Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst

Wang, Xiaoxing; Hu, Xiaoyan; Song, Chunshan; Lux, Kenneth W.; Namazian, Mehdi; Imam, Tahmina

doi:10.1021/acs.iecr.7b02316

Title: Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst

Abstract

As a part of a new approach to convert biomass to liquid fuels, we investigated the effects of alkali treatment on the property and performance of HZSM-5 for oligomerization of biomass-derived ethylene under atmospheric pressure. The characterization results showed that alkali treatment led to the increase in the total and mesopore volumes, but decrease in the surface area and micropore volume. Furthermore, when NaOH concentration was low (< 0.5 M), the ZSM-5 structure was largely preserved with the increase in the mesopores and acidity, while higher NaOH concentration can severely destroy the zeolite structure, resulting in a significant reduction in the micropores and acidity. The ethylene oligomerization results showed that not only the ethylene conversion and the liquid yield increased, but also the catalyst stability was improved after proper NaOH treatment. Finally, we discussed the relationship between the structure and performance

Authors:

^[1]; Hu, Xiaoyan ^[1];

^[2]; Lux, Kenneth W. ^[3]; Namazian, Mehdi ^[3]; Imam, Tahmina ^[3]

Pennsylvania State Univ., University Park, PA (United States). Joint Center for Energy Research, EMS Energy Inst., Dept. of Energy and Mineral Engineering
Pennsylvania State Univ., University Park, PA (United States). Joint Center for Energy Research, EMS Energy Inst., Dept. of Energy and Mineral Engineering, Dept. of Chemical Engineering
Altex Technologies Corporation, Sunnyvale, CA (United States)

Publication Date:: 2017-09-27

Research Org.:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1395007

Grant/Contract Number:: FE0010427; SC0006466; FE0023663; W911SR-11-C-0018

Resource Type:: Accepted Manuscript

Journal Name:: Industrial and Engineering Chemistry Research

Additional Journal Information:: Journal Volume: 56; Journal Issue: 42; Journal ID: ISSN 0888-5885

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; biomass; mesoporous HZSM-5; zeolite; alkali treatment; ethylene oligomerization; catalysis

Citation Formats


                    Wang, Xiaoxing, Hu, Xiaoyan, Song, Chunshan, Lux, Kenneth W., Namazian, Mehdi, and Imam, Tahmina. Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst.  United States: N. p., 2017. 
Web.  doi:10.1021/acs.iecr.7b02316.

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                    Wang, Xiaoxing, Hu, Xiaoyan, Song, Chunshan, Lux, Kenneth W., Namazian, Mehdi, & Imam, Tahmina. Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst.  United States.  https://doi.org/10.1021/acs.iecr.7b02316

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                    Wang, Xiaoxing, Hu, Xiaoyan, Song, Chunshan, Lux, Kenneth W., Namazian, Mehdi, and Imam, Tahmina. Wed .  
"Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst".  United States.  https://doi.org/10.1021/acs.iecr.7b02316.  https://www.osti.gov/servlets/purl/1395007.

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@article{osti_1395007,

  title        = {Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst},

  author       = {Wang, Xiaoxing and Hu, Xiaoyan and Song, Chunshan and Lux, Kenneth W. and Namazian, Mehdi and Imam, Tahmina},

  abstractNote = {As a part of a new approach to convert biomass to liquid fuels, we investigated the effects of alkali treatment on the property and performance of HZSM-5 for oligomerization of biomass-derived ethylene under atmospheric pressure. The characterization results showed that alkali treatment led to the increase in the total and mesopore volumes, but decrease in the surface area and micropore volume. Furthermore, when NaOH concentration was low (< 0.5 M), the ZSM-5 structure was largely preserved with the increase in the mesopores and acidity, while higher NaOH concentration can severely destroy the zeolite structure, resulting in a significant reduction in the micropores and acidity. The ethylene oligomerization results showed that not only the ethylene conversion and the liquid yield increased, but also the catalyst stability was improved after proper NaOH treatment. Finally, we discussed the relationship between the structure and performance},

  doi          = {10.1021/acs.iecr.7b02316},

  journal      = {Industrial and Engineering Chemistry Research},

  number       = 42,

  volume       = 56,

  place        = {United States},

  year         = {2017},

  month        = {9}

}

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Works referencing / citing this record:

Ethylene Oligomerization over Nickel Supported Silica-Alumina Catalysts with High Selectivity for C10+ Products
journal, February 2020

Chen, Lei; Li, Guangci; Wang, Zhong
Catalysts, Vol. 10, Issue 2
DOI: 10.3390/catal10020180

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Title: Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment of HZSM-5 Catalyst

Abstract

Citation Formats

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal, September 2006

Chemical Routes for the Transformation of Biomass into Chemicals journal, June 2007

Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes journal, October 2008

The critical role of heterogeneous catalysis in lignocellulosic biomass conversion journal, January 2009

Fuel Ethanol from Cellulosic Biomass journal, March 1991

Ni-exchanged AlMCM-41—An efficient bifunctional catalyst for ethylene oligomerization journal, July 2004

Nickel-based solid catalysts for ethylene oligomerization – a review journal, January 2014

Light olefins dimerization to high quality gasoline components journal, February 2001

Propene oligomerization over Ni-exchanged Na-X zeolites journal, December 2012

Selective production of olefins from bioethanol on HZSM-5 zeolite catalysts treated with NaOH journal, June 2010

New bifunctional Ni–H-Beta catalysts for the heterogeneous oligomerization of ethylene journal, October 2013

Alkene oligomerization journal, January 1990

Olefin oligomerization via zeolite catalysis journal, January 1994

Conversion of propene into gasoline and middle distillate using alkalised ZSM-5 zeolite catalysts journal, January 1988

Oligomerization of ethene over nickel-exchanged zeolite y into a diesel-range product journal, September 1988

Propylene oligomerization over molecular sieves journal, August 1985

Conversion of propylene and butylene over ZSM-5 catalyst journal, September 1986

Catalytic oligomerization of ethylene over Ni-containing dealuminated Y zeolites journal, February 2006

Heterogeneous oligomerization of ethylene over highly active and stable Ni-AlSBA-15 mesoporous catalysts journal, March 2015

Mossgas “gas-to-liquid” diesel fuels—an environmentally friendly option journal, January 2002

Chemistry of olefin oligomerization over ZSM-5 catalyst journal, April 1988

Low temperature conversion of linear C4 olefins with acid ZSM-5 zeolites of homogeneous composition journal, January 2012

Ethylene dimerization over modified nickel exchanged Y-zeolite journal, November 1994

The oligomerization of butenes with partially alkali exchanged NiNaY zeolite catalysts journal, September 1997

Hierarchical Zeolites: A Proven Strategy to Combine Shape Selectivity with Efficient Mass Transport journal, November 2004

Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design journal, January 2008

Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores journal, October 2010

Hierarchically structured zeolites: synthesis, mass transport properties and applications journal, January 2012

Mesopore-Modified Zeolites: Preparation, Characterization, and Applications journal, March 2006

Alkali-treatment technique — new method for modification of structural and acid-catalytic properties of ZSM-5 zeolites journal, October 2001

Formation of Uniform Mesopores in ZSM-5 Zeolite upon Alkaline Post-treatment? journal, January 2002

Direct Demonstration of Enhanced Diffusion in Mesoporous ZSM-5 Zeolite Obtained via Controlled Desilication journal, January 2007

An effective method to enhance the stability on-stream of butene aromatization: Post-treatment of ZSM-5 by alkali solution of sodium hydroxide journal, March 2006

Aromatization and isomerization of 1-hexene over alkali-treated HZSM-5 zeolites: Improved reaction stability journal, April 2008

Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH journal, July 2008

Selective Transformation of Syngas into Gasoline-Range Hydrocarbons over Mesoporous H-ZSM-5-Supported Cobalt Nanoparticles journal, November 2014

Characterization of nanocrystalline zeolite Beta journal, December 1998

Measurement of the acidity of various zeolites by temperature-programmed desorption of ammonia journal, February 1984

Determination of the Acidic Properties of Zeolite by Theoretical Analysis of Temperature-Programmed Desorption of Ammonia Based on Adsorption Equilibrium journal, July 1997

Oligomerization of .alpha.-olefins to higher oligomers journal, June 1991

IR study of ethene and propene oligomerization on H-ZSM-5: hydrogen-bonded precursor formation, initiation and propagation mechanisms and structure of the entrapped oligomers journal, January 1994

The effect of dealumination on the apparent and actual rates of aromatization of methane over MFI-supported molybdenum catalysts journal, August 2004

Dealumination of HZSM-5 zeolites: Effect of steaming on acidity and aromatization activity journal, June 1997

Low-temperature steam reforming of jet fuel in the absence and presence of sulfur over Rh and Rh–Ni catalysts for fuel cells journal, March 2006

Ethylene Oligomerization over Nickel Supported Silica-Alumina Catalysts with High Selectivity for C10+ Products journal, February 2020

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006

Chemical Routes for the Transformation of Biomass into Chemicals
journal, June 2007

Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes
journal, October 2008

The critical role of heterogeneous catalysis in lignocellulosic biomass conversion
journal, January 2009

Fuel Ethanol from Cellulosic Biomass
journal, March 1991

Ni-exchanged AlMCM-41—An efficient bifunctional catalyst for ethylene oligomerization
journal, July 2004

Nickel-based solid catalysts for ethylene oligomerization – a review
journal, January 2014

Light olefins dimerization to high quality gasoline components
journal, February 2001

Propene oligomerization over Ni-exchanged Na-X zeolites
journal, December 2012

Selective production of olefins from bioethanol on HZSM-5 zeolite catalysts treated with NaOH
journal, June 2010

New bifunctional Ni–H-Beta catalysts for the heterogeneous oligomerization of ethylene
journal, October 2013

Alkene oligomerization
journal, January 1990

Olefin oligomerization via zeolite catalysis
journal, January 1994

Conversion of propene into gasoline and middle distillate using alkalised ZSM-5 zeolite catalysts
journal, January 1988

Oligomerization of ethene over nickel-exchanged zeolite y into a diesel-range product
journal, September 1988

Propylene oligomerization over molecular sieves
journal, August 1985

Conversion of propylene and butylene over ZSM-5 catalyst
journal, September 1986

Catalytic oligomerization of ethylene over Ni-containing dealuminated Y zeolites
journal, February 2006

Heterogeneous oligomerization of ethylene over highly active and stable Ni-AlSBA-15 mesoporous catalysts
journal, March 2015

Mossgas “gas-to-liquid” diesel fuels—an environmentally friendly option
journal, January 2002

Chemistry of olefin oligomerization over ZSM-5 catalyst
journal, April 1988

Low temperature conversion of linear C4 olefins with acid ZSM-5 zeolites of homogeneous composition
journal, January 2012

Ethylene dimerization over modified nickel exchanged Y-zeolite
journal, November 1994

The oligomerization of butenes with partially alkali exchanged NiNaY zeolite catalysts
journal, September 1997

Hierarchical Zeolites: A Proven Strategy to Combine Shape Selectivity with Efficient Mass Transport
journal, November 2004

Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design
journal, January 2008

Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores
journal, October 2010

Hierarchically structured zeolites: synthesis, mass transport properties and applications
journal, January 2012

Mesopore-Modified Zeolites: Preparation, Characterization, and Applications
journal, March 2006

Alkali-treatment technique — new method for modification of structural and acid-catalytic properties of ZSM-5 zeolites
journal, October 2001

Formation of Uniform Mesopores in ZSM-5 Zeolite upon Alkaline Post-treatment?
journal, January 2002

Direct Demonstration of Enhanced Diffusion in Mesoporous ZSM-5 Zeolite Obtained via Controlled Desilication
journal, January 2007

An effective method to enhance the stability on-stream of butene aromatization: Post-treatment of ZSM-5 by alkali solution of sodium hydroxide
journal, March 2006

Aromatization and isomerization of 1-hexene over alkali-treated HZSM-5 zeolites: Improved reaction stability
journal, April 2008

Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH
journal, July 2008

Selective Transformation of Syngas into Gasoline-Range Hydrocarbons over Mesoporous H-ZSM-5-Supported Cobalt Nanoparticles
journal, November 2014

Characterization of nanocrystalline zeolite Beta
journal, December 1998

Measurement of the acidity of various zeolites by temperature-programmed desorption of ammonia
journal, February 1984

Determination of the Acidic Properties of Zeolite by Theoretical Analysis of Temperature-Programmed Desorption of Ammonia Based on Adsorption Equilibrium
journal, July 1997

Oligomerization of .alpha.-olefins to higher oligomers
journal, June 1991

IR study of ethene and propene oligomerization on H-ZSM-5: hydrogen-bonded precursor formation, initiation and propagation mechanisms and structure of the entrapped oligomers
journal, January 1994

The effect of dealumination on the apparent and actual rates of aromatization of methane over MFI-supported molybdenum catalysts
journal, August 2004

Dealumination of HZSM-5 zeolites: Effect of steaming on acidity and aromatization activity
journal, June 1997

Low-temperature steam reforming of jet fuel in the absence and presence of sulfur over Rh and Rh–Ni catalysts for fuel cells
journal, March 2006

Ethylene Oligomerization over Nickel Supported Silica-Alumina Catalysts with High Selectivity for C10+ Products
journal, February 2020