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Title: Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface

Abstract

The chemical transformation of CO2 not only mitigates the anthropogenic CO2 emission into the Earth’s atmosphere but also produces carbon compounds that can be used as precursors for the production of chemicals and fuels. The activation and conversion of CO2 can be achieved on multifunctional catalytic sites available at the metal/oxide interface by taking advantage of the synergy between the metal nanoparticles and oxide support. In this paper, we look at the recent progress in mechanistic studies of CO2 hydrogenation to C1 (CO, CH3OH, and CH4) compounds on metal/oxide catalysts. On this basis, we are able to provide a better understanding of the complex reaction network, grasp the capability of manipulating structure and combination of metal and oxide at the interface in tuning selectivity, and identify the key descriptors to control the activity and, in particular, the selectivity of catalysts. In conclusion, we also discuss challenges and future research opportunities for tuning the selective conversion of CO2 on metal/oxide catalysts.

Authors:
 [1]; ORCiD logo [1]; ORCiD logo [2]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1395947
Report Number(s):
BNL-114374-2017-JA
Journal ID: ISSN 0002-7863; R&D Project: CO035; KC0302010; TRN: US1702389
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 29; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kattel, Shyam, Liu, Ping, and Chen, Jingguang G. Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface. United States: N. p., 2017. Web. doi:10.1021/jacs.7b05362.
Kattel, Shyam, Liu, Ping, & Chen, Jingguang G. Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface. United States. doi:10.1021/jacs.7b05362.
Kattel, Shyam, Liu, Ping, and Chen, Jingguang G. Mon . "Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface". United States. doi:10.1021/jacs.7b05362. https://www.osti.gov/servlets/purl/1395947.
@article{osti_1395947,
title = {Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface},
author = {Kattel, Shyam and Liu, Ping and Chen, Jingguang G.},
abstractNote = {The chemical transformation of CO2 not only mitigates the anthropogenic CO2 emission into the Earth’s atmosphere but also produces carbon compounds that can be used as precursors for the production of chemicals and fuels. The activation and conversion of CO2 can be achieved on multifunctional catalytic sites available at the metal/oxide interface by taking advantage of the synergy between the metal nanoparticles and oxide support. In this paper, we look at the recent progress in mechanistic studies of CO2 hydrogenation to C1 (CO, CH3OH, and CH4) compounds on metal/oxide catalysts. On this basis, we are able to provide a better understanding of the complex reaction network, grasp the capability of manipulating structure and combination of metal and oxide at the interface in tuning selectivity, and identify the key descriptors to control the activity and, in particular, the selectivity of catalysts. In conclusion, we also discuss challenges and future research opportunities for tuning the selective conversion of CO2 on metal/oxide catalysts.},
doi = {10.1021/jacs.7b05362},
journal = {Journal of the American Chemical Society},
number = 29,
volume = 139,
place = {United States},
year = {2017},
month = {6}
}

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Works referencing / citing this record:

The Interplay between Structure and Product Selectivity of CO 2 Hydrogenation
journal, June 2019

  • Yang, Chengsheng; Liu, Sihang; Wang, Yanan
  • Angewandte Chemie International Edition, Vol. 58, Issue 33
  • DOI: 10.1002/anie.201904649

The Interplay between Structure and Product Selectivity of CO 2 Hydrogenation
journal, June 2019

  • Yang, Chengsheng; Liu, Sihang; Wang, Yanan
  • Angewandte Chemie International Edition, Vol. 58, Issue 33
  • DOI: 10.1002/anie.201904649