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Title: Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing

Abstract

In this letter, we present a nanophotonic device consisting of plasmonic nanopatch array (NPA) with integrated metal–organic framework (MOF) for enhanced infrared absorption gas sensing. By designing a gold NPA on a sapphire substrate, we are able to achieve enhanced optical field that spatially overlaps with the MOF layer, which can adsorb carbon dioxide (CO2) with high capacity. Additionally, experimental results show that this hybrid plasmonic–MOF device can effectively increase the infrared absorption path of on-chip gas sensors by more than 1100-fold. Lastly, the demonstration of infrared absorption spectroscopy of CO2 using the hybrid plasmonic–MOF device proves a promising strategy for future on-chip gas sensing with ultra-compact size.

Authors:
 [1];  [2];  [3];  [1];  [4];  [3];  [1]
  1. Oregon State University, Corvallis, OR (United States). School of Electrical Engineering and Computer Science
  2. Oregon State University, Corvallis, OR (United States). School of Chemical, Biological and Environmental Engineering; National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); AECOM, Pittsburgh, PA (United States)
  3. Oregon State University, Corvallis, OR (United States). School of Chemical, Biological and Environmental Engineering
  4. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Carnegie Mellon University, Pittsburgh, PA (United States). Materials Science and Engineering, Department
Publication Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA (United States). In house research
Sponsoring Org.:
USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)
OSTI Identifier:
1393389
Grant/Contract Number:  
1449383
Resource Type:
Accepted Manuscript
Journal Name:
Nanotechnology
Additional Journal Information:
Journal Volume: 28; Journal Issue: 26; Journal ID: ISSN 0957-4484
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; plasmonics; gas sensing; metal–organic framework; infrared absorption

Citation Formats

Chong, Xinyuan, Kim, Ki-joong, Zhang, Yujing, Li, Erwen, Ohodnicki, Paul R., Chang, Chih-Hung, and Wang, Alan X.. Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing. United States: N. p., 2017. Web. https://doi.org/10.1088/1361-6528/aa7433.
Chong, Xinyuan, Kim, Ki-joong, Zhang, Yujing, Li, Erwen, Ohodnicki, Paul R., Chang, Chih-Hung, & Wang, Alan X.. Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing. United States. https://doi.org/10.1088/1361-6528/aa7433
Chong, Xinyuan, Kim, Ki-joong, Zhang, Yujing, Li, Erwen, Ohodnicki, Paul R., Chang, Chih-Hung, and Wang, Alan X.. Tue . "Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing". United States. https://doi.org/10.1088/1361-6528/aa7433. https://www.osti.gov/servlets/purl/1393389.
@article{osti_1393389,
title = {Plasmonic nanopatch array with integrated metal–organic framework for enhanced infrared absorption gas sensing},
author = {Chong, Xinyuan and Kim, Ki-joong and Zhang, Yujing and Li, Erwen and Ohodnicki, Paul R. and Chang, Chih-Hung and Wang, Alan X.},
abstractNote = {In this letter, we present a nanophotonic device consisting of plasmonic nanopatch array (NPA) with integrated metal–organic framework (MOF) for enhanced infrared absorption gas sensing. By designing a gold NPA on a sapphire substrate, we are able to achieve enhanced optical field that spatially overlaps with the MOF layer, which can adsorb carbon dioxide (CO2) with high capacity. Additionally, experimental results show that this hybrid plasmonic–MOF device can effectively increase the infrared absorption path of on-chip gas sensors by more than 1100-fold. Lastly, the demonstration of infrared absorption spectroscopy of CO2 using the hybrid plasmonic–MOF device proves a promising strategy for future on-chip gas sensing with ultra-compact size.},
doi = {10.1088/1361-6528/aa7433},
journal = {Nanotechnology},
number = 26,
volume = 28,
place = {United States},
year = {2017},
month = {6}
}

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Works referenced in this record:

The Potential Applications of Nanoporous Materials for the Adsorption, Separation, and Catalytic Conversion of Carbon Dioxide
journal, March 2014

  • Sneddon, Gregor; Greenaway, Alex; Yiu, Humphrey H. P.
  • Advanced Energy Materials, Vol. 4, Issue 10
  • DOI: 10.1002/aenm.201301873

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites
journal, January 2014

  • Li, Liangjun; Tang, Sifu; Wang, Chao
  • Chemical Communications, Vol. 50, Issue 18
  • DOI: 10.1039/c3cc48275h

The effect of structural and energetic parameters of MOFs and COFs towards the improvement of their hydrogen storage properties
journal, April 2009


Olsalazine-Based Metal–Organic Frameworks as Biocompatible Platforms for H 2 Adsorption and Drug Delivery
journal, August 2016

  • Levine, Dana J.; Runčevski, Tomče; Kapelewski, Matthew T.
  • Journal of the American Chemical Society, Vol. 138, Issue 32
  • DOI: 10.1021/jacs.6b03523

Near-infrared absorption gas sensing with metal-organic framework on optical fibers
journal, September 2016


Ultrashort Near-Infrared Fiber-Optic Sensors for Carbon Dioxide Detection
journal, September 2015


Plasmonics-enhanced metal–organic framework nanoporous films for highly sensitive near-infrared absorption
journal, January 2015

  • Kim, Ki-Joong; Chong, Xinyuan; Kreider, Peter B.
  • Journal of Materials Chemistry C, Vol. 3, Issue 12
  • DOI: 10.1039/C4TC02846E

Flexible metal–organic framework-based one-dimensional photonic crystals
journal, January 2015

  • Hu, Zhihong; Tao, Cheng-an; Wang, Fang
  • Journal of Materials Chemistry C, Vol. 3, Issue 1
  • DOI: 10.1039/C4TC01501K

Heterogeneous Asymmetric Catalysis with Homochiral Metal–Organic Frameworks: Network-Structure-Dependent Catalytic Activity
journal, February 2007

  • Wu, Chuan-De; Lin, Wenbin
  • Angewandte Chemie International Edition, Vol. 46, Issue 7
  • DOI: 10.1002/anie.200602099

A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis
journal, July 2010

  • Ma, Liqing; Falkowski, Joseph M.; Abney, Carter
  • Nature Chemistry, Vol. 2, Issue 10
  • DOI: 10.1038/nchem.738

Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions
journal, January 2014

  • Zhao, Meiting; Deng, Ke; He, Liangcan
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja411468e

Core–Shell Catalysts of Metal Nanoparticle Core and Metal–Organic Framework Shell
journal, November 2014

  • Hu, Pan; Morabito, Joseph V.; Tsung, Chia-Kuang
  • ACS Catalysis, Vol. 4, Issue 12
  • DOI: 10.1021/cs5012662

Core-Shell Upconversion Nanoparticle@Metal-Organic Framework Nanoprobes for Luminescent/Magnetic Dual-Mode Targeted Imaging
journal, June 2015


SERS of molecules that do not adsorb on Ag surfaces: a metal–organic framework-based functionalization strategy
journal, January 2014

  • Kreno, Lauren E.; Greeneltch, Nathan G.; Farha, Omar K.
  • The Analyst, Vol. 139, Issue 16
  • DOI: 10.1039/C4AN00413B

Core-Shell Noble-Metal@Metal-Organic-Framework Nanoparticles with Highly Selective Sensing Property
journal, February 2013

  • He, Liangcan; Liu, Yong; Liu, Jingzhu
  • Angewandte Chemie International Edition, Vol. 52, Issue 13
  • DOI: 10.1002/anie.201209903

Stable and Functional Gold Nanorod Composites with a Metal–Organic Framework Crystalline Shell
journal, June 2013

  • Sugikawa, Kouta; Nagata, Shunjiro; Furukawa, Yuki
  • Chemistry of Materials, Vol. 25, Issue 13
  • DOI: 10.1021/cm302735b

Silver Cluster Formation, Dynamics, and Chemistry in Metal−Organic Frameworks
journal, October 2009

  • Houk, Ronald J. T.; Jacobs, Benjamin W.; Gabaly, Farid El
  • Nano Letters, Vol. 9, Issue 10
  • DOI: 10.1021/nl901397k

Fabrication of Gold Nanoparticle-Embedded Metal–Organic Framework for Highly Sensitive Surface-Enhanced Raman Scattering Detection
journal, March 2014

  • Hu, Yuling; Liao, Jia; Wang, Dongmei
  • Analytical Chemistry, Vol. 86, Issue 8
  • DOI: 10.1021/ac5002355

Metal-organic frameworks: a novel SERS substrate: A novel SERS substrate
journal, September 2013

  • Yu, Tsung-Han; Ho, Chin-Hsian; Wu, Cheng-You
  • Journal of Raman Spectroscopy, Vol. 44, Issue 11
  • DOI: 10.1002/jrs.4378

SERS-Active Metal–Organic Frameworks Embedding Gold Nanorods
journal, July 2011

  • Sugikawa, Kouta; Furukawa, Yuki; Sada, Kazuki
  • Chemistry of Materials, Vol. 23, Issue 13
  • DOI: 10.1021/cm200737c

Mesoscopic Constructs of Ordered and Oriented Metal–Organic Frameworks on Plasmonic Silver Nanocrystals
journal, February 2015

  • Zhao, Yingbo; Kornienko, Nikolay; Liu, Zheng
  • Journal of the American Chemical Society, Vol. 137, Issue 6
  • DOI: 10.1021/ja512951e

Enhanced third harmonic generation by organic materials on high-Q plasmonic photonic crystals
journal, January 2014

  • Ren, Fanghui; Wang, Xiangyu; Li, Zhong’an
  • Optics Express, Vol. 22, Issue 17
  • DOI: 10.1364/OE.22.020292

Metal−Organic Framework Thin Film for Enhanced Localized Surface Plasmon Resonance Gas Sensing
journal, October 2010

  • Kreno, Lauren E.; Hupp, Joseph T.; Van Duyne, Richard P.
  • Analytical Chemistry, Vol. 82, Issue 19, p. 8042-8046
  • DOI: 10.1021/ac102127p

Effect of finite metallic grating size on Rayleigh anomaly-surface plasmon polariton resonances
journal, January 2015

  • Ren, Fanghui; Kim, Kyoung-Youm; Chong, Xinyuan
  • Optics Express, Vol. 23, Issue 22
  • DOI: 10.1364/OE.23.028868

Rigorous coupled-wave analysis of planar-grating diffraction
journal, January 1981

  • Moharam, M. G.; Gaylord, T. K.
  • Journal of the Optical Society of America, Vol. 71, Issue 7
  • DOI: 10.1364/JOSA.71.000811

Metallodielectric gratings with subwavelength slots:  Optical properties
journal, November 2003


Rayleigh anomaly-surface plasmon polariton resonances in palladium and gold subwavelength hole arrays
journal, January 2009


In Situ Measurement of CO 2 and H 2 O Adsorption by ZIF-8 Films
journal, June 2015

  • Tian, Fangyuan; Mosier, Amber M.; Park, Aileen
  • The Journal of Physical Chemistry C, Vol. 119, Issue 27
  • DOI: 10.1021/acs.jpcc.5b02991

    Works referencing / citing this record:

    Hybrid Metamaterial Absorber Platform for Sensing of CO 2 Gas at Mid-IR
    journal, February 2018


    Organic–inorganic hybrids for CO 2 sensing, separation and conversion
    journal, January 2020

    • Rebber, Matthias; Willa, Christoph; Koziej, Dorota
    • Nanoscale Horizons, Vol. 5, Issue 3
    • DOI: 10.1039/c9nh00380k