Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature

Deng, Changjian; Lau, Miu Lun; Barkholtz, Heather M.; Xu, Haiping; Parrish, Riley; Xu, Meiyue (Olivia); Xu, Tao; Liu, Yuzi; Wang, Hao; Connell, Justin G.; Smith, Kassiopeia A.; Xiong, Hui

doi:10.1039/c7nr03017g

Title: Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature

Abstract

We report an amorphous boron nanorod anode material for lithium-ion batteries prepared through smelting non-toxic boron oxide in liquid lithium.

Authors:

Deng, Changjian ^[1]; Lau, Miu Lun ^[1]; Barkholtz, Heather M. ^[2]; Xu, Haiping ^[2]; Parrish, Riley ^[1]; Xu, Meiyue ^[3]; Xu, Tao ^[2]; Liu, Yuzi ^[4]; Wang, Hao ^[5]; Connell, Justin G. ^[6]; Smith, Kassiopeia A. ^[1];

^[1]

Boise State Univ., ID (United States). Micron School of Materials Science and Engineering
Northern Illinois Univ., DeKalb, IL (United States). Dept. of Chemistry and Biochemistry
(Olivia) [Northern Illinois Univ., DeKalb, IL (United States). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research

Publication Date:: Thu Jun 22 00:00:00 EDT 2017

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

OSTI Identifier:: 1395544

Grant/Contract Number:: AC02-06CH11357; CBET-1150617

Resource Type:: Accepted Manuscript

Journal Name:: Nanoscale

Additional Journal Information:: Journal Volume: 9; Journal Issue: 30; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats


                    Deng, Changjian, Lau, Miu Lun, Barkholtz, Heather M., Xu, Haiping, Parrish, Riley, Xu, Meiyue, Xu, Tao, Liu, Yuzi, Wang, Hao, Connell, Justin G., Smith, Kassiopeia A., and Xiong, Hui. Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature.  United States: N. p., 2017. 
Web.  doi:10.1039/c7nr03017g.

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                    Deng, Changjian, Lau, Miu Lun, Barkholtz, Heather M., Xu, Haiping, Parrish, Riley, Xu, Meiyue, Xu, Tao, Liu, Yuzi, Wang, Hao, Connell, Justin G., Smith, Kassiopeia A., & Xiong, Hui. Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature.  United States.  https://doi.org/10.1039/c7nr03017g

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                    Deng, Changjian, Lau, Miu Lun, Barkholtz, Heather M., Xu, Haiping, Parrish, Riley, Xu, Meiyue, Xu, Tao, Liu, Yuzi, Wang, Hao, Connell, Justin G., Smith, Kassiopeia A., and Xiong, Hui. Thu .  
"Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature".  United States.  https://doi.org/10.1039/c7nr03017g.  https://www.osti.gov/servlets/purl/1395544.

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@article{osti_1395544,

  title        = {Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature},

  author       = {Deng, Changjian and Lau, Miu Lun and Barkholtz, Heather M. and Xu, Haiping and Parrish, Riley and Xu, Meiyue and Xu, Tao and Liu, Yuzi and Wang, Hao and Connell, Justin G. and Smith, Kassiopeia A. and Xiong, Hui},

  abstractNote = {We report an amorphous boron nanorod anode material for lithium-ion batteries prepared through smelting non-toxic boron oxide in liquid lithium.},

  doi          = {10.1039/c7nr03017g},

  journal      = {Nanoscale},

  number       = 30,

  volume       = 9,

  place        = {United States},

  year         = {Thu Jun 22 00:00:00 EDT 2017},

  month        = {Thu Jun 22 00:00:00 EDT 2017}

}

Copy to clipboard

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Works referencing / citing this record:

MoS _0.5 Se _1.5 Embedded in 2D Porous Carbon Sheets Boost Lithium Storage Performance as an Anode Material
journal, January 2018

Li, Tongfei; Wang, Ao; Li, Xin
Advanced Materials Interfaces, Vol. 5, Issue 7
DOI: 10.1002/admi.201701604

In Situ Synthesis of Mn ₃ O ₄ Nanoparticles on Hollow Carbon Nanofiber as High-Performance Lithium-Ion Battery Anode
journal, June 2018

Zhang, Dan; Li, Guangshe; Fan, Jianming
Chemistry - A European Journal, Vol. 24, Issue 38
DOI: 10.1002/chem.201801196

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Title: Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature

Abstract

Citation Formats

Preparation and characterization of lithium-boron alloys: electrochemical studies as anodes in molten salt media, and comparison with pure lithium-involving systems journal, January 1992

One-pot synthesis of heterogeneous Co3O4-nanocube/Co(OH)2-nanosheet hybrids for high-performance flexible asymmetric all-solid-state supercapacitors journal, May 2017

Thermal Analysis of Lithium-Boron Alloys journal, January 1979

The dimensionality of Sn anodes in Li-ion batteries journal, December 2012

Superhard Semiconducting Optically Transparent High Pressure Phase of Boron journal, May 2009

Electrochemical studies of LiB compound as anode material for lithium-ion battery journal, August 2006

Neutron- and x-ray-diffraction measurements of the bulk modulus of boron journal, April 1993

A neutron diffraction study of amorphous boron using a pulsed source journal, December 1988

The B-Li (Boron-Lithium) system journal, December 2003

The molecular and electronic structure of Li5B4 journal, September 1979

Dilithium Hexaboride, Li2B6 journal, July 1999

Controlled vesicle deformation and lysis by single oscillating bubbles journal, May 2003

The Structure Chemistry of Boron-Rich Solids of the Alkali Metals journal, August 2000

A neutron diffraction study of amorphous boron journal, September 1988

An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries journal, January 1998

Ionic high-pressure form of elemental boron journal, January 2009

Comparison of anodic dischargability of Li-B alloy with pure lithium in LiClO4-propylene carbonate journal, May 1982

The Electrochemical Reaction of Li with Amorphous Si-Sn Alloys journal, January 2003

Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles journal, October 2007

Alloy Negative Electrodes for Li-Ion Batteries journal, October 2014

Infinite, Linear, Unbranched Borynide Chains in LiBx—Isoelectronic to Polyyne and Polycumulene journal, July 2000

An unusual phenomenon in the formation of Li5B4 compound-alloy journal, March 1979

The role and utilization of pseudocapacitance for energy storage by supercapacitors journal, May 1997

Temperature-dependent lithium storage behavior in tetragonal boron (B50) thin film anode for Li-ion batteries journal, January 2013

Structure and Bulk Modulus of High-Strength Boron Compounds journal, October 1997

Investigations of a number of alternative negative electrode materials for use in lithium cells journal, July 2001

Li + Ion Insertion in TiO 2 (Anatase). 2. Voltammetry on Nanoporous Films journal, September 1997

Electrochemical studies of lithium-boron alloys in non-aqueous media — comparison with pure lithium journal, May 1989

A Comparison of the Reactions of the SiSn, SiAg, and SiZn Binary Systems with L3i journal, January 2006

Chemical Composition and Morphology of the Elevated Temperature SEI on Graphite journal, January 2001

MoS 0.5 Se 1.5 Embedded in 2D Porous Carbon Sheets Boost Lithium Storage Performance as an Anode Material journal, January 2018

In Situ Synthesis of Mn 3 O 4 Nanoparticles on Hollow Carbon Nanofiber as High-Performance Lithium-Ion Battery Anode journal, June 2018

Preparation and characterization of lithium-boron alloys: electrochemical studies as anodes in molten salt media, and comparison with pure lithium-involving systems
journal, January 1992

One-pot synthesis of heterogeneous Co3O4-nanocube/Co(OH)2-nanosheet hybrids for high-performance flexible asymmetric all-solid-state supercapacitors
journal, May 2017

Thermal Analysis of Lithium-Boron Alloys
journal, January 1979

The dimensionality of Sn anodes in Li-ion batteries
journal, December 2012

Superhard Semiconducting Optically Transparent High Pressure Phase of Boron
journal, May 2009

Electrochemical studies of LiB compound as anode material for lithium-ion battery
journal, August 2006

Neutron- and x-ray-diffraction measurements of the bulk modulus of boron
journal, April 1993

A neutron diffraction study of amorphous boron using a pulsed source
journal, December 1988

The B-Li (Boron-Lithium) system
journal, December 2003

The molecular and electronic structure of Li5B4
journal, September 1979

Dilithium Hexaboride, Li2B6
journal, July 1999

Controlled vesicle deformation and lysis by single oscillating bubbles
journal, May 2003

The Structure Chemistry of Boron-Rich Solids of the Alkali Metals
journal, August 2000

A neutron diffraction study of amorphous boron
journal, September 1988

An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries
journal, January 1998

Ionic high-pressure form of elemental boron
journal, January 2009

Comparison of anodic dischargability of Li-B alloy with pure lithium in LiClO4-propylene carbonate
journal, May 1982

The Electrochemical Reaction of Li with Amorphous Si-Sn Alloys
journal, January 2003

Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO₂ (Anatase) Nanoparticles
journal, October 2007

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Infinite, Linear, Unbranched Borynide Chains in LiBx—Isoelectronic to Polyyne and Polycumulene
journal, July 2000

An unusual phenomenon in the formation of Li5B4 compound-alloy
journal, March 1979

The role and utilization of pseudocapacitance for energy storage by supercapacitors
journal, May 1997

Temperature-dependent lithium storage behavior in tetragonal boron (B50) thin film anode for Li-ion batteries
journal, January 2013

Structure and Bulk Modulus of High-Strength Boron Compounds
journal, October 1997

Investigations of a number of alternative negative electrode materials for use in lithium cells
journal, July 2001

Li ⁺ Ion Insertion in TiO ₂ (Anatase). 2. Voltammetry on Nanoporous Films
journal, September 1997

Electrochemical studies of lithium-boron alloys in non-aqueous media — comparison with pure lithium
journal, May 1989

A Comparison of the Reactions of the SiSn, SiAg, and SiZn Binary Systems with L3i
journal, January 2006

Chemical Composition and Morphology of the Elevated Temperature SEI on Graphite
journal, January 2001

MoS _0.5 Se _1.5 Embedded in 2D Porous Carbon Sheets Boost Lithium Storage Performance as an Anode Material
journal, January 2018

In Situ Synthesis of Mn ₃ O ₄ Nanoparticles on Hollow Carbon Nanofiber as High-Performance Lithium-Ion Battery Anode
journal, June 2018