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Title: Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing

Journal Article · · Nanotechnology
 [1];  [2];  [3];  [1];  [4];  [3];  [1]
  1. Oregon State University, Corvallis, OR (United States). School of Electrical Engineering and Computer Science
  2. Oregon State University, Corvallis, OR (United States). School of Chemical, Biological and Environmental Engineering; National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); AECOM, Pittsburgh, PA (United States)
  3. Oregon State University, Corvallis, OR (United States). School of Chemical, Biological and Environmental Engineering
  4. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Carnegie Mellon University, Pittsburgh, PA (United States). Materials Science and Engineering, Department
+ Show Author Affiliations

In this letter, we present a nanophotonic device consisting of plasmonic nanopatch array (NPA) with integrated metal–organic framework (MOF) for enhanced infrared absorption gas sensing. By designing a gold NPA on a sapphire substrate, we are able to achieve enhanced optical field that spatially overlaps with the MOF layer, which can adsorb carbon dioxide (CO2) with high capacity. Additionally, experimental results show that this hybrid plasmonic–MOF device can effectively increase the infrared absorption path of on-chip gas sensors by more than 1100-fold. Lastly, the demonstration of infrared absorption spectroscopy of CO2 using the hybrid plasmonic–MOF device proves a promising strategy for future on-chip gas sensing with ultra-compact size.

Research Organization:
National Energy Technology Laboratory (NETL), Pittsburgh, PA (United States). In house research
Sponsoring Organization:
USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)
OSTI ID:
1393389
Alternate ID(s):
OSTI ID: 22798716
Journal Information:
Nanotechnology, Journal Name: Nanotechnology Journal Issue: 26 Vol. 28; ISSN 0957-4484
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (4)

Hybrid Metamaterial Absorber Platform for Sensing of CO 2 Gas at Mid-IR journal February 2018
Flexible all-solid-state supercapacitors of polyaniline nanowire arrays deposited on electrospun carbon nanofibers decorated with MOFs journal December 2018
Organic–inorganic hybrids for CO 2 sensing, separation and conversion journal January 2020
Nanostructured copper sulfide thin film via a spatial successive ionic layer adsorption and reaction process showing significant surface-enhanced infrared absorption of CO 2 journal January 2020

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Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
plasmonics
gas sensing
metal–organic framework
infrared absorption