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Title: Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Division of Chemistry and Chemical Engineering, ‡Joint Center for Artificial Photosynthesis, £Resnick Sustainability Institute, ∥Division of Engineering and Applied Sciences, and §Beckman Institute Molecular Materials Research Center, California Institute of Technology, Pasadena, California 91125, United States
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1392190
Grant/Contract Number:  
SC0004993
Resource Type:
Published Article
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Name: ACS Catalysis Journal Volume: 6 Journal Issue: 3; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Torelli, Daniel A., Francis, Sonja A., Crompton, J. Chance, Javier, Alnald, Thompson, Jonathan R., Brunschwig, Bruce S., Soriaga, Manuel P., and Lewis, Nathan S.. Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials. United States: N. p., 2016. Web. https://doi.org/10.1021/acscatal.5b02888.
Torelli, Daniel A., Francis, Sonja A., Crompton, J. Chance, Javier, Alnald, Thompson, Jonathan R., Brunschwig, Bruce S., Soriaga, Manuel P., & Lewis, Nathan S.. Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials. United States. https://doi.org/10.1021/acscatal.5b02888
Torelli, Daniel A., Francis, Sonja A., Crompton, J. Chance, Javier, Alnald, Thompson, Jonathan R., Brunschwig, Bruce S., Soriaga, Manuel P., and Lewis, Nathan S.. Tue . "Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials". United States. https://doi.org/10.1021/acscatal.5b02888.
@article{osti_1392190,
title = {Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials},
author = {Torelli, Daniel A. and Francis, Sonja A. and Crompton, J. Chance and Javier, Alnald and Thompson, Jonathan R. and Brunschwig, Bruce S. and Soriaga, Manuel P. and Lewis, Nathan S.},
abstractNote = {},
doi = {10.1021/acscatal.5b02888},
journal = {ACS Catalysis},
number = 3,
volume = 6,
place = {United States},
year = {2016},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscatal.5b02888

Citation Metrics:
Cited by: 69 works
Citation information provided by
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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction
journal, January 2012

  • Tang, Wei; Peterson, Andrew A.; Varela, Ana Sofia
  • Phys. Chem. Chem. Phys., Vol. 14, Issue 1
  • DOI: 10.1039/C1CP22700A

A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO 2 to CO
journal, December 2014

  • Rasul, Shahid; Anjum, Dalaver H.; Jedidi, Abdesslem
  • Angewandte Chemie International Edition, Vol. 54, Issue 7
  • DOI: 10.1002/anie.201410233

Electrochemistry of Acids on Platinum. Application to the Reduction of Carbon Dioxide in the Presence of Pyridinium Ion in Water
journal, November 2013

  • Costentin, Cyrille; Canales, Juan Carlos; Haddou, Baptiste
  • Journal of the American Chemical Society, Vol. 135, Issue 47
  • DOI: 10.1021/ja407988w

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014

  • Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
  • Nature, Vol. 508, Issue 7497
  • DOI: 10.1038/nature13249

Electrochemical Reduction of CO at a Copper Electrode
journal, September 1997

  • Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru
  • The Journal of Physical Chemistry B, Vol. 101, Issue 36
  • DOI: 10.1021/jp970284i

Design of alloy electrocatalysts for CO2 reduction
journal, May 1991

  • Watanabe, Masahiro; Shibata, Masami; Katoh, Akihiro
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 305, Issue 2
  • DOI: 10.1016/0022-0728(91)85528-W

Composition-dependent activity of Cu–Pt alloy nanocubes for electrocatalytic CO 2 reduction
journal, January 2015

  • Zhao, Xueyu; Luo, Binbin; Long, Ran
  • Journal of Materials Chemistry A, Vol. 3, Issue 8
  • DOI: 10.1039/C4TA06608A

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014

  • Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1873

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides
journal, April 2004


Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
journal, August 2014

  • Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R.
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja505791r

Design of Allory Electrocatalysts for CO2 Reduction (I).The Selective and Reversible Reduction of CO2 at Cu-Ni Alloy Electrodes
journal, January 1991


Pulsed Electroreduction of CO[sub 2] on Cu-Ag Alloy Electrodes
journal, January 2000

  • Ishimaru, S.; Shiratsuchi, R.; Nogami, G.
  • Journal of The Electrochemical Society, Vol. 147, Issue 5
  • DOI: 10.1149/1.1393448

Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces
journal, January 2014

  • Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 27
  • DOI: 10.1039/C4CP00692E

The influence of pH on the reduction of CO and CO 2 to hydrocarbons on copper electrodes
journal, March 2014

  • Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M.
  • Journal of Electroanalytical Chemistry, Vol. 716
  • DOI: 10.1016/j.jelechem.2013.08.033

Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond
journal, September 2015

  • Liu, Yanming; Chen, Shuo; Quan, Xie
  • Journal of the American Chemical Society, Vol. 137, Issue 36
  • DOI: 10.1021/jacs.5b02975

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

  • Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs502128q

Gold–Copper Nanoalloys Supported on TiO 2 as Photocatalysts for CO 2 Reduction by Water
journal, October 2014

  • Neaţu, Ştefan; Maciá-Agulló, Juan Antonio; Concepción, Patricia
  • Journal of the American Chemical Society, Vol. 136, Issue 45
  • DOI: 10.1021/ja506433k

Electrochemical CO 2 reduction on Cu 2 O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons
journal, January 2014

  • Kas, Recep; Kortlever, Ruud; Milbrat, Alexander
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 24
  • DOI: 10.1039/c4cp01520g

Selective Solar-Driven Reduction of CO 2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell
journal, May 2008

  • Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B.
  • Journal of the American Chemical Society, Vol. 130, Issue 20
  • DOI: 10.1021/ja0776327

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

  • Manthiram, Karthish; Beberwyck, Brandon J.; Alivisatos, A. Paul
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja5065284

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
journal, January 2010

  • Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix
  • Energy & Environmental Science, Vol. 3, Issue 9
  • DOI: 10.1039/c0ee00071j

PRODUCTION OF CO AND CH 4 IN ELECTROCHEMICAL REDUCTION OF CO 2 AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION
journal, November 1985

  • Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin
  • Chemistry Letters, Vol. 14, Issue 11
  • DOI: 10.1246/cl.1985.1695

Reactions and Mechanism of the Electrochemical Reduction of Carbon Dioxide at Alloyed Copper-Silver Electrodes
journal, January 1991


Synthesis of thin film AuPd alloys and their investigation for electrocatalytic CO 2 reduction
journal, January 2015

  • Hahn, Christopher; Abram, David N.; Hansen, Heine A.
  • Journal of Materials Chemistry A, Vol. 3, Issue 40
  • DOI: 10.1039/C5TA04863J

Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution
journal, January 1989

  • Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 8
  • DOI: 10.1039/f19898502309

Reduction of Carbon Dioxide to Methanol on n- and p-GaAs and p-InP. Effect of Crystal Face, Electrolyte and Current Density
journal, January 1983

  • Canfield, D.
  • Journal of The Electrochemical Society, Vol. 130, Issue 8
  • DOI: 10.1149/1.2120090

Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates
journal, May 2009


Intermetallic Alloys as CO Electroreduction Catalysts—Role of Isolated Active Sites
journal, May 2014

  • Karamad, Mohammadreza; Tripkovic, Vladimir; Rossmeisl, Jan
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500328c

Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles
journal, September 2014

  • Kim, Dohyung; Resasco, Joaquin; Yu, Yi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5948

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

Electrochemical evidence of intermediate formation of adsorbed CO in cathodic reduction of CO2 at a nickel electrode
journal, November 1990


Electrochemical reduction of CO 2 to ethylene glycol on imidazolium ion-terminated self-assembly monolayer-modified Au electrodes in an aqueous solution
journal, January 2015

  • Tamura, Jun; Ono, Akihiko; Sugano, Yoshitsune
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 39
  • DOI: 10.1039/C5CP03028E

Metal-Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO 2 Electroreduction to CO and Hydrocarbons
journal, July 2015

  • Varela, Ana Sofia; Ranjbar Sahraie, Nastaran; Steinberg, Julian
  • Angewandte Chemie International Edition, Vol. 54, Issue 37
  • DOI: 10.1002/anie.201502099

Reduction of CO[sub 2] on n-GaAs Electrodes and Selective Methanol Synthesis
journal, January 1984

  • Frese, K. W.
  • Journal of The Electrochemical Society, Vol. 131, Issue 11
  • DOI: 10.1149/1.2115351

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

  • Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
  • Angewandte Chemie International Edition, Vol. 54, Issue 17
  • DOI: 10.1002/anie.201412214

Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals
journal, April 2013

  • Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M.
  • ACS Catalysis, Vol. 3, Issue 6
  • DOI: 10.1021/cs4002404

Carbon dioxide reduction on gallium arsenide electrodes
journal, July 1985

  • Sears, W. M.; Morrison, S. Roy
  • The Journal of Physical Chemistry, Vol. 89, Issue 15
  • DOI: 10.1021/j100261a026

Electroreduction of Carbon Dioxide on Copper-Based Electrodes: Activity of Copper Single Crystals and Copper–Gold Alloys
journal, April 2012


A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
journal, January 2014

  • Qiao, Jinli; Liu, Yuyu; Hong, Feng
  • Chem. Soc. Rev., Vol. 43, Issue 2
  • DOI: 10.1039/C3CS60323G