DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds

Abstract

Disulfide exchange and thiol–disulfide interchange reactions allow for reprocessing and recycling of azobenzene-based liquid crystalline networks.

Authors:
 [1];  [1];  [2];  [2]; ORCiD logo [3]
  1. Washington State Univ., Pullman, WA (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Washington State Univ., Pullman, WA (United States); North Dakota State Univ., Fargo, ND (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office
OSTI Identifier:
1399940
Alternate Identifier(s):
OSTI ID: 1394560
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
RSC Advances
Additional Journal Information:
Journal Volume: 7; Journal Issue: 59; Journal ID: ISSN 2046-2069
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Li, Yuzhan, Zhang, Yuehong, Rios, Orlando, Keum, Jong K., and Kessler, Michael R. Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds. United States: N. p., 2017. Web. doi:10.1039/C7RA06343A.
Li, Yuzhan, Zhang, Yuehong, Rios, Orlando, Keum, Jong K., & Kessler, Michael R. Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds. United States. https://doi.org/10.1039/C7RA06343A
Li, Yuzhan, Zhang, Yuehong, Rios, Orlando, Keum, Jong K., and Kessler, Michael R. Thu . "Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds". United States. https://doi.org/10.1039/C7RA06343A. https://www.osti.gov/servlets/purl/1399940.
@article{osti_1399940,
title = {Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds},
author = {Li, Yuzhan and Zhang, Yuehong and Rios, Orlando and Keum, Jong K. and Kessler, Michael R.},
abstractNote = {Disulfide exchange and thiol–disulfide interchange reactions allow for reprocessing and recycling of azobenzene-based liquid crystalline networks.},
doi = {10.1039/C7RA06343A},
journal = {RSC Advances},
number = 59,
volume = 7,
place = {United States},
year = {Thu Jul 27 00:00:00 EDT 2017},
month = {Thu Jul 27 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 38 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Multifunctional Shape-Memory Polymers
journal, June 2010

  • Behl, Marc; Razzaq, Muhammad Yasar; Lendlein, Andreas
  • Advanced Materials, Vol. 22, Issue 31
  • DOI: 10.1002/adma.200904447

Torsional mechanical responses in azobenzene functionalized liquid crystalline polymer networks
journal, January 2013

  • Wie, Jeong Jae; Lee, Kyung Min; Smith, Matthew L.
  • Soft Matter, Vol. 9, Issue 39
  • DOI: 10.1039/c3sm51574e

Light-triggered self-healing and shape-memory polymers
journal, January 2013

  • Habault, Damien; Zhang, Hongji; Zhao, Yue
  • Chemical Society Reviews, Vol. 42, Issue 17
  • DOI: 10.1039/c3cs35489j

Photodriven, Flexural-Torsional Oscillation of Glassy Azobenzene Liquid Crystal Polymer Networks
journal, June 2011

  • Lee, Kyung Min; Smith, Matthew L.; Koerner, Hilmar
  • Advanced Functional Materials, Vol. 21, Issue 15
  • DOI: 10.1002/adfm.201100333

Mouldable liquid-crystalline elastomer actuators with exchangeable covalent bonds
journal, December 2013

  • Pei, Zhiqiang; Yang, Yang; Chen, Qiaomei
  • Nature Materials, Vol. 13, Issue 1
  • DOI: 10.1038/nmat3812

Disulfide Bonds and Protein Folding
journal, April 2000

  • Wedemeyer, William J.; Welker, Ervin; Narayan, Mahesh
  • Biochemistry, Vol. 39, Issue 15
  • DOI: 10.1021/bi992922o

Photoresponsive Liquid Crystalline Epoxy Networks with Shape Memory Behavior and Dynamic Ester Bonds
journal, June 2016

  • Li, Yuzhan; Rios, Orlando; Keum, Jong K.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 24
  • DOI: 10.1021/acsami.6b04374

Shape Memory Effect Exhibited by Smectic-C Liquid Crystalline Elastomers
journal, December 2003

  • Rousseau, Ingrid A.; Mather, Patrick T.
  • Journal of the American Chemical Society, Vol. 125, Issue 50
  • DOI: 10.1021/ja039001s

Printed artificial cilia from liquid-crystal network actuators modularly driven by light
journal, June 2009

  • van Oosten, Casper L.; Bastiaansen, Cees W. M.; Broer, Dirk J.
  • Nature Materials, Vol. 8, Issue 8
  • DOI: 10.1038/nmat2487

Polarization-controlled, photodriven bending in monodomain liquid crystal elastomer cantilevers
journal, January 2009

  • White, Timothy J.; Serak, Svetlana V.; Tabiryan, Nelson V.
  • J. Mater. Chem., Vol. 19, Issue 8
  • DOI: 10.1039/B818457G

Exploiting Microphase-Separated Morphologies of Side-Chain Liquid Crystalline Polymer Networks for Triple Shape Memory Properties
journal, September 2011

  • Ahn, Suk-kyun; Kasi, Rajeswari M.
  • Advanced Functional Materials, Vol. 21, Issue 23
  • DOI: 10.1002/adfm.201101369

Photomechanics of Liquid-Crystalline Elastomers and Other Polymers
journal, January 2007

  • Ikeda, Tomiki; Mamiya, Jun-ichi; Yu, Yanlei
  • Angewandte Chemie International Edition, Vol. 46, Issue 4
  • DOI: 10.1002/anie.200602372

Soft Actuators Based on Liquid-Crystalline Elastomers
journal, August 2006

  • Yu, Yanlei; Ikeda, Tomiki
  • Angewandte Chemie International Edition, Vol. 45, Issue 33
  • DOI: 10.1002/anie.200601760

Reversible actuation in main-chain liquid crystalline elastomers with varying crosslink densities
journal, November 2014


Making and Remaking Dynamic 3D Structures by Shining Light on Flat Liquid Crystalline Vitrimer Films without a Mold
journal, February 2016

  • Yang, Yang; Pei, Zhiqiang; Li, Zhen
  • Journal of the American Chemical Society, Vol. 138, Issue 7
  • DOI: 10.1021/jacs.5b12531

Nematic main-chain elastomers: Coupling and orientational behavior
journal, January 2009


Room-Temperature Self-Healable and Remoldable Cross-linked Polymer Based on the Dynamic Exchange of Disulfide Bonds
journal, March 2014

  • Lei, Zhou Qiao; Xiang, Hong Ping; Yuan, Yong Jian
  • Chemistry of Materials, Vol. 26, Issue 6
  • DOI: 10.1021/cm4040616

Programmed morphing of liquid crystal networks
journal, November 2014


Polysiloxane-Based Liquid Crystalline Polymers and Elastomers Prepared by Thiol–Ene Chemistry
journal, April 2013

  • Yang, Hong; Liu, Ming-Xia; Yao, Yue-Wei
  • Macromolecules, Vol. 46, Issue 9
  • DOI: 10.1021/ma400462e

Controlled degradation of disulfide-based epoxy thermosets for extreme environments
journal, May 2015


Using the dynamic bond to access macroscopically responsive structurally dynamic polymers
journal, December 2010

  • Wojtecki, Rudy J.; Meador, Michael A.; Rowan, Stuart J.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2891

Dynamic Covalent Polymers via Inverse Vulcanization of Elemental Sulfur for Healable Infrared Optical Materials
journal, August 2015


Light to work transduction and shape memory in glassy, photoresponsive macromolecular systems: Trends and opportunities
journal, April 2012

  • White, Timothy J.
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 50, Issue 13
  • DOI: 10.1002/polb.23079

Liquid Crystalline Elastomers as Actuators and Sensors
journal, May 2010

  • Ohm, Christian; Brehmer, Martin; Zentel, Rudolf
  • Advanced Materials, Vol. 22, Issue 31
  • DOI: 10.1002/adma.200904059

Programmable and adaptive mechanics with liquid crystal polymer networks and elastomers
journal, October 2015

  • White, Timothy J.; Broer, Dirk J.
  • Nature Materials, Vol. 14, Issue 11
  • DOI: 10.1038/nmat4433

Disulfide bonds as switches for protein function
journal, April 2003


Photocontrollable Liquid-Crystalline Actuators
journal, April 2011


New directions in the chemistry of shape memory polymers
journal, November 2014


Bioinspired Actuated Adhesive Patterns of Liquid Crystalline Elastomers
journal, June 2012

  • Cui, Jiaxi; Drotlef, Dirk-Michael; Larraza, Iñigo
  • Advanced Materials, Vol. 24, Issue 34
  • DOI: 10.1002/adma.201200895

Light-activated shape memory of glassy, azobenzene liquid crystalline polymer networks
journal, January 2011

  • Lee, Kyung Min; Koerner, Hilmar; Vaia, Richard A.
  • Soft Matter, Vol. 7, Issue 9
  • DOI: 10.1039/c1sm00004g

A Continuous Flow Synthesis of Micrometer-Sized Actuators from Liquid Crystalline Elastomers
journal, July 2009

  • Ohm, Christian; Serra, Christophe; Zentel, Rudolf
  • Advanced Materials, Vol. 21, Issue 47
  • DOI: 10.1002/adma.200901522

Twists and Turns in Glassy, Liquid Crystalline Polymer Networks
journal, January 2015

  • Wie, Jeong Jae; Lee, Kyung Min; Ware, Taylor H.
  • Macromolecules, Vol. 48, Issue 4
  • DOI: 10.1021/ma502563q

Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding
journal, October 2015


Degradable epoxy resins prepared from diepoxide monomer with dynamic covalent disulfide linkage
journal, January 2016


Directed bending of a polymer film by light
journal, September 2003

  • Yu, Yanlei; Nakano, Makoto; Ikeda, Tomiki
  • Nature, Vol. 425, Issue 6954
  • DOI: 10.1038/425145a

Making waves in a photoactive polymer film
journal, June 2017

  • Gelebart, Anne Helene; Jan Mulder, Dirk; Varga, Michael
  • Nature, Vol. 546, Issue 7660
  • DOI: 10.1038/nature22987

Combined One-Way and Two-Way Shape Memory in a Glass-Forming Nematic Network
journal, January 2009

  • Qin, Haihu; Mather, Patrick T.
  • Macromolecules, Vol. 42, Issue 1
  • DOI: 10.1021/ma8022926

Anisotropic Colloidal Micromuscles from Liquid Crystal Elastomers
journal, December 2013

  • Marshall, Jean E.; Gallagher, Sarah; Terentjev, Eugene M.
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410930g

Regional Shape Control of Strategically Assembled Multishape Memory Vitrimers
journal, November 2015


Inherently Photohealable and Thermal Shape-Memory Polydisulfide Networks
journal, July 2013

  • Michal, Brian T.; Jaye, Colin A.; Spencer, Emily J.
  • ACS Macro Letters, Vol. 2, Issue 8
  • DOI: 10.1021/mz400318m

Programmed liquid crystal elastomers with tunable actuation strain
journal, January 2015


Photomechanical mechanism and structure-property considerations in the generation of photomechanical work in glassy, azobenzene liquid crystal polymer networks
journal, January 2012

  • Lee, Kyung Min; Tabiryan, Nelson V.; Bunning, Timothy J.
  • J. Mater. Chem., Vol. 22, Issue 2
  • DOI: 10.1039/C1JM14017E

Disulfide Bonds and Protein Folding
journal, June 2000

  • Wedemeyer, William J.; Welker, Ervin; Narayan, Mahesh
  • Biochemistry, Vol. 39, Issue 23
  • DOI: 10.1021/bi005111p

Photomechanics of Liquid-Crystalline Elastomers and Other Polymers
journal, April 2007


Works referencing / citing this record:

Liquid Crystalline Vitrimers with Full or Partial Boronic‐Ester Bond Exchange
journal, October 2019

  • Saed, Mohand O.; Gablier, Alexandra; Terentejv, Eugene M.
  • Advanced Functional Materials, Vol. 30, Issue 3
  • DOI: 10.1002/adfm.201906458

Untethered Recyclable Tubular Actuators with Versatile Locomotion for Soft Continuum Robots
journal, May 2018


Photodeformable Azobenzene‐Containing Liquid Crystal Polymers and Soft Actuators
journal, October 2019


Dynamic Covalent Bonds in Polymeric Materials
journal, April 2019


Durable liquid-crystalline vitrimer actuators
journal, January 2019

  • Chen, Qiaomei; Li, Yongsan; Yang, Yang
  • Chemical Science, Vol. 10, Issue 10
  • DOI: 10.1039/c8sc05358h

A cut-and-paste strategy towards liquid crystal elastomers with complex shape morphing
journal, January 2018

  • Chen, Ling; Wang, Meng; Guo, Ling-Xiang
  • Journal of Materials Chemistry C, Vol. 6, Issue 30
  • DOI: 10.1039/c8tc01236a

Programmable actuation of liquid crystal elastomers via “living” exchange reaction
journal, January 2019

  • Wang, Zhijian; He, Qiguang; Wang, Yang
  • Soft Matter, Vol. 15, Issue 13
  • DOI: 10.1039/c9sm00322c

Liquid crystal elastomers: an introduction and review of emerging technologies
journal, January 2018


A readily programmable, fully reversible shape-switching material
journal, August 2018

  • McBride, Matthew K.; Martinez, Alina M.; Cox, Lewis
  • Science Advances, Vol. 4, Issue 8
  • DOI: 10.1126/sciadv.aat4634

Dynamic Covalent Bonds in Polymeric Materials
journal, July 2019

  • Chakma, Progyateg; Konkolewicz, Dominik
  • Angewandte Chemie International Edition, Vol. 58, Issue 29
  • DOI: 10.1002/anie.201813525