Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films
Abstract
Here, methylammonium lead iodide (MAPbI3) thin films were examined via piezoresponse force microscopy (PFM) and nanoindentation (NI) to determine if long-range atomic order existed across the full width and depth of the apparent grains. And from the PFM, the piezoelectric response of the films was strongly correlated with low-index planes of the crystal structure and ferroelastic domains in macroscale solution-grown MAPbI3 crystals, which implied long-range order near the top surface. From the NI, it was found that the induced cracks were straight and extended across the full width of the apparent grains, which indicated that the long-range order was not limited to the near-surface region, but extended through the film thickness. Interestingly, the two MAPbI3 processes examined resulted in subtle differences in the extracted electro-mechanical and fracture properties, but exhibited similar power conversion efficiencies of >17% in completed devices.
- Authors:
-
- National Inst. of Standards and Technology (NIST), Boulder, CO (United States). Material Measurement Lab.
- Univ. of Colorado, Boulder, CO (United States). Dept. of Mechanical Engineering
- National Renewable Energy Lab. (NREL), Golden, CO (United States). Chemistry and Nanoscience Center
- Univ. of Colorado, Boulder, CO (United States). Dept. of Mechanical Engineering, Materials Science Program
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; National Institutes of Health (NIH); National Science Foundation (NSF)
- OSTI Identifier:
- 1395493
- Report Number(s):
- NREL/JA-5K00-70187
Journal ID: ISSN 1944-8244; TRN: US1702021
- Grant/Contract Number:
- AC36-08GO28308; T32AG000279; 1338154
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 39; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; ferroelastic domains; grain size; nanoindentation; perovskites; photovoltaic devices; piezoresponse force microscopy
Citation Formats
MacDonald, Gordon A., Heveran, Chelsea M., Yang, Mengjin, Moore, David, Zhu, Kai, Ferguson, Virginia L., Killgore, Jason P., and DelRio, Frank W. Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films. United States: N. p., 2017.
Web. doi:10.1021/acsami.7b11434.
MacDonald, Gordon A., Heveran, Chelsea M., Yang, Mengjin, Moore, David, Zhu, Kai, Ferguson, Virginia L., Killgore, Jason P., & DelRio, Frank W. Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films. United States. https://doi.org/10.1021/acsami.7b11434
MacDonald, Gordon A., Heveran, Chelsea M., Yang, Mengjin, Moore, David, Zhu, Kai, Ferguson, Virginia L., Killgore, Jason P., and DelRio, Frank W. Fri .
"Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films". United States. https://doi.org/10.1021/acsami.7b11434. https://www.osti.gov/servlets/purl/1395493.
@article{osti_1395493,
title = {Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films},
author = {MacDonald, Gordon A. and Heveran, Chelsea M. and Yang, Mengjin and Moore, David and Zhu, Kai and Ferguson, Virginia L. and Killgore, Jason P. and DelRio, Frank W.},
abstractNote = {Here, methylammonium lead iodide (MAPbI3) thin films were examined via piezoresponse force microscopy (PFM) and nanoindentation (NI) to determine if long-range atomic order existed across the full width and depth of the apparent grains. And from the PFM, the piezoelectric response of the films was strongly correlated with low-index planes of the crystal structure and ferroelastic domains in macroscale solution-grown MAPbI3 crystals, which implied long-range order near the top surface. From the NI, it was found that the induced cracks were straight and extended across the full width of the apparent grains, which indicated that the long-range order was not limited to the near-surface region, but extended through the film thickness. Interestingly, the two MAPbI3 processes examined resulted in subtle differences in the extracted electro-mechanical and fracture properties, but exhibited similar power conversion efficiencies of >17% in completed devices.},
doi = {10.1021/acsami.7b11434},
journal = {ACS Applied Materials and Interfaces},
number = 39,
volume = 9,
place = {United States},
year = {Fri Sep 15 00:00:00 EDT 2017},
month = {Fri Sep 15 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Perovskite Solar Cells: From Materials to Devices
journal, October 2014
- Jung, Hyun Suk; Park, Nam-Gyu
- Small, Vol. 11, Issue 1
Solution Chemistry Engineering toward High-Efficiency Perovskite Solar Cells
journal, November 2014
- Zhao, Yixin; Zhu, Kai
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
Impact of microstructure on local carrier lifetime in perovskite solar cells
journal, April 2015
- de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D.
- Science, Vol. 348, Issue 6235
Benefit of Grain Boundaries in Organic–Inorganic Halide Planar Perovskite Solar Cells
journal, February 2015
- Yun, Jae S.; Ho-Baillie, Anita; Huang, Shujuan
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
Methylammonium lead iodide grain boundaries exhibit depth-dependent electrical properties
journal, January 2016
- MacDonald, Gordon A.; Yang, Mengjin; Berweger, Samuel
- Energy & Environmental Science, Vol. 9, Issue 12
Electronic and Morphological Inhomogeneities in Pristine and Deteriorated Perovskite Photovoltaic Films
journal, February 2017
- Berweger, Samuel; MacDonald, Gordon A.; Yang, Mengjin
- Nano Letters, Vol. 17, Issue 3
Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite
journal, July 2016
- Leblebici, Sibel Y.; Leppert, Linn; Li, Yanbo
- Nature Energy, Vol. 1, Issue 8
Defect Tolerance in Methylammonium Lead Triiodide Perovskite
journal, July 2016
- Steirer, K. Xerxes; Schulz, Philip; Teeter, Glenn
- ACS Energy Letters, Vol. 1, Issue 2
Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films
journal, August 2016
- Reid, Obadiah G.; Yang, Mengjin; Kopidakis, Nikos
- ACS Energy Letters, Vol. 1, Issue 3
Square-Centimeter Solution-Processed Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Efficiency Exceeding 15%
journal, September 2015
- Yang, Mengjin; Zhou, Yuanyuan; Zeng, Yining
- Advanced Materials, Vol. 27, Issue 41
Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite
journal, January 2016
- Hermes, Ilka M.; Bretschneider, Simon A.; Bergmann, Victor W.
- The Journal of Physical Chemistry C, Vol. 120, Issue 10
The Role of Chlorine in the Formation Process of “CH 3 NH 3 PbI 3-x Cl x ” Perovskite
journal, September 2014
- Yu, Hui; Wang, Feng; Xie, Fangyan
- Advanced Functional Materials
Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films
journal, October 2014
- Williams, Spencer T.; Zuo, Fan; Chueh, Chu-Chen
- ACS Nano, Vol. 8, Issue 10
Growth and form of spherulites
journal, July 2005
- Gránásy, László; Pusztai, Tamás; Tegze, György
- Physical Review E, Vol. 72, Issue 1
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015
- Nie, W.; Tsai, H.; Asadpour, R.
- Science, Vol. 347, Issue 6221, p. 522-525
Efficient planar heterojunction perovskite solar cells with weak hysteresis fabricated via bar coating
journal, January 2017
- Liu, Xuan; Xia, Xinxin; Cai, Qiuquan
- Solar Energy Materials and Solar Cells, Vol. 159
Dual-frequency resonance-tracking atomic force microscopy
journal, October 2007
- Rodriguez, Brian J.; Callahan, Clint; Kalinin, Sergei V.
- Nanotechnology, Vol. 18, Issue 47, Article No. 475504
CH 3 NH 3 PbI 3 perovskites: Ferroelasticity revealed
journal, April 2017
- Strelcov, Evgheni; Dong, Qingfeng; Li, Tao
- Science Advances, Vol. 3, Issue 4
Direct observation of intrinsic twin domains in tetragonal CH3NH3PbI3
journal, February 2017
- Rothmann, Mathias Uller; Li, Wei; Zhu, Ye
- Nature Communications, Vol. 8, Issue 1
Mechanism for rapid growth of organic–inorganic halide perovskite crystals
journal, November 2016
- Nayak, Pabitra K.; Moore, David T.; Wenger, Bernard
- Nature Communications, Vol. 7, Issue 1
Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide
journal, October 2015
- Brivio, Federico; Frost, Jarvist M.; Skelton, Jonathan M.
- Physical Review B, Vol. 92, Issue 14
Mechanical and thermal properties of physical vapour deposited alumina films Part II Elastic, plastic, fracture, and adhesive behaviour
journal, August 2004
- Thurn, J.; Cook, R. F.
- Journal of Materials Science, Vol. 39, Issue 15
Deformation and fracture of single-crystal silicon theta-like specimens
journal, October 2011
- Gaither, Michael S.; DelRio, Frank W.; Gates, Richard S.
- Journal of Materials Research, Vol. 26, Issue 20
Probing the Soft and Nanoductile Mechanical Nature of Single and Polycrystalline Organic–Inorganic Hybrid Perovskites for Flexible Functional Devices
journal, November 2016
- Yu, Jingui; Wang, Mingchao; Lin, Shangchao
- ACS Nano, Vol. 10, Issue 12
Direct observation of an inhomogeneous chlorine distribution in CH 3 NH 3 PbI 3−x Cl x layers: surface depletion and interface enrichment
journal, January 2015
- Starr, David E.; Sadoughi, Golnaz; Handick, Evelyn
- Energy & Environmental Science, Vol. 8, Issue 5
Elusive Presence of Chloride in Mixed Halide Perovskite Solar Cells
journal, September 2014
- Colella, Silvia; Mosconi, Edoardo; Pellegrino, Giovanna
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 20
Real-Time Nanoscale Open-Circuit Voltage Dynamics of Perovskite Solar Cells
journal, March 2017
- Garrett, Joseph L.; Tennyson, Elizabeth M.; Hu, Miao
- Nano Letters, Vol. 17, Issue 4
Works referencing / citing this record:
Chemical nature of ferroelastic twin domains in CH3NH3PbI3 perovskite
journal, August 2018
- Liu, Yongtao; Collins, Liam; Proksch, Roger
- Nature Materials, Vol. 17, Issue 11
Experimental reconstruction of the contact resonance shape factor for quantification and amplification of bias-induced strain in atomic force microscopy
journal, April 2019
- Killgore, Jason P.; Deolia, Akshay; Robins, Lawrence
- Applied Physics Letters, Vol. 114, Issue 13
Twin domains modulate light-matter interactions in metal halide perovskites
journal, January 2020
- Liu, Yongtao; Li, Mingxing; Wang, Miaosheng
- APL Materials, Vol. 8, Issue 1
Dynamic behavior of CH 3 NH 3 PbI 3 perovskite twin domains
journal, August 2018
- Liu, Yongtao; Collins, Liam; Belianinov, Alex
- Applied Physics Letters, Vol. 113, Issue 7