Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes

Sun, Ke; McDowell, Matthew T.; Nielander, Adam C.; Hu, Shu; Shaner, Matthew R.; Yang, Fan; Brunschwig, Bruce S.; Lewis, Nathan S.

doi:10.1021/jz5026195

Title: Stable Solar-Driven Water Oxidation to O ₂ (g) by Ni-Oxide-Coated Silicon Photoanodes

Authors:

Sun, Ke ^[1]; McDowell, Matthew T. ^[1]; Nielander, Adam C. ^[1]; Hu, Shu ^[1]; Shaner, Matthew R. ^[1]; Yang, Fan ^[1]; Brunschwig, Bruce S. ^[1]; Lewis, Nathan S. ^[1]

Division of Chemistry and Chemical Engineering, ‡Joint Center for Artificial Photosynthesis, §Beckman Institute and Molecular Materials Research Center, and ∥Kavli Nanoscience Institute, California Institute of Technology, Pasadena, California 91125, United States

Publication Date:: Thu Jan 29 00:00:00 EST 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1392187

Resource Type:: Published Article

Journal Name:: Journal of Physical Chemistry Letters

Additional Journal Information:: Journal Name: Journal of Physical Chemistry Letters Journal Volume: 6 Journal Issue: 4; Journal ID: ISSN 1948-7185

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Sun, Ke, McDowell, Matthew T., Nielander, Adam C., Hu, Shu, Shaner, Matthew R., Yang, Fan, Brunschwig, Bruce S., and Lewis, Nathan S. Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes.  United States: N. p., 2015. 
Web.  doi:10.1021/jz5026195.

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                    Sun, Ke, McDowell, Matthew T., Nielander, Adam C., Hu, Shu, Shaner, Matthew R., Yang, Fan, Brunschwig, Bruce S., & Lewis, Nathan S. Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes.  United States.  https://doi.org/10.1021/jz5026195

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                    Sun, Ke, McDowell, Matthew T., Nielander, Adam C., Hu, Shu, Shaner, Matthew R., Yang, Fan, Brunschwig, Bruce S., and Lewis, Nathan S. Thu .  
"Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes".  United States.  https://doi.org/10.1021/jz5026195.

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@article{osti_1392187,

  title        = {Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes},

  author       = {Sun, Ke and McDowell, Matthew T. and Nielander, Adam C. and Hu, Shu and Shaner, Matthew R. and Yang, Fan and Brunschwig, Bruce S. and Lewis, Nathan S.},

  abstractNote = {},

  doi          = {10.1021/jz5026195},

  journal      = {Journal of Physical Chemistry Letters},

  number       = 4,

  volume       = 6,

  place        = {United States},

  year         = {Thu Jan 29 00:00:00 EST 2015},

  month        = {Thu Jan 29 00:00:00 EST 2015}

}

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Title: Stable Solar-Driven Water Oxidation to O 2 (g) by Ni-Oxide-Coated Silicon Photoanodes

Citation Formats

Highly active oxide photocathode for photoelectrochemical water reduction journal, May 2011

Photoelectrochemical Behavior of n-type Si(100) Electrodes Coated with Thin Films of Manganese Oxide Grown by Atomic Layer Deposition journal, March 2013

Heterojunction Photoelectrodes: III . Cyclic Voltammetry at Indium Tin Oxide‐Coated Silicon/Aqueous Redox Electrolyte Interfaces journal, March 1986

Degradation of the electrochromic nickel oxide film upon redox cycling journal, July 1996

Metal Oxide Composite Enabled Nanotextured Si Photoanode for Efficient Solar Driven Water Oxidation journal, April 2013

Powering the planet: Chemical challenges in solar energy utilization journal, October 2006

Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces journal, April 2014

Current-voltage characteristics of coupled photodiode-electrocatalyst devices journal, September 2013

Si photoanode protected by a metal modified ITO layer with ultrathin NiO x for solar water oxidation journal, January 2014

Iron-Treated NiO as a Highly Transparent p-Type Protection Layer for Efficient Si-Based Photoanodes journal, September 2014

Protection of p + -n-Si Photoanodes by Sputter-Deposited Ir/IrO x Thin Films journal, May 2014

An Optocatalytic Model for Semiconductor–Catalyst Water-Splitting Photoelectrodes Based on In Situ Optical Measurements on Operational Catalysts journal, March 2013

High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation journal, November 2013

Photoelectrochemical Generation of Chlorine on Catalytically Modified n‐Silicon/Indium Tin Oxide Anodes journal, September 1982

The microstructure and electrochromic properties of nickel oxide films deposited with different substrate temperatures journal, April 1997

p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production journal, September 2012

An optical study of the deposition and conversion of nickel hydroxide films journal, June 1976

Theory and Simulations of Electrocatalyst-Coated Semiconductor Electrodes for Solar Water Splitting journal, April 2014

An ellipsometric investigation of nickel oxide films in alkaline solution: The multilayer film approach journal, May 1989

Heterojunction silicon/indium tin oxide photoelectrodes: development of stable systems in aqueous electrolytes and their applicability to solar energy conversion and storage journal, February 1983

Atomic layer-deposited tunnel oxide stabilizes silicon photoanodes for water oxidation journal, June 2011

Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation journal, May 2014

Solar Water Splitting Cells journal, November 2010

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation journal, April 2014

High Photocurrent in Silicon Photoanodes Catalyzed by Iron Oxide Thin Films for Water Oxidation journal, November 2011

Light-induced water oxidation at silicon electrodes functionalized with a cobalt oxygen-evolving catalyst journal, June 2011

Anisotropy in the Anodic Oxidation of Silicon in KOH Solution journal, September 2005

An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems journal, January 2013

Efficient electrochromic nickel oxide thin films by electrodeposition journal, January 2010

Improved n-Si/oxide junctions for environmentally safe solar energy conversion journal, February 2002

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An Integrated, Systems Approach to the Development of Solar Fuel Generators journal, January 2013

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Title: Stable Solar-Driven Water Oxidation to O ₂ (g) by Ni-Oxide-Coated Silicon Photoanodes

Highly active oxide photocathode for photoelectrochemical water reduction
journal, May 2011

Photoelectrochemical Behavior of n-type Si(100) Electrodes Coated with Thin Films of Manganese Oxide Grown by Atomic Layer Deposition
journal, March 2013

Heterojunction Photoelectrodes: III . Cyclic Voltammetry at Indium Tin Oxide‐Coated Silicon/Aqueous Redox Electrolyte Interfaces
journal, March 1986

Degradation of the electrochromic nickel oxide film upon redox cycling
journal, July 1996

Metal Oxide Composite Enabled Nanotextured Si Photoanode for Efficient Solar Driven Water Oxidation
journal, April 2013

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces
journal, April 2014

Current-voltage characteristics of coupled photodiode-electrocatalyst devices
journal, September 2013

Si photoanode protected by a metal modified ITO layer with ultrathin NiO _x for solar water oxidation
journal, January 2014

Iron-Treated NiO as a Highly Transparent p-Type Protection Layer for Efficient Si-Based Photoanodes
journal, September 2014

Protection of p ⁺ -n-Si Photoanodes by Sputter-Deposited Ir/IrO _x Thin Films
journal, May 2014

An Optocatalytic Model for Semiconductor–Catalyst Water-Splitting Photoelectrodes Based on In Situ Optical Measurements on Operational Catalysts
journal, March 2013

High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation
journal, November 2013

Photoelectrochemical Generation of Chlorine on Catalytically Modified n‐Silicon/Indium Tin Oxide Anodes
journal, September 1982

The microstructure and electrochromic properties of nickel oxide films deposited with different substrate temperatures
journal, April 1997

p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production
journal, September 2012

An optical study of the deposition and conversion of nickel hydroxide films
journal, June 1976

Theory and Simulations of Electrocatalyst-Coated Semiconductor Electrodes for Solar Water Splitting
journal, April 2014

An ellipsometric investigation of nickel oxide films in alkaline solution: The multilayer film approach
journal, May 1989

Heterojunction silicon/indium tin oxide photoelectrodes: development of stable systems in aqueous electrolytes and their applicability to solar energy conversion and storage
journal, February 1983

Atomic layer-deposited tunnel oxide stabilizes silicon photoanodes for water oxidation
journal, June 2011

Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation
journal, May 2014

Solar Water Splitting Cells
journal, November 2010

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation
journal, April 2014

High Photocurrent in Silicon Photoanodes Catalyzed by Iron Oxide Thin Films for Water Oxidation
journal, November 2011

Light-induced water oxidation at silicon electrodes functionalized with a cobalt oxygen-evolving catalyst
journal, June 2011

Anisotropy in the Anodic Oxidation of Silicon in KOH Solution
journal, September 2005

An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems
journal, January 2013

Efficient electrochromic nickel oxide thin films by electrodeposition
journal, January 2010

Improved n-Si/oxide junctions for environmentally safe solar energy conversion
journal, February 2002

Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution
journal, October 2012

Anisotropic Etching of Crystalline Silicon in Alkaline Solutions: I . Orientation Dependence and Behavior of Passivation Layers
journal, January 1990

An Integrated, Systems Approach to the Development of Solar Fuel Generators
journal, January 2013

Nickel oxide functionalized silicon for efficient photo-oxidation of water
journal, January 2012

Amorphous Si Thin Film Based Photocathodes with High Photovoltage for Efficient Hydrogen Production
journal, October 2013

Using TiO ₂ as a Conductive Protective Layer for Photocathodic H ₂ Evolution
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