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Title: Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries

Abstract

We present that irreversible electrochemical behavior and large voltage hysteresis are commonly observed in battery materials, in particular for materials reacting through conversion reaction, resulting in undesirable round-trip energy loss and low coulombic efficiency. Seeking solutions to these challenges relies on the understanding of the underlying mechanism and physical origins. Here, this study combines in operando 2D transmission X-ray microscopy with X-ray absorption near edge structure, 3D tomography, and galvanostatic intermittent titration techniques to uncover the conversion reaction in sodium–metal sulfide batteries, a promising high-energy battery system. This study shows a high irreversible electrochemistry process predominately occurs at first cycle, which can be largely linked to Na ion trapping during the first desodiation process and large interfacial ion mobility resistance. Subsequently, phase transformation evolution and electrochemical reaction show good reversibility at multiple discharge/charge cycles due to materials' microstructural change and equilibrium. The origin of large hysteresis between discharge and charge is investigated and it can be attributed to multiple factors including ion mobility resistance at the two-phase interface, intrinsic slow sodium ion diffusion kinetics, and irreversibility as well as ohmic voltage drop and overpotential. In conclusion, this study expects that such understandings will help pave the way for engineering designmore » and optimization of materials microstructure for future-generation batteries.« less

Authors:
 [1];  [1];  [1];  [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1392215
Alternate Identifier(s):
OSTI ID: 1401282
Report Number(s):
BNL-114149-2017-JA
Journal ID: ISSN 1614-6832
Grant/Contract Number:  
SC0012704; AC02-98CH10886; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 14; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; batteries; synchrotron; conversion reaction; electrochemistry

Citation Formats

Wang, Jiajun, Wang, Liguang, Eng, Christopher, and Wang, Jun. Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries. United States: N. p., 2017. Web. doi:10.1002/aenm.201602706.
Wang, Jiajun, Wang, Liguang, Eng, Christopher, & Wang, Jun. Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries. United States. doi:10.1002/aenm.201602706.
Wang, Jiajun, Wang, Liguang, Eng, Christopher, and Wang, Jun. Fri . "Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries". United States. doi:10.1002/aenm.201602706. https://www.osti.gov/servlets/purl/1392215.
@article{osti_1392215,
title = {Elucidating the Irreversible Mechanism and Voltage Hysteresis in Conversion Reaction for High-Energy Sodium-Metal Sulfide Batteries},
author = {Wang, Jiajun and Wang, Liguang and Eng, Christopher and Wang, Jun},
abstractNote = {We present that irreversible electrochemical behavior and large voltage hysteresis are commonly observed in battery materials, in particular for materials reacting through conversion reaction, resulting in undesirable round-trip energy loss and low coulombic efficiency. Seeking solutions to these challenges relies on the understanding of the underlying mechanism and physical origins. Here, this study combines in operando 2D transmission X-ray microscopy with X-ray absorption near edge structure, 3D tomography, and galvanostatic intermittent titration techniques to uncover the conversion reaction in sodium–metal sulfide batteries, a promising high-energy battery system. This study shows a high irreversible electrochemistry process predominately occurs at first cycle, which can be largely linked to Na ion trapping during the first desodiation process and large interfacial ion mobility resistance. Subsequently, phase transformation evolution and electrochemical reaction show good reversibility at multiple discharge/charge cycles due to materials' microstructural change and equilibrium. The origin of large hysteresis between discharge and charge is investigated and it can be attributed to multiple factors including ion mobility resistance at the two-phase interface, intrinsic slow sodium ion diffusion kinetics, and irreversibility as well as ohmic voltage drop and overpotential. In conclusion, this study expects that such understandings will help pave the way for engineering design and optimization of materials microstructure for future-generation batteries.},
doi = {10.1002/aenm.201602706},
journal = {Advanced Energy Materials},
number = 14,
volume = 7,
place = {United States},
year = {2017},
month = {3}
}

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