January 1980

Meschede, D.; Steglich, F.; Felsch, W.
Physical Review Letters, Vol. 44, Issue 2
DOI: 10.1103/PhysRevLett.44.102

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Title: GdPtPb: A noncollinear antiferromagnet with distorted kagome lattice

Abstract

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