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Title: Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries

Although the energy densities of batteries continue to increase, safety problems (for example, fires and explosions) associated with the use of highly flammable liquid organic electrolytes remain a big issue, significantly hindering further practical applications of the next generation of high-energy batteries. We have fabricated a novel “smart” nonwoven electrospun separator with thermal-triggered flame-retardant properties for lithium-ion batteries. The encapsulation of a flame retardant inside a protective polymer shell has prevented direct dissolution of the retardant agent into the electrolyte, which would otherwise have negative effects on battery performance. Furthermore, during thermal runaway of the lithium-ion battery, the protective polymer shell would melt, triggered by the increased temperature, and the flame retardant would be released, thus effectively suppressing the combustion of the highly flammable electrolytes.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2]
  1. Stanford Univ., Stanford, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Grant/Contract Number:
AC02-76SF00515
Type:
Accepted Manuscript
Journal Name:
Science Advances
Additional Journal Information:
Journal Volume: 3; Journal Issue: 1; Journal ID: ISSN 2375-2548
Publisher:
AAAS
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; lithium ion batteries; flame-retardant; smart separator; thermal responsive
OSTI Identifier:
1390314

Liu, Kai, Liu, Wei, Qiu, Yongcai, Kong, Biao, Sun, Yongming, Chen, Zheng, Zhuo, Denys, Lin, Dingchang, and Cui, Yi. Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries. United States: N. p., Web. doi:10.1126/sciadv.1601978.
Liu, Kai, Liu, Wei, Qiu, Yongcai, Kong, Biao, Sun, Yongming, Chen, Zheng, Zhuo, Denys, Lin, Dingchang, & Cui, Yi. Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries. United States. doi:10.1126/sciadv.1601978.
Liu, Kai, Liu, Wei, Qiu, Yongcai, Kong, Biao, Sun, Yongming, Chen, Zheng, Zhuo, Denys, Lin, Dingchang, and Cui, Yi. 2017. "Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries". United States. doi:10.1126/sciadv.1601978. https://www.osti.gov/servlets/purl/1390314.
@article{osti_1390314,
title = {Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries},
author = {Liu, Kai and Liu, Wei and Qiu, Yongcai and Kong, Biao and Sun, Yongming and Chen, Zheng and Zhuo, Denys and Lin, Dingchang and Cui, Yi},
abstractNote = {Although the energy densities of batteries continue to increase, safety problems (for example, fires and explosions) associated with the use of highly flammable liquid organic electrolytes remain a big issue, significantly hindering further practical applications of the next generation of high-energy batteries. We have fabricated a novel “smart” nonwoven electrospun separator with thermal-triggered flame-retardant properties for lithium-ion batteries. The encapsulation of a flame retardant inside a protective polymer shell has prevented direct dissolution of the retardant agent into the electrolyte, which would otherwise have negative effects on battery performance. Furthermore, during thermal runaway of the lithium-ion battery, the protective polymer shell would melt, triggered by the increased temperature, and the flame retardant would be released, thus effectively suppressing the combustion of the highly flammable electrolytes.},
doi = {10.1126/sciadv.1601978},
journal = {Science Advances},
number = 1,
volume = 3,
place = {United States},
year = {2017},
month = {1}
}

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