Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu)

Svanidze, E.; II, M. Kindy; Georgen, C.; Fulfer, B. W.; Lapidus, S. H.; Chan, J. Y.; Morosan, E.

doi:10.1016/j.jmmm.2016.04.082

Title: Magnetic and crystallographic properties of ZrM_2-δZn_20+δ (M=Cr–Cu)

Abstract

Single crystals of the cubic Laves ternaries ZrM_2-δZn_20+δ (M=Mn, Fe, Co, Ni and Cu, 0 ≤ δ ≤ 1) have been synthesized in this paper using a self-flux method. The magnetic properties of these compounds were compared with structurally similar cubic binaries ZrM₂ (M=Mn, Fe, Co, Ni and Cu). A transition from local to itinerant moment magnetism was observed for M=Fe and M=Mn, while all other ternaries exhibit weakly para- or diamagnetic behavior. The local-to-itinerant crossover can be explained by a nearly two-fold increase of the M–M bond length d_M–M in ZrM_2-δZn_20+δ compounds, as compared with the ZrM₂ binaries. Additionally, we report two new compounds in this series ZrCrZn₂₁ and ZrCu₂Zn₂₀. Finally, analysis of crystallographic and magnetic trends in these materials will aid in understanding of magnetism in general and 3d intermetallics in particular.

Authors:

Svanidze, E. ^[1]; II, M. Kindy ^[1]; Georgen, C. ^[1]; Fulfer, B. W. ^[2]; Lapidus, S. H. ^[3]; Chan, J. Y. ^[2]; Morosan, E. ^[1]

Rice Univ., Houston, TX (United States)
Univ. of Texas, Dallas, TX (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Fri Apr 29 00:00:00 EDT 2016

Research Org.:: Rice Univ., Houston, TX (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE; National Science Foundation (NSF)

OSTI Identifier:: 1392294

Grant/Contract Number:: AC02-06CH11357; DMR-1506704; DMR-1063735; DMR-1360863

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Magnetism and Magnetic Materials

Additional Journal Information:: Journal Volume: 416; Journal ID: ISSN 0304-8853

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; magnetism; itinerant magnetism; transition metal; intermetallics; magnetic moment dilution; cubic Laves phases

Citation Formats


                    Svanidze, E., II, M. Kindy, Georgen, C., Fulfer, B. W., Lapidus, S. H., Chan, J. Y., and Morosan, E. Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu).  United States: N. p., 2016. 
Web.  doi:10.1016/j.jmmm.2016.04.082.

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                    Svanidze, E., II, M. Kindy, Georgen, C., Fulfer, B. W., Lapidus, S. H., Chan, J. Y., & Morosan, E. Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu).  United States.  https://doi.org/10.1016/j.jmmm.2016.04.082

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                    Svanidze, E., II, M. Kindy, Georgen, C., Fulfer, B. W., Lapidus, S. H., Chan, J. Y., and Morosan, E. Fri .  
"Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu)".  United States.  https://doi.org/10.1016/j.jmmm.2016.04.082.  https://www.osti.gov/servlets/purl/1392294.

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@article{osti_1392294,

  title        = {Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu)},

  author       = {Svanidze, E. and II, M. Kindy and Georgen, C. and Fulfer, B. W. and Lapidus, S. H. and Chan, J. Y. and Morosan, E.},

  abstractNote = {Single crystals of the cubic Laves ternaries ZrM2-δZn20+δ (M=Mn, Fe, Co, Ni and Cu, 0 ≤ δ ≤ 1) have been synthesized in this paper using a self-flux method. The magnetic properties of these compounds were compared with structurally similar cubic binaries ZrM2 (M=Mn, Fe, Co, Ni and Cu). A transition from local to itinerant moment magnetism was observed for M=Fe and M=Mn, while all other ternaries exhibit weakly para- or diamagnetic behavior. The local-to-itinerant crossover can be explained by a nearly two-fold increase of the M–M bond length dM–M in ZrM2-δZn20+δ compounds, as compared with the ZrM2 binaries. Additionally, we report two new compounds in this series ZrCrZn21 and ZrCu2Zn20. Finally, analysis of crystallographic and magnetic trends in these materials will aid in understanding of magnetism in general and 3d intermetallics in particular.},

  doi          = {10.1016/j.jmmm.2016.04.082},

  journal      = {Journal of Magnetism and Magnetic Materials},

  number       = ,

  volume       = 416,

  place        = {United States},

  year         = {Fri Apr 29 00:00:00 EDT 2016},

  month        = {Fri Apr 29 00:00:00 EDT 2016}

}

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Works referencing / citing this record:

Disorder-driven non-Fermi liquid behavior in itinerant ferromagnet α -Co ₅ Ge ₃
journal, January 2020

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Title: Magnetic and crystallographic properties of ZrM2-δZn20+δ (M=Cr–Cu)

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Structural and magnetic properties of non-stoichiometric Fe 2 Zr journal, August 2007

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Generalized Gradient Approximation Made Simple journal, October 1996

Magnetic properties of the Zr(Cr1−xNix)2 alloys and their hydrides journal, February 1993

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Transition from itinerant electron to local moment system in Y(Mn1−xAlx)2 journal, February 1986

Critical Phenomena and the Quantum Critical Point of Ferromagnetic Zr 1 − x Nb x Zn 2 journal, March 2006

An itinerant antiferromagnetic metal without magnetic constituents journal, July 2015

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Hydrogen in Laves phase Zr X 2 ( X = V , Cr, Mn, Fe, Co, Ni) compounds: Binding energies and electronic and magnetic structure journal, September 2002

Pressure Dependent Magnetism in Y1.05(Mn0.95Al0.05)2 journal, January 2012

Transitions from local moment to itinerant magnetism as a function of composition in alloys journal, July 1977

Neutron diffraction study of ZrM2D deuterides (M=Fe, Co) journal, August 2003

On the magnetic behaviour of ACo2 (A = Y, Lu, Zr, Sc and Hf) compounds journal, May 1993

Magnetism and Electronic Structure of Sc3In journal, August 2007

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Title: Magnetic and crystallographic properties of ZrM_2-δZn_20+δ (M=Cr–Cu)

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Magnetic order in ${TbCo}_{2} {Zn}_{20}$ and ${TbFe}_{2} {Zn}_{20}$
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Nearly ferromagnetic Fermi-liquid behaviour in YFe2Zn20 and high-temperature ferromagnetism of GdFe2Zn20
journal, March 2007

Magnetic properties of ${Gd}_{x} Y_{1 - x} {Fe}_{2} {Zn}_{20}$ : Dilute, large- $S$ moments in a nearly ferromagnetic Fermi liquid
journal, November 2007

Magnetism and spin fluctuations of laves phase manganese compounds
journal, March 1988

Generalized Gradient Approximation Made Simple
journal, October 1996

Magnetic properties of the Zr(Cr1−xNix)2 alloys and their hydrides
journal, February 1993

Magnetic and structural characteristics of TiCr2, ZrCr2, HfCr2 and the TiCo2ZrCo2 and YFe2YCo2 alloy systems
journal, October 1968

Transition from itinerant electron to local moment system in Y(Mn1−xAlx)2
journal, February 1986

Critical Phenomena and the Quantum Critical Point of Ferromagnetic ${Zr}_{1 - x} {Nb}_{x} {Zn}_{2}$
journal, March 2006

An itinerant antiferromagnetic metal without magnetic constituents
journal, July 2015

A new polymorphic material? Structural degeneracy of ZrMn ₂
journal, September 2004

Hydrogen in Laves phase $Zr X_{2}$ $(X = V,$ Cr, Mn, Fe, Co, Ni) compounds: Binding energies and electronic and magnetic structure
journal, September 2002

Pressure Dependent Magnetism in Y1.05(Mn0.95Al0.05)2
journal, January 2012

Transitions from local moment to itinerant magnetism as a function of composition in alloys
journal, July 1977

Neutron diffraction study of ZrM2D deuterides (M=Fe, Co)
journal, August 2003

On the magnetic behaviour of ACo2 (A = Y, Lu, Zr, Sc and Hf) compounds
journal, May 1993

Magnetism and Electronic Structure of Sc3In
journal, August 2007

Self-consistent spin polarized energy band structure and magnetism in ZrZn2 and TiBe2
journal, June 1981

Phase stability and neutron diffraction studies of Laves phases Zr(Cr1−M )2 with M = Mn, Fe, Co, Ni, Cu and 0 < x < 0.2 and their hydrides
journal, March 1995

Formation of the Laves phases in Co/Fe-V-Zr and their magnetic and superconducting properties
journal, May 1992

Thermal expansion of ZrZn2
journal, April 1983

Quantum Phase Transitions in the Itinerant Ferromagnet ${Z r Z n}_{2}$
journal, December 2004

Superconductivity in zirconium-nickel glasses
journal, July 1981

Paramagnetic susceptibility of Zr Zn2
journal, May 1966

Disorder-driven non-Fermi liquid behavior in itinerant ferromagnet α -Co ₅ Ge ₃
journal, January 2020