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Title: Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe 2Nb Laves Phase

Abstract

We have develooped a new Fe-Cr-Al (FCA) alloy system with good oxidation resistance and creep strength at high temperature. The alloy system is a candidate for use in future fossil-fueled power plants. The creep strength of these alloys at 973 K (700 °C) was found to be comparable with traditional 9 pct Cr ferritic–martensitic steels. A few FCA alloys with general composition of Fe-30Cr-3Al-.2Si-xNb (x = 0, 1, or 2) with a ferrite matrix and Fe 2Nb-type Laves precipitates were prepared. The detailed microstructural characterization of samples, before and after creep rupture testing, indicated precipitation of the Laves phase within the matrix, Laves phase at the grain boundaries, and a 0.5 to 1.5 μm wide precipitate-free zone (PFZ) parallel to all the grain boundaries. In these alloys, the areal fraction of grain boundary Laves phase and the width of the PFZ controlled the cavitation nucleation and eventual grain boundary ductile failure. Finally, we used a phenomenological model to compare the creep strain rates controlled by the effects of the particles on the dislocations within the grain and at grain boundaries. (The research sponsored by US-DOE, Office of Fossil Energy, the Crosscutting Research Program).

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Mechanical Aerospace and Biomedical Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC); USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1394222
Alternate Identifier(s):
OSTI ID: 1474845
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science
Additional Journal Information:
Journal Volume: 48; Journal Issue: 10; Journal ID: ISSN 1073-5623
Publisher:
ASM International
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Shassere, Benjamin, Yamamoto, Yukinori, Poplawsky, Jonathan, Guo, Wei, and Babu, Sudarsanam Suresh. Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe2Nb Laves Phase. United States: N. p., 2017. Web. doi:10.1007/s11661-017-4274-8.
Shassere, Benjamin, Yamamoto, Yukinori, Poplawsky, Jonathan, Guo, Wei, & Babu, Sudarsanam Suresh. Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe2Nb Laves Phase. United States. doi:10.1007/s11661-017-4274-8.
Shassere, Benjamin, Yamamoto, Yukinori, Poplawsky, Jonathan, Guo, Wei, and Babu, Sudarsanam Suresh. Mon . "Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe2Nb Laves Phase". United States. doi:10.1007/s11661-017-4274-8. https://www.osti.gov/servlets/purl/1394222.
@article{osti_1394222,
title = {Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe2Nb Laves Phase},
author = {Shassere, Benjamin and Yamamoto, Yukinori and Poplawsky, Jonathan and Guo, Wei and Babu, Sudarsanam Suresh},
abstractNote = {We have develooped a new Fe-Cr-Al (FCA) alloy system with good oxidation resistance and creep strength at high temperature. The alloy system is a candidate for use in future fossil-fueled power plants. The creep strength of these alloys at 973 K (700 °C) was found to be comparable with traditional 9 pct Cr ferritic–martensitic steels. A few FCA alloys with general composition of Fe-30Cr-3Al-.2Si-xNb (x = 0, 1, or 2) with a ferrite matrix and Fe2Nb-type Laves precipitates were prepared. The detailed microstructural characterization of samples, before and after creep rupture testing, indicated precipitation of the Laves phase within the matrix, Laves phase at the grain boundaries, and a 0.5 to 1.5 μm wide precipitate-free zone (PFZ) parallel to all the grain boundaries. In these alloys, the areal fraction of grain boundary Laves phase and the width of the PFZ controlled the cavitation nucleation and eventual grain boundary ductile failure. Finally, we used a phenomenological model to compare the creep strain rates controlled by the effects of the particles on the dislocations within the grain and at grain boundaries. (The research sponsored by US-DOE, Office of Fossil Energy, the Crosscutting Research Program).},
doi = {10.1007/s11661-017-4274-8},
journal = {Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science},
number = 10,
volume = 48,
place = {United States},
year = {2017},
month = {8}
}

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    Works referencing / citing this record:

    Correlation of Microstructure to Creep Response of Hot Isostatically Pressed and Aged Electron Beam Melted Inconel 718
    journal, July 2018

    • Shassere, Benjamin; Greeley, Duncan; Okello, Alfred
    • Metallurgical and Materials Transactions A, Vol. 49, Issue 10
    • DOI: 10.1007/s11661-018-4812-z

    Correlation of Microstructure to Creep Response of Hot Isostatically Pressed and Aged Electron Beam Melted Inconel 718
    journal, July 2018

    • Shassere, Benjamin; Greeley, Duncan; Okello, Alfred
    • Metallurgical and Materials Transactions A, Vol. 49, Issue 10
    • DOI: 10.1007/s11661-018-4812-z