3D Bragg coherent diffractive imaging of five-fold multiply twinned gold nanoparticle
Abstract
The formation mechanism of five-fold multiply twinned nanoparticles has been a long-term topic because of their geometrical incompatibility. So, various models have been proposed to explain how the internal structure of the multiply twinned nanoparticles accommodates the constraints of the solid-angle deficiency. Here, we investigate the internal structure, strain field and strain energy density of 600 nm sized five-fold multiply twinned gold nanoparticles quantitatively using Bragg coherent diffractive imaging, which is suitable for the study of buried defects and three-dimensional strain distribution with great precision. Our study reveals that the strain energy density in five-fold multiply twinned gold nanoparticles is an order of magnitude higher than that of the single nanocrystals such as an octahedron and triangular plate synthesized under the same conditions. This result indicates that the strain developed while accommodating an angular misfit, although partially released through the introduction of structural defects, is still large throughout the crystal.
- Authors:
-
[1];
[2];
- Univ. of California, San Diego, CA (United States). Dept. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Univ. of California, San Diego, CA (United States). Dept. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Center for Magnetic Recording Research; University of California-San Diego; La Jolla; USA
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Univ. of California, San Diego, CA (United States). Center for Magnetic Recording Research
- Univ. of California, San Diego, CA (United States). Dept. of Physics
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1393173
- Grant/Contract Number:
- AC02-06CH11357; SC0001805; DMR-1411335
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 35; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Kim, Jong Woo, Ulvestad, Andrew, Manna, Sohini, Harder, Ross, Fullerton, Eric E., and Shpyrko, Oleg G. 3D Bragg coherent diffractive imaging of five-fold multiply twinned gold nanoparticle. United States: N. p., 2017.
Web. doi:10.1039/C7NR05028C.
Kim, Jong Woo, Ulvestad, Andrew, Manna, Sohini, Harder, Ross, Fullerton, Eric E., & Shpyrko, Oleg G. 3D Bragg coherent diffractive imaging of five-fold multiply twinned gold nanoparticle. United States. https://doi.org/10.1039/C7NR05028C
Kim, Jong Woo, Ulvestad, Andrew, Manna, Sohini, Harder, Ross, Fullerton, Eric E., and Shpyrko, Oleg G. Fri .
"3D Bragg coherent diffractive imaging of five-fold multiply twinned gold nanoparticle". United States. https://doi.org/10.1039/C7NR05028C. https://www.osti.gov/servlets/purl/1393173.
@article{osti_1393173,
title = {3D Bragg coherent diffractive imaging of five-fold multiply twinned gold nanoparticle},
author = {Kim, Jong Woo and Ulvestad, Andrew and Manna, Sohini and Harder, Ross and Fullerton, Eric E. and Shpyrko, Oleg G.},
abstractNote = {The formation mechanism of five-fold multiply twinned nanoparticles has been a long-term topic because of their geometrical incompatibility. So, various models have been proposed to explain how the internal structure of the multiply twinned nanoparticles accommodates the constraints of the solid-angle deficiency. Here, we investigate the internal structure, strain field and strain energy density of 600 nm sized five-fold multiply twinned gold nanoparticles quantitatively using Bragg coherent diffractive imaging, which is suitable for the study of buried defects and three-dimensional strain distribution with great precision. Our study reveals that the strain energy density in five-fold multiply twinned gold nanoparticles is an order of magnitude higher than that of the single nanocrystals such as an octahedron and triangular plate synthesized under the same conditions. This result indicates that the strain developed while accommodating an angular misfit, although partially released through the introduction of structural defects, is still large throughout the crystal.},
doi = {10.1039/C7NR05028C},
journal = {Nanoscale},
number = 35,
volume = 9,
place = {United States},
year = {Fri Aug 11 00:00:00 EDT 2017},
month = {Fri Aug 11 00:00:00 EDT 2017}
}
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Works referencing / citing this record:
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