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Title: The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films

Authors:
 [1];  [1];  [2];  [1];  [3];  [4];  [3];  [4];  [5]; ORCiD logo [6]
  1. Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles CA 90095-1569 USA
  2. Lake Shore Cryotronics, Westerville OH 43082 USA
  3. Materials Science and Engineering Department, University of Washington, Seattle WA 98195-2120 USA
  4. Department of Chemistry, Temple University, Philadelphia PA 19122 USA
  5. Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles CA 90095-1569 USA, Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles CA 90095 USA, California NanoSystems Institute, University of California, Los Angeles, Los Angeles CA 90095 USA
  6. Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles CA 90095-1569 USA, California NanoSystems Institute, University of California, Los Angeles, Los Angeles CA 90095 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1395403
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 27 Journal Issue: 44; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Scholes, D. Tyler, Yee, Patrick Y., Lindemuth, Jeffrey R., Kang, Hyeyeon, Onorato, Jonathan, Ghosh, Raja, Luscombe, Christine K., Spano, Frank C., Tolbert, Sarah H., and Schwartz, Benjamin J. The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films. Germany: N. p., 2017. Web. doi:10.1002/adfm.201702654.
Scholes, D. Tyler, Yee, Patrick Y., Lindemuth, Jeffrey R., Kang, Hyeyeon, Onorato, Jonathan, Ghosh, Raja, Luscombe, Christine K., Spano, Frank C., Tolbert, Sarah H., & Schwartz, Benjamin J. The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films. Germany. doi:10.1002/adfm.201702654.
Scholes, D. Tyler, Yee, Patrick Y., Lindemuth, Jeffrey R., Kang, Hyeyeon, Onorato, Jonathan, Ghosh, Raja, Luscombe, Christine K., Spano, Frank C., Tolbert, Sarah H., and Schwartz, Benjamin J. Wed . "The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films". Germany. doi:10.1002/adfm.201702654.
@article{osti_1395403,
title = {The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films},
author = {Scholes, D. Tyler and Yee, Patrick Y. and Lindemuth, Jeffrey R. and Kang, Hyeyeon and Onorato, Jonathan and Ghosh, Raja and Luscombe, Christine K. and Spano, Frank C. and Tolbert, Sarah H. and Schwartz, Benjamin J.},
abstractNote = {},
doi = {10.1002/adfm.201702654},
journal = {Advanced Functional Materials},
number = 44,
volume = 27,
place = {Germany},
year = {2017},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adfm.201702654

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Cited by: 29 works
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Works referenced in this record:

Sequential Processing for Organic Photovoltaics: Design Rules for Morphology Control by Tailored Semi-Orthogonal Solvent Blends
journal, March 2015

  • Aguirre, Jordan C.; Hawks, Steven A.; Ferreira, Amy S.
  • Advanced Energy Materials, Vol. 5, Issue 11
  • DOI: 10.1002/aenm.201402020

Identifying Atomic Scale Structure in Undoped/Doped Semicrystalline P3HT Using Inelastic Neutron Scattering
journal, March 2017


Infrared signatures of high carrier densities induced in semiconducting poly(3-hexylthiophene) by fluorinated organosilane molecules
journal, June 2010

  • Khatib, O.; Lee, B.; Yuen, J.
  • Journal of Applied Physics, Vol. 107, Issue 12
  • DOI: 10.1063/1.3436567

Aggregates Promote Efficient Charge Transfer Doping of Poly(3-hexylthiophene)
journal, August 2013

  • Gao, Jian; Niles, Edwards T.; Grey, John K.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
  • DOI: 10.1021/jz401555x

Localized Charge Transfer in a Molecularly Doped Conducting Polymer
journal, September 2007

  • Aziz, E. F.; Vollmer, A.; Eisebitt, S.
  • Advanced Materials, Vol. 19, Issue 20, p. 3257-3260
  • DOI: 10.1002/adma.200700926

Organic metals
journal, May 1984

  • Bryce, Martin R.; Murphy, Lynne C.
  • Nature, Vol. 309, Issue 5964
  • DOI: 10.1038/309119a0

Direct observation of charge-induced π -electronic structural changes in a conjugated polymer
journal, October 1989


The Influence of Molecular Configuration on the Thermoelectrical Properties of Poly(3-hexylthiophene)
journal, September 2015


Two-dimensional charge transport in self-organized, high-mobility conjugated polymers
journal, October 1999

  • Sirringhaus, H.; Brown, P. J.; Friend, R. H.
  • Nature, Vol. 401, Issue 6754, p. 685-688
  • DOI: 10.1038/44359

Thermoelectric properties of conducting polymers: The case of poly(3-hexylthiophene)
journal, September 2010


History and recent progress in piezoelectric polymer research
conference, January 1998


Electronic and Vibrational Spectra of Positive Polarons and Bipolarons in Regioregular Poly(3-hexylthiophene) Doped with Ferric Chloride
journal, March 2015

  • Yamamoto, Jun; Furukawa, Yukio
  • The Journal of Physical Chemistry B, Vol. 119, Issue 13
  • DOI: 10.1021/jp512654b

Stability studies of the electrical conductivity of various poly(3-alkylthiophenes)
journal, December 1990


Moderate doping leads to high performance of semiconductor/insulator polymer blend transistors
journal, March 2013

  • Lu, Guanghao; Blakesley, James; Himmelberger, Scott
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2587

Measurement of Small Molecular Dopant F4TCNQ and C 60 F 36 Diffusion in Organic Bilayer Architectures
journal, December 2015

  • Li, Jun; Rochester, Chris W.; Jacobs, Ian E.
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 51
  • DOI: 10.1021/acsami.5b09216

Conduction in glasses containing transition metal ions
journal, December 1968


Development of Semiconducting Polymers for Solar Energy Harvesting
journal, October 2010


Variable temperature Hall measurements on low-mobility materials
conference, October 2012

  • Lindemuth, J.
  • SPIE Solar Energy + Technology, SPIE Proceedings
  • DOI: 10.1117/12.929655

Increasing the Thermoelectric Power Factor of a Semiconducting Polymer by Doping from the Vapor Phase
journal, February 2016


Controlling Electrical Properties of Conjugated Polymers via a Solution-Based p-Type Doping
journal, September 2008

  • Yim, Keng-Hoong; Whiting, Gregory L.; Murphy, Craig E.
  • Advanced Materials, Vol. 20, Issue 17, p. 3319-3324
  • DOI: 10.1002/adma.200800735

Effect of molecular electrical doping on polyfuran based photovoltaic cells
journal, May 2015

  • Yu, Shuwen; Frisch, Johannes; Opitz, Andreas
  • Applied Physics Letters, Vol. 106, Issue 20
  • DOI: 10.1063/1.4921484

Enhanced Charge Transfer Doping Efficiency in J-Aggregate Poly(3-hexylthiophene) Nanofibers
journal, June 2015

  • Gao, Jian; Stein, Benjamin W.; Thomas, Alan K.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 28
  • DOI: 10.1021/acs.jpcc.5b05191

Towards polymer-based organic thermoelectric generators
journal, January 2012

  • Bubnova, Olga; Crispin, Xavier
  • Energy & Environmental Science, Vol. 5, Issue 11
  • DOI: 10.1039/c2ee22777k

A general relationship between disorder, aggregation and charge transport in conjugated polymers
journal, August 2013

  • Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen
  • Nature Materials, Vol. 12, Issue 11
  • DOI: 10.1038/nmat3722

The effect of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane charge transfer dopants on the conformation and aggregation of poly(3-hexylthiophene)
journal, January 2013

  • Gao, Jian; Roehling, John D.; Li, Yongle
  • Journal of Materials Chemistry C, Vol. 1, Issue 36
  • DOI: 10.1039/c3tc31047g

Conjugated Polymer-Based Organic Solar Cells
journal, April 2007

  • Günes, Serap; Neugebauer, Helmut; Sariciftci, Niyazi Serdar
  • Chemical Reviews, Vol. 107, Issue 4, p. 1324-1338
  • DOI: 10.1021/cr050149z

Externally Initiated Regioregular P3HT with Controlled Molecular Weight and Narrow Polydispersity
journal, September 2009

  • Bronstein, Hugo A.; Luscombe, Christine K.
  • Journal of the American Chemical Society, Vol. 131, Issue 36
  • DOI: 10.1021/ja9054977

Molecular Electrical Doping of Organic Semiconductors: Fundamental Mechanisms and Emerging Dopant Design Rules
journal, February 2016


High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends
journal, October 2005

  • Li, Gang; Shrotriya, Vishal; Huang, Jinsong
  • Nature Materials, Vol. 4, Issue 11, p. 864-868
  • DOI: 10.1038/nmat1500

Increasing Polymer Solar Cell Fill Factor by Trap-Filling with F4-TCNQ at Parts Per Thousand Concentration
journal, May 2016

  • Yan, Han; Manion, Joseph G.; Yuan, Mingjian
  • Advanced Materials, Vol. 28, Issue 30
  • DOI: 10.1002/adma.201601553

Electrical Conduction of Regioregular and Regiorandom Poly(3-hexylthiophene) Doped with Iodine
journal, December 2005

  • Ukai, Sota; Ito, Hiroshi; Marumoto, Kazuhiro
  • Journal of the Physical Society of Japan, Vol. 74, Issue 12
  • DOI: 10.1143/JPSJ.74.3314

Direct Observation of Doping Sites in Temperature-Controlled, p-Doped P3HT Thin Films by Conducting Atomic Force Microscopy
journal, July 2014


Soluble and processable regioregular poly(3‐hexylthiophene) for thin film field‐effect transistor applications with high mobility
journal, December 1996

  • Bao, Zhenan; Dodabalapur, Ananth; Lovinger, Andrew J.
  • Applied Physics Letters, Vol. 69, Issue 26, p. 4108-4110
  • DOI: 10.1063/1.117834

Mechanism of Dedoping Processes of Conducting Poly(3-alkylthiophenes)
journal, August 2005

  • Koizumi, Hitoshi; Dougauchi, Hiroshi; Ichikawa, Tsuneki
  • The Journal of Physical Chemistry B, Vol. 109, Issue 32
  • DOI: 10.1021/jp051989k

Integrated Optoelectronic Devices Based on Conjugated Polymers
journal, June 1998


Doped Organic Transistors
journal, October 2016


Imaging of morphological changes and phase segregation in doped polymeric semiconductors
journal, January 2015


Depositing Fullerenes in Swollen Polymer Layers via Sequential Processing of Organic Solar Cells
journal, May 2015

  • van Franeker, Jacobus J.; Kouijzer, Sandra; Lou, Xianwen
  • Advanced Energy Materials, Vol. 5, Issue 14
  • DOI: 10.1002/aenm.201500464

Micromorphology, photophysical and electrical properties of pristine and ferric chloride doped poly(3-hexylthiophene) films
journal, August 2007


Device Physics of Solution-Processed Organic Field-Effect Transistors
journal, October 2005


Hopping transport and the Hall effect near the insulator–metal transition in electrochemically gated poly(3-hexylthiophene) transistors
journal, January 2012

  • Wang, Shun; Ha, Mingjing; Manno, Michael
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms2213

Crystallinity Effects in Sequentially Processed and Blend-Cast Bulk-Heterojunction Polymer/Fullerene Photovoltaics
journal, July 2014

  • Zhang, Guangye; Huber, Rachel C.; Ferreira, Amy S.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 32
  • DOI: 10.1021/jp5054315

Charge carrier coherence and Hall effect in organic semiconductors
journal, March 2016

  • Yi, H. T.; Gartstein, Y. N.; Podzorov, V.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep23650

25th Anniversary Article: Organic Field-Effect Transistors: The Path Beyond Amorphous Silicon
journal, January 2014


Comparison of solution-mixed and sequentially processed P3HT:F4TCNQ films: effect of doping-induced aggregation on film morphology
journal, January 2016

  • Jacobs, Ian E.; Aasen, Erik W.; Oliveira, Julia L.
  • J. Mater. Chem. C, Vol. 4, Issue 16
  • DOI: 10.1039/C5TC04207K

The effect of thermal annealing on dopant site choice in conjugated polymers
journal, June 2016


Charge-transfer crystallites as molecular electrical dopants
journal, October 2015

  • Méndez, Henry; Heimel, Georg; Winkler, Stefanie
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9560

An organic p-type dopant with high thermal stability for an organic semiconductor
journal, January 2008

  • Gao, Zhi Qiang; Mi, Bao Xiu; Xu, Gui Zhen
  • Chem. Commun., Issue 1
  • DOI: 10.1039/B713566A

Polaron Delocalization in Conjugated Polymer Films
journal, May 2016

  • Ghosh, Raja; Pochas, Christopher M.; Spano, Frank C.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 21
  • DOI: 10.1021/acs.jpcc.6b02917

Impact of the Doping Method on Conductivity and Thermopower in Semiconducting Polythiophenes
journal, October 2014

  • Glaudell, Anne M.; Cochran, Justin E.; Patel, Shrayesh N.
  • Advanced Energy Materials, Vol. 5, Issue 4
  • DOI: 10.1002/aenm.201401072

How intermolecular geometrical disorder affects the molecular doping of donor–acceptor copolymers
journal, March 2015

  • Di Nuzzo, Daniele; Fontanesi, Claudio; Jones, Rebecca
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7460

Modeling disorder in polymer aggregates: The optical spectroscopy of regioregular poly(3-hexylthiophene) thin films
journal, June 2005

  • Spano, Frank C.
  • The Journal of Chemical Physics, Vol. 122, Issue 23
  • DOI: 10.1063/1.1914768

Molecular Doping Enhances Photoconductivity in Polymer Bulk Heterojunction Solar Cells
journal, September 2013

  • Zhang, Yuan; Zhou, Huiqiong; Seifter, Jason
  • Advanced Materials, Vol. 25, Issue 48
  • DOI: 10.1002/adma.201302159

Charge-Transfer–Solvent Interaction Predefines Doping Efficiency in p-Doped P3HT Films
journal, June 2016


Bulk Heterojunction versus Diffused Bilayer: The Role of Device Geometry in Solution p-Doped Polymer-Based Solar Cells
journal, July 2012

  • Loiudice, Anna; Rizzo, Aurora; Biasiucci, Mariano
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 14
  • DOI: 10.1021/jz300754p

Introducing Solubility Control for Improved Organic P-Type Dopants
journal, August 2015


Reappraising the Need for Bulk Heterojunctions in Polymer−Fullerene Photovoltaics: The Role of Carrier Transport in All-Solution-Processed P3HT/PCBM Bilayer Solar Cells
journal, October 2009

  • Ayzner, Alexander L.; Tassone, Christopher J.; Tolbert, Sarah H.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 46
  • DOI: 10.1021/jp9050897

Charge Transport in Organic Semiconductors
journal, April 2007

  • Coropceanu, Veaceslav; Cornil, Jérôme; da Silva Filho, Demetrio A.
  • Chemical Reviews, Vol. 107, Issue 4
  • DOI: 10.1021/cr050140x

Hall measurements on low-mobility materials and high resistivity materials
conference, September 2011

  • Lindemuth, Jeffrey; Mizuta, Shin-Ichiro
  • SPIE Solar Energy + Technology, SPIE Proceedings
  • DOI: 10.1117/12.893100

Infrared photoexcitation and doping studies of poly(3-methylthienylene)
journal, November 1987


Microstructural Characterization and Charge Transport in Thin Films of Conjugated Polymers
journal, July 2010

  • Salleo, Alberto; Kline, R. Joseph; DeLongchamp, Dean M.
  • Advanced Materials, Vol. 22, Issue 34
  • DOI: 10.1002/adma.200903712

Doping effect of dodecyl benzene sulphonic acid in poly(3-hexylthiophene)-P3HT-films
journal, April 2015


Doping of Conjugated Polythiophenes with Alkyl Silanes
journal, June 2009

  • Kao, Chi Yueh; Lee, Bumsu; Wielunski, Leszek S.
  • Advanced Functional Materials, Vol. 19, Issue 12, p. 1906-1911
  • DOI: 10.1002/adfm.200900120

Optical measurement of doping efficiency in poly(3-hexylthiophene) solutions and thin films
journal, February 2015


Molecular Interactions and Ordering in Electrically Doped Polymers: Blends of PBTTT and F 4 TCNQ
journal, September 2014

  • Cochran, Justin E.; Junk, Matthias J. N.; Glaudell, A. M.
  • Macromolecules, Vol. 47, Issue 19
  • DOI: 10.1021/ma501547h

Charge Transfer in Molecular Complexes with 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F 4 -TCNQ): A Density Functional Theory Study
journal, December 2011

  • Zhu, Lingyun; Kim, Eung-Gun; Yi, Yuanping
  • Chemistry of Materials, Vol. 23, Issue 23
  • DOI: 10.1021/cm201798x

Light-emitting diodes based on conjugated polymers
journal, October 1990

  • Burroughes, J. H.; Bradley, D. D. C.; Brown, A. R.
  • Nature, Vol. 347, Issue 6293
  • DOI: 10.1038/347539a0

Coulomb gap and low temperature conductivity of disordered systems
journal, February 1975


2D coherent charge transport in highly ordered conducting polymers doped by solid state diffusion
journal, May 2016

  • Kang, Keehoon; Watanabe, Shun; Broch, Katharina
  • Nature Materials, Vol. 15, Issue 8
  • DOI: 10.1038/nmat4634

Overcoming Film Quality Issues for Conjugated Polymers Doped with F 4 TCNQ by Solution Sequential Processing: Hall Effect, Structural, and Optical Measurements
journal, November 2015

  • Scholes, D. Tyler; Hawks, Steven A.; Yee, Patrick Y.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 23
  • DOI: 10.1021/acs.jpclett.5b02332

Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions
journal, December 1995


The poly‐3‐hexylthiophene/NOPF 6 system: A photoelectron spectroscopy study of electronic structural changes induced by the charge transfer in the solid state
journal, September 1990

  • Lazzaroni, R.; Lögdlund, M.; Stafström, S.
  • The Journal of Chemical Physics, Vol. 93, Issue 6
  • DOI: 10.1063/1.458725

Comparing Matched Polymer:Fullerene Solar Cells Made by Solution-Sequential Processing and Traditional Blend Casting: Nanoscale Structure and Device Performance
journal, July 2014

  • Hawks, Steven A.; Aguirre, Jordan C.; Schelhas, Laura T.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 31
  • DOI: 10.1021/jp504560r

Effects of Thermal Annealing Upon the Morphology of Polymer-Fullerene Blends
journal, August 2010

  • Verploegen, Eric; Mondal, Rajib; Bettinger, Christopher J.
  • Advanced Functional Materials, Vol. 20, Issue 20
  • DOI: 10.1002/adfm.201000975

Analytic model of carrier mobility in doped disordered organic semiconductors
journal, December 2005


Effect of Mesoscale Crystalline Structure on the Field-Effect Mobility of Regioregular Poly(3-hexyl thiophene) in Thin-Film Transistors
journal, April 2005


New insights on the nature of two-dimensional polarons in semiconducting polymers: Infrared absorption in poly(3-hexylthiophene)
journal, June 2014

  • Pochas, Christopher M.; Spano, Frank C.
  • The Journal of Chemical Physics, Vol. 140, Issue 24
  • DOI: 10.1063/1.4882696

Effect of Regioregularity on Charge Transport and Structural and Excitonic Coherence in Poly(3-hexylthiophene) Nanowires
journal, June 2015

  • Mazzio, Katherine A.; Rice, Andrew H.; Durban, Mathew M.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 27
  • DOI: 10.1021/acs.jpcc.5b02914

Understanding How Polymer Properties Control OPV Device Performance: Regioregularity, Swelling, and Morphology Optimization Using Random Poly(3-butylthiophene- co -3-octylthiophene) Polymers
journal, September 2016

  • Ferreira, Amy S.; Aguirre, Jordan C.; Subramaniyan, Selvam
  • The Journal of Physical Chemistry C, Vol. 120, Issue 39
  • DOI: 10.1021/acs.jpcc.6b03300

Toward a comprehensive understanding of molecular doping organic semiconductors (review)
journal, October 2015


Enhanced Mobility of Poly(3-hexylthiophene) Transistors by Spin-Coating from High-Boiling-Point Solvents
journal, November 2004

  • Chang, Jui-Fen; Sun, Baoquan; Breiby, Dag W.
  • Chemistry of Materials, Vol. 16, Issue 23, p. 4772-4776
  • DOI: 10.1021/cm049617w

Comprehensive picture of p -type doping of P3HT with the molecular acceptor F 4 TCNQ
journal, March 2013


Atomistic simulation on charge mobility of amorphous tris(8-hydroxyquinoline) aluminum (Alq3): Origin of Poole–Frenkel–type behavior
journal, July 2008

  • Nagata, Yuki; Lennartz, Christian
  • The Journal of Chemical Physics, Vol. 129, Issue 3
  • DOI: 10.1063/1.2949506

Confined and delocalized polarons in π -conjugated oligomers and polymers: A study of the effective conjugation length
journal, June 2004


High-Resolution ac Measurements of the Hall Effect in Organic Field-Effect Transistors
journal, March 2016


Enhanced performance of inverted organic solar cell by a solution-based fluorinated acceptor doped P3HT:PCBM layer
journal, April 2013


Determining exciton bandwidth and film microstructure in polythiophene films using linear absorption spectroscopy
journal, April 2009

  • Clark, Jenny; Chang, Jui-Fen; Spano, Frank C.
  • Applied Physics Letters, Vol. 94, Issue 16, Article No. 163306
  • DOI: 10.1063/1.3110904

Optical spectroscopy of field-induced charge in self-organized high mobility poly(3-hexylthiophene)
journal, March 2001


The chemical and structural origin of efficient p-type doping in P3HT
journal, May 2013