Stability of iron-bearing carbonates in the deep Earth’s interior
Abstract
The presence of carbonates in inclusions in diamonds coming from depths exceeding 670 km are obvious evidence that carbonates exist in the Earth’s lower mantle. However, their range of stability, crystal structures and the thermodynamic conditions of the decarbonation processes remain poorly constrained. We investigate the behaviour of pure iron carbonate at pressures over 100 GPa and temperatures over 2,500 K using single-crystal X-ray diffraction and Mossbauer spectroscopy in laser-heated diamond anvil cells. On heating to temperatures of the Earth’s geotherm at pressures to B 50 GPa FeCO 3 partially dissociates to form various iron oxides. Furthermore, at higher pressures FeCO 3 forms two new structures— tetrairon(III) orthocarbonate Fe$$3+\atop{4}$$C3O12 and diiron(II) diiron(III) tetracarbonate Fe$$2+\atop{2}$$ Fe$$3+\atop{2}$$C4 O13, both phases containing CO4 tetrahedra. Fe4 C4 O13 is stable at conditions along the entire geotherm to depths of at least 2,500 km, thus demonstrating that self-oxidation-reduction reactions can preserve carbonates in the Earth’s lower mantle.
- Authors:
-
- European Synchrotron Radiation Facility (ESRF), Grenoble (France); Univ. of Bayreuth (Germany). Bavarian Geoinstitute
- Univ. of Bayreuth (Germany). Bavarian Geoinstitute; Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
- European Synchrotron Radiation Facility (ESRF), Grenoble (France)
- Univ. of Milan (Italy). Dept. of Earth Sciences
- Center for Hydrocarbon Recovery, Moscow (Russia). Skolkovo Inst. of Science and Technology
- Univ. of Bayreuth (Germany). Bavarian Geoinstitute
- Univ. of Bayreuth (Germany). Bavarian Geoinstitute; National Univ., of Science and Technology, Moscow (Russia). Material Modeling and Development Lab.
- Univ. of Cologne (Germany). Inst. of Geology and Mineralogy
- Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources
- Publication Date:
- Research Org.:
- Univ. of Chicago, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1393163
- Grant/Contract Number:
- FG02-94ER14466; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Cerantola, Valerio, Bykova, Elena, Kupenko, Ilya, Merlini, Marco, Ismailova, Leyla, McCammon, Catherine, Bykov, Maxim, Chumakov, Alexandr I., Petitgirard, Sylvain, Kantor, Innokenty, Svitlyk, Volodymyr, Jacobs, Jeroen, Hanfland, Michael, Mezouar, Mohamed, Prescher, Clemens, Rüffer, Rudolf, Prakapenka, Vitali B., and Dubrovinsky, Leonid. Stability of iron-bearing carbonates in the deep Earth’s interior. United States: N. p., 2017.
Web. doi:10.1038/ncomms15960.
Cerantola, Valerio, Bykova, Elena, Kupenko, Ilya, Merlini, Marco, Ismailova, Leyla, McCammon, Catherine, Bykov, Maxim, Chumakov, Alexandr I., Petitgirard, Sylvain, Kantor, Innokenty, Svitlyk, Volodymyr, Jacobs, Jeroen, Hanfland, Michael, Mezouar, Mohamed, Prescher, Clemens, Rüffer, Rudolf, Prakapenka, Vitali B., & Dubrovinsky, Leonid. Stability of iron-bearing carbonates in the deep Earth’s interior. United States. https://doi.org/10.1038/ncomms15960
Cerantola, Valerio, Bykova, Elena, Kupenko, Ilya, Merlini, Marco, Ismailova, Leyla, McCammon, Catherine, Bykov, Maxim, Chumakov, Alexandr I., Petitgirard, Sylvain, Kantor, Innokenty, Svitlyk, Volodymyr, Jacobs, Jeroen, Hanfland, Michael, Mezouar, Mohamed, Prescher, Clemens, Rüffer, Rudolf, Prakapenka, Vitali B., and Dubrovinsky, Leonid. Wed .
"Stability of iron-bearing carbonates in the deep Earth’s interior". United States. https://doi.org/10.1038/ncomms15960. https://www.osti.gov/servlets/purl/1393163.
@article{osti_1393163,
title = {Stability of iron-bearing carbonates in the deep Earth’s interior},
author = {Cerantola, Valerio and Bykova, Elena and Kupenko, Ilya and Merlini, Marco and Ismailova, Leyla and McCammon, Catherine and Bykov, Maxim and Chumakov, Alexandr I. and Petitgirard, Sylvain and Kantor, Innokenty and Svitlyk, Volodymyr and Jacobs, Jeroen and Hanfland, Michael and Mezouar, Mohamed and Prescher, Clemens and Rüffer, Rudolf and Prakapenka, Vitali B. and Dubrovinsky, Leonid},
abstractNote = {The presence of carbonates in inclusions in diamonds coming from depths exceeding 670 km are obvious evidence that carbonates exist in the Earth’s lower mantle. However, their range of stability, crystal structures and the thermodynamic conditions of the decarbonation processes remain poorly constrained. We investigate the behaviour of pure iron carbonate at pressures over 100 GPa and temperatures over 2,500 K using single-crystal X-ray diffraction and Mossbauer spectroscopy in laser-heated diamond anvil cells. On heating to temperatures of the Earth’s geotherm at pressures to B 50 GPa FeCO 3 partially dissociates to form various iron oxides. Furthermore, at higher pressures FeCO 3 forms two new structures— tetrairon(III) orthocarbonate Fe$3+\atop{4}$C3O12 and diiron(II) diiron(III) tetracarbonate Fe$2+\atop{2}$ Fe$3+\atop{2}$C4 O13, both phases containing CO4 tetrahedra. Fe4 C4 O13 is stable at conditions along the entire geotherm to depths of at least 2,500 km, thus demonstrating that self-oxidation-reduction reactions can preserve carbonates in the Earth’s lower mantle.},
doi = {10.1038/ncomms15960},
journal = {Nature Communications},
number = ,
volume = 8,
place = {United States},
year = {Wed Jul 19 00:00:00 EDT 2017},
month = {Wed Jul 19 00:00:00 EDT 2017}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Nuclear Resonance Beamline at ESRF
journal, December 1996
- Rüffer, Rudolf; Chumakov, Aleksandr I.
- Hyperfine Interactions, Vol. 97-98, Issue 1
Spin crossover in : A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data
journal, March 2006
- Kantor, I. Yu.; Dubrovinsky, L. S.; McCammon, C. A.
- Physical Review B, Vol. 73, Issue 10
Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle
journal, August 2008
- Oganov, Artem R.; Ono, Shigeaki; Ma, Yanming
- Earth and Planetary Science Letters, Vol. 273, Issue 1-2
Mineralogy of the lower mantle: A review of ‘super-deep’ mineral inclusions in diamond
journal, January 2012
- Kaminsky, Felix
- Earth-Science Reviews, Vol. 110, Issue 1-4
FeO2 and FeOOH under deep lower-mantle conditions and Earth’s oxygen–hydrogen cycles
journal, June 2016
- Hu, Qingyang; Kim, Duck Young; Yang, Wenge
- Nature, Vol. 534, Issue 7606
New host for carbon in the deep Earth
journal, March 2011
- Boulard, E.; Gloter, A.; Corgne, A.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 13
Optical properties of siderite (FeCO 3 ) across the spin transition: Crossover to iron-rich carbonates in the lower mantle
journal, May 2015
- Lobanov, Sergey S.; Goncharov, Alexander F.; Litasov, Konstantin D.
- American Mineralogist, Vol. 100, Issue 5-6
The structure of the metallic high-pressure Fe 3 O 4 polymorph: experimental and theoretical study
journal, October 2003
- Dubrovinsky, L. S.; Dubrovinskaia, N. A.; McCammon, C.
- Journal of Physics: Condensed Matter, Vol. 15, Issue 45
Toward an internally consistent pressure scale
journal, May 2007
- Fei, Y.; Ricolleau, A.; Frank, M.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 22
Adiabatic temperature profile in the mantle
journal, November 2010
- Katsura, Tomoo; Yoneda, Akira; Yamazaki, Daisuke
- Physics of the Earth and Planetary Interiors, Vol. 183, Issue 1-2
Tetrahedrally coordinated carbonates in Earth’s lower mantle
journal, February 2015
- Boulard, Eglantine; Pan, Ding; Galli, Giulia
- Nature Communications, Vol. 6, Issue 1
GEOCHEMISTRY: The Paradox of Mantle Redox
journal, May 2005
- McCammon, C.
- Science, Vol. 308, Issue 5723
MossA : a program for analyzing energy-domain Mössbauer spectra from conventional and synchrotron sources
journal, March 2012
- Prescher, Clemens; McCammon, Catherine; Dubrovinsky, Leonid
- Journal of Applied Crystallography, Vol. 45, Issue 2
Melting of siderite to 20GPa and thermodynamic properties of FeCO3-melt
journal, April 2015
- Kang, Nathan; Schmidt, Max W.; Poli, Stefano
- Chemical Geology, Vol. 400
Carbonates from the lower part of transition zone or even the lower mantle
journal, August 2007
- Brenker, Frank E.; Vollmer, Christian; Vincze, Laszlo
- Earth and Planetary Science Letters, Vol. 260, Issue 1-2
Slab melting as a barrier to deep carbon subduction
journal, January 2016
- Thomson, Andrew R.; Walter, Michael J.; Kohn, Simon C.
- Nature, Vol. 529, Issue 7584
Siderite at lower mantle conditions and the effects of the pressure-induced spin-pairing transition
journal, January 2009
- Lavina, B.; Dera, P.; Downs, R. T.
- Geophysical Research Letters, Vol. 36, Issue 23
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements
journal, December 2012
- Kantor, I.; Prakapenka, V.; Kantor, A.
- Review of Scientific Instruments, Vol. 83, Issue 12, Article No. 125102
High-pressure phases of CaCO3: Crystal structure prediction and experiment
journal, January 2006
- Oganov, Artem R.; Glass, Colin W.; Ono, Shigeaki
- Earth and Planetary Science Letters, Vol. 241, Issue 1-2
Origin of sub-lithospheric diamonds from the Juina-5 kimberlite (Brazil): constraints from carbon isotopes and inclusion compositions
journal, November 2014
- Thomson, A. R.; Kohn, S. C.; Bulanova, G. P.
- Contributions to Mineralogy and Petrology, Vol. 168, Issue 6
The MnCO 3 -II high-pressure polymorph of rhodocrosite
journal, November 2015
- Merlini, Marco; Hanfland, Michael; Gemmi, Mauro
- American Mineralogist, Vol. 100, Issue 11-12
High pressure–high temperature equations of state of neon and diamond
journal, March 2008
- Dewaele, Agnès; Datchi, Frédéric; Loubeyre, Paul
- Physical Review B, Vol. 77, Issue 9, Article No. 094106
Experimental investigation of the stability of Fe-rich carbonates in the lower mantle: STABILITY OF CARBONATES IN THE MANTLE
journal, February 2012
- Boulard, E.; Menguy, N.; Auzende, A. L.
- Journal of Geophysical Research: Solid Earth, Vol. 117, Issue B2
The crystal structures of Mg 2 Fe 2 C 4 O 13 , with tetrahedrally coordinated carbon, and Fe 13 O 19 , synthesized at deep mantle conditions
journal, August 2015
- Merlini, Marco; Hanfland, Michael; Salamat, Ashkan
- American Mineralogist, Vol. 100, Issue 8-9
The 57 Fe Synchrotron Mössbauer Source at the ESRF
journal, May 2012
- Potapkin, Vasily; Chumakov, Aleksandr I.; Smirnov, Gennadii V.
- Journal of Synchrotron Radiation, Vol. 19, Issue 4
Vibrational and elastic properties of ferromagnesite across the electronic spin-pairing transition of iron
journal, March 2012
- Lin, J. -F.; Liu, J.; Jacobs, C.
- American Mineralogist, Vol. 97, Issue 4
Structure, Bonding, and Mineralogy of Carbon at Extreme Conditions
journal, January 2013
- Oganov, A. R.; Hemley, R. J.; Hazen, R. M.
- Reviews in Mineralogy and Geochemistry, Vol. 75, Issue 1
A short history of SHELX
journal, December 2007
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Static disorders of atoms and experimental determination of Debye temperature in pyrope: Low- and high-temperature single-crystal X-ray diffraction study
journal, September 2011
- Nakatsuka, A.; Shimokawa, M.; Nakayama, N.
- American Mineralogist, Vol. 96, Issue 10
Thermal equation of state and spin transition of magnesiosiderite at high pressure and temperature
journal, January 2014
- Liu, J.; Lin, J. -F.; Mao, Z.
- American Mineralogist, Vol. 99, Issue 1
Stability of magnesite and its high-pressure form in the lowermost mantle
journal, January 2004
- Isshiki, Maiko; Irifune, Tetsuo; Hirose, Kei
- Nature, Vol. 427, Issue 6969
High-pressure spectroscopic study of siderite (FeCO 3 ) with a focus on spin crossover
journal, November 2015
- Cerantola, Valerio; McCammon, Catherine; Kupenko, Ilya
- American Mineralogist, Vol. 100, Issue 11-12
Reevaluating carbon fluxes in subduction zones, what goes down, mostly comes up
journal, June 2015
- Kelemen, Peter B.; Manning, Craig E.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 30
Deep Mantle Cycling of Oceanic Crust: Evidence from Diamonds and Their Mineral Inclusions
journal, September 2011
- Walter, M. J.; Kohn, S. C.; Araujo, D.
- Science, Vol. 334, Issue 6052
Redox freezing and melting in the Earth’s deep mantle resulting from carbon–iron redox coupling
journal, March 2011
- Rohrbach, Arno; Schmidt, Max W.
- Nature, Vol. 472, Issue 7342
High-pressure polymorphs of ZnCO3: Evolutionary crystal structure prediction
journal, June 2014
- Bouibes, A.; Zaoui, A.
- Scientific Reports, Vol. 4, Issue 1
The global range of subduction zone thermal models
journal, November 2010
- Syracuse, Ellen M.; van Keken, Peter E.; Abers, Geoffrey A.
- Physics of the Earth and Planetary Interiors, Vol. 183, Issue 1-2
Oxidation state of the lower mantle: In situ observations of the iron electronic configuration in bridgmanite at extreme conditions
journal, August 2015
- Kupenko, I.; McCammon, C.; Sinmyo, R.
- Earth and Planetary Science Letters, Vol. 423
High-pressure transition of CaCO3
journal, July 2007
- Ono, S.; Kikegawa, T.; Ohishi, Y.
- American Mineralogist, Vol. 92, Issue 7
The influence of trench migration on slab penetration into the lower mantle
journal, May 1996
- Christensen, Ulrich R.
- Earth and Planetary Science Letters, Vol. 140, Issue 1-4
Experimental determination of siderite stability at high pressure
journal, August 2013
- Tao, R.; Fei, Y.; Zhang, L.
- American Mineralogist, Vol. 98, Issue 8-9
Melting and decomposition of MgCO3 at pressures up to 84 GPa
journal, August 2014
- Solopova, N. A.; Dubrovinsky, L.; Spivak, A. V.
- Physics and Chemistry of Minerals, Vol. 42, Issue 1
Reduced radiative conductivity of low spin FeO6-octahedra in FeCO3 at high pressure and temperature
journal, September 2016
- Lobanov, Sergey S.; Holtgrewe, Nicholas; Goncharov, Alexander F.
- Earth and Planetary Science Letters, Vol. 449
Stability of the MgCO3 structures under lower mantle conditions
journal, May 2005
- Skorodumova, N. V.
- American Mineralogist, Vol. 90, Issue 5-6
High-Pressure Orthorhombic Ferromagnesite as a Potential Deep-Mantle Carbon Carrier
journal, January 2015
- Liu, Jin; Lin, Jung-Fu; Prakapenka, Vitali B.
- Scientific Reports, Vol. 5, Issue 1
Charge-ordering transition in iron oxide Fe4O5 involving competing dimer and trimer formation
journal, April 2016
- Ovsyannikov, Sergey V.; Bykov, Maxim; Bykova, Elena
- Nature Chemistry, Vol. 8, Issue 5
Structural complexity of simple Fe2O3 at high pressures and temperatures
journal, February 2016
- Bykova, E.; Dubrovinsky, L.; Dubrovinskaia, N.
- Nature Communications, Vol. 7, Issue 1
Portable double-sided laser-heating system for Mössbauer spectroscopy and X-ray diffraction experiments at synchrotron facilities with diamond anvil cells
journal, December 2012
- Kupenko, I.; Dubrovinsky, L.; Dubrovinskaia, N.
- Review of Scientific Instruments, Vol. 83, Issue 12
Structures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle
journal, August 2012
- Merlini, M.; Crichton, W. A.; Hanfland, M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 34
The stability of magnesite in the transition zone and the lower mantle as function of oxygen fugacity: CARBON/CARBONATE fo2 BUFFER AT HP
journal, October 2011
- Stagno, V.; Tange, Y.; Miyajima, N.
- Geophysical Research Letters, Vol. 38, Issue 19
Applications of quantum mechanical potential surfaces to mineral physics calculations
journal, February 1987
- Lasaga, Antonio C.; Gibbs, G. V.
- Physics and Chemistry of Minerals, Vol. 14, Issue 2
Deep carbon cycle constrained by carbonate solubility.
text, January 2021
- Farsang, Stefan; Louvel, Marion; Zhao, Chaoshuai
- Apollo - University of Cambridge Repository
Nuclear-resonance beamline at ESRF
journal, February 1996
- Rüffer, R.; Chumakov, A. I.
- Il Nuovo Cimento D, Vol. 18, Issue 2-3
Melting of siderite to 20GPa and thermodynamic properties of FeCO3-melt
journal, April 2015
- Kang, Nathan; Schmidt, Max W.; Poli, Stefano
- Chemical Geology, Vol. 400
Carbonates from the lower part of transition zone or even the lower mantle
journal, August 2007
- Brenker, Frank E.; Vollmer, Christian; Vincze, Laszlo
- Earth and Planetary Science Letters, Vol. 260, Issue 1-2
Oxidation state of the lower mantle: In situ observations of the iron electronic configuration in bridgmanite at extreme conditions
journal, August 2015
- Kupenko, I.; McCammon, C.; Sinmyo, R.
- Earth and Planetary Science Letters, Vol. 423
Stagnant slabs in the upper and lower mantle transition region
journal, August 2001
- Fukao, Yoshio; Widiyantoro, Sri; Obayashi, Masayuki
- Reviews of Geophysics, Vol. 39, Issue 3
Stability of magnesite and its high-pressure form in the lowermost mantle
journal, January 2004
- Isshiki, Maiko; Irifune, Tetsuo; Hirose, Kei
- Nature, Vol. 427, Issue 6969
Redox freezing and melting in the Earth’s deep mantle resulting from carbon–iron redox coupling
journal, March 2011
- Rohrbach, Arno; Schmidt, Max W.
- Nature, Vol. 472, Issue 7342
Structural complexity of simple Fe2O3 at high pressures and temperatures
journal, February 2016
- Bykova, E.; Dubrovinsky, L.; Dubrovinskaia, N.
- Nature Communications, Vol. 7, Issue 1
High-Pressure Orthorhombic Ferromagnesite as a Potential Deep-Mantle Carbon Carrier
journal, January 2015
- Liu, Jin; Lin, Jung-Fu; Prakapenka, Vitali B.
- Scientific Reports, Vol. 5, Issue 1
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements
journal, December 2012
- Kantor, I.; Prakapenka, V.; Kantor, A.
- Review of Scientific Instruments, Vol. 83, Issue 12, Article No. 125102
Portable double-sided laser-heating system for Mössbauer spectroscopy and X-ray diffraction experiments at synchrotron facilities with diamond anvil cells
journal, December 2012
- Kupenko, I.; Dubrovinsky, L.; Dubrovinskaia, N.
- Review of Scientific Instruments, Vol. 83, Issue 12
Toward an internally consistent pressure scale
journal, May 2007
- Fei, Y.; Ricolleau, A.; Frank, M.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 22
New host for carbon in the deep Earth
journal, March 2011
- Boulard, E.; Gloter, A.; Corgne, A.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 13
Structures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle
journal, August 2012
- Merlini, M.; Crichton, W. A.; Hanfland, M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 34
Reevaluating carbon fluxes in subduction zones, what goes down, mostly comes up
journal, June 2015
- Kelemen, Peter B.; Manning, Craig E.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 30
Ba 2 Gd 2 (Si 4 O 13 ): a silicate with finite Si 4 O 13 chains
journal, February 2010
- Wierzbicka-Wieczorek, Maria; Kolitsch, Uwe; Tillmanns, Ekkehart
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 66, Issue 3
The MnCO 3 -II high-pressure polymorph of rhodocrosite
journal, November 2015
- Merlini, Marco; Hanfland, Michael; Gemmi, Mauro
- American Mineralogist, Vol. 100, Issue 11-12
Tetrahedrally coordinated carbonates in Earth's lower mantle
text, January 2015
- Boulard, Eglantine; Pan, Ding; Galli, Giulia
- arXiv
Works referencing / citing this record:
High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN 8 ⋅ x N 2 with Conjugated Polymeric Nitrogen Chains
journal, June 2018
- Bykov, Maxim; Bykova, Elena; Koemets, Egor
- Angewandte Chemie, Vol. 130, Issue 29
High-Pressure Synthesis of a Nitrogen-Rich Inclusion Compound ReN 8 ⋅ x N 2 with Conjugated Polymeric Nitrogen Chains
journal, June 2018
- Bykov, Maxim; Bykova, Elena; Koemets, Egor
- Angewandte Chemie International Edition, Vol. 57, Issue 29
Single crystal growth, crystalline structure investigation and high-pressure behavior of impurity-free siderite (FeCO3)
journal, March 2018
- Liang, Wen; Yin, Yuan; Li, Zeming
- Physics and Chemistry of Minerals, Vol. 45, Issue 9
Thermal Conductivity Anomaly in (Fe 0.78 Mg 0.22 )CO 3 Siderite Across Spin Transition of Iron
journal, February 2019
- Chao, Keng‐Hsien; Hsieh, Wen‐Pin
- Journal of Geophysical Research: Solid Earth, Vol. 124, Issue 2
Stability and nature of the volume collapse of ε-Fe2O3 under extreme conditions
journal, November 2018
- Sans, J. A.; Monteseguro, V.; Garbarino, G.
- Nature Communications, Vol. 9, Issue 1
Pressure driven spin transition in siderite and magnesiosiderite single crystals
journal, November 2017
- Weis, Christopher; Sternemann, Christian; Cerantola, Valerio
- Scientific Reports, Vol. 7, Issue 1
Combining X-ray Kβ 1,3 , valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite
journal, January 2019
- Weis, Christopher; Spiekermann, Georg; Sternemann, Christian
- Journal of Analytical Atomic Spectrometry, Vol. 34, Issue 2
Pentacoordinated silicon in the high-pressure modification of datolite, CaBSiO 4 (OH)
journal, January 2018
- Gorelova, Liudmila A.; Pakhomova, Anna S.; Aprilis, Georgios
- Inorganic Chemistry Frontiers, Vol. 5, Issue 7
Natural diamond formation by self-redox of ferromagnesian carbonate
journal, February 2018
- Chen, Ming; Shu, Jinfu; Xie, Xiande
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 11
CO2-induced destabilization of pyrite-structured FeO2Hx in the lower mantle
journal, March 2018
- Boulard, Eglantine; Guyot, François; Menguy, Nicolas
- National Science Review, Vol. 5, Issue 6
Carbon, carbides, carbonates and carbonatitic melts in the Earth's interior
journal, January 2019
- Stagno, Vincenzo
- Journal of the Geological Society, Vol. 176, Issue 2
Polymerized 4-Fold Coordinated Carbonate Melts in the Deep Mantle
text, January 2019
- Sanloup, Chrystèle; Hudspeth, Jessica M.; Afonina, Veronika
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Pressure driven spin transition in siderite and magnesiosiderite single crystals
text, January 2017
- Weis, Christopher; Sternemann, Christian; Cerantola, Valerio
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
High-pressure synthesis of a nitrogen-rich inclusion compound $ReN_{8}·xN_{2}$ with conjugated polymeric nitrogen chains
text, January 2018
- Bykov, Maxim; Bykova, Elena; Koemets, Egor
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Polymerized 4-Fold Coordinated Carbonate Melts in the Deep Mantle
journal, April 2019
- Sanloup, Chrystèle; Hudspeth, Jessica M.; Afonina, Veronika
- Frontiers in Earth Science, Vol. 7
Natural diamond formation by self-redox of ferromagnesian carbonate
journal, February 2018
- Chen, Ming; Shu, Jinfu; Xie, Xiande
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 11
Pressure driven spin transition in siderite and magnesiosiderite single crystals
text, January 2017
- Weis, Christopher; Sternemann, Christian; Cerantola, Valerio
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Figures / Tables found in this record: