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Title: Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations

A novel and simple perturbation-assisted nanofusion (PNF) synthetic strategy was developed for the fabrication of stable hierarchically superstructured metal sulfides. This promising approach, based on a kinetically controlled precipitation to simultaneously condense and re-dissolve polymorphic nanocrystallites, provides the resultant samples with a unique mesoporous framework. This PNF approach is environmentally friendly, produces gram-scale products in a matter of hours, and is complimentary to traditional hard or soft templating methods for the construction of mesoporous metal sulfides. PNF derived hierarchical porous CdS exhibited a vastly improved photocatalytic performance over its commercial bulk counterpart under visible light irradiation, demonstrating the advantage of the porous morphology for photocatalysis resulting from the enlarged surface area and the easy accessibility of the mesopores.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [4] ;  [4] ;  [3] ;  [5] ;  [2] ; ORCiD logo [6]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.; Sul Ros State Univ., Alpine, TX (United States). Dept. of Biology, Geology, and Physical Science
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.; Univ. of Tennessee, Knoxville, TN (United States). The Bredesen Center for Interdisciplinary Research and Graduate Education
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
  5. Sul Ros State Univ., Alpine, TX (United States). Dept. of Biology, Geology, and Physical Science
  6. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
ChemNanoMat
Additional Journal Information:
Journal Volume: 2; Journal Issue: 12; Journal ID: ISSN 2199-692X
Publisher:
Wiley
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY
OSTI Identifier:
1393864

Yue, Yanfeng, Li, Yunchao, Bridges, Craig A., Rother, Gernot, Zhang, Jinshui, Chen, Jihua, Hensley, Dale K., Kidder, Michelle K., Richardson, Bruce C., Parans Paranthaman, Mariappan, and Dai, Sheng. Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations. United States: N. p., Web. doi:10.1002/cnma.201600292.
Yue, Yanfeng, Li, Yunchao, Bridges, Craig A., Rother, Gernot, Zhang, Jinshui, Chen, Jihua, Hensley, Dale K., Kidder, Michelle K., Richardson, Bruce C., Parans Paranthaman, Mariappan, & Dai, Sheng. Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations. United States. doi:10.1002/cnma.201600292.
Yue, Yanfeng, Li, Yunchao, Bridges, Craig A., Rother, Gernot, Zhang, Jinshui, Chen, Jihua, Hensley, Dale K., Kidder, Michelle K., Richardson, Bruce C., Parans Paranthaman, Mariappan, and Dai, Sheng. 2016. "Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations". United States. doi:10.1002/cnma.201600292. https://www.osti.gov/servlets/purl/1393864.
@article{osti_1393864,
title = {Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations},
author = {Yue, Yanfeng and Li, Yunchao and Bridges, Craig A. and Rother, Gernot and Zhang, Jinshui and Chen, Jihua and Hensley, Dale K. and Kidder, Michelle K. and Richardson, Bruce C. and Parans Paranthaman, Mariappan and Dai, Sheng},
abstractNote = {A novel and simple perturbation-assisted nanofusion (PNF) synthetic strategy was developed for the fabrication of stable hierarchically superstructured metal sulfides. This promising approach, based on a kinetically controlled precipitation to simultaneously condense and re-dissolve polymorphic nanocrystallites, provides the resultant samples with a unique mesoporous framework. This PNF approach is environmentally friendly, produces gram-scale products in a matter of hours, and is complimentary to traditional hard or soft templating methods for the construction of mesoporous metal sulfides. PNF derived hierarchical porous CdS exhibited a vastly improved photocatalytic performance over its commercial bulk counterpart under visible light irradiation, demonstrating the advantage of the porous morphology for photocatalysis resulting from the enlarged surface area and the easy accessibility of the mesopores.},
doi = {10.1002/cnma.201600292},
journal = {ChemNanoMat},
number = 12,
volume = 2,
place = {United States},
year = {2016},
month = {11}
}

Works referenced in this record:

Ordered Mesoporous Carbons
journal, May 2001

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
journal, October 1992
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