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Title: Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film Substrates

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [3]
+ Show Author Affiliations
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States); Univ. of Colorado, Boulder, CO (United States). Department of Electrical, Computer, and Energy Engineering
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1393379
Alternate Identifier(s):
OSTI ID: 1390308
Report Number(s):
NREL/JA-5K00-68900
Journal ID: ISSN 0897-4756
Grant/Contract Number:  
AC36-08GO28308; EE0005951; AC02-76SF00515; AC36-08G028308
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 14; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; XRD; perovskites; solar

Citation Formats

Dou, Benjia, Pool, Vanessa L., Toney, Michael F., and van Hest, Maikel F. A. M. Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film Substrates. United States: N. p., 2017. Web. doi:10.1021/acs.chemmater.7b01467.
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Dou, Benjia, Pool, Vanessa L., Toney, Michael F., & van Hest, Maikel F. A. M. Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film Substrates. United States. https://doi.org/10.1021/acs.chemmater.7b01467
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Dou, Benjia, Pool, Vanessa L., Toney, Michael F., and van Hest, Maikel F. A. M. Mon . "Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film Substrates". United States. https://doi.org/10.1021/acs.chemmater.7b01467. https://www.osti.gov/servlets/purl/1393379.
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@article{osti_1393379,
title = {Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film Substrates},
author = {Dou, Benjia and Pool, Vanessa L. and Toney, Michael F. and van Hest, Maikel F. A. M.},
abstractNote = {},
doi = {10.1021/acs.chemmater.7b01467},
journal = {Chemistry of Materials},
number = 14,
volume = 29,
place = {United States},
year = {Mon Jun 19 00:00:00 EDT 2017},
month = {Mon Jun 19 00:00:00 EDT 2017}
}
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Publisher's Version of Record
https://doi.org/10.1021/acs.chemmater.7b01467
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Works referenced in this record:

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Hybrid Perovskites for Photovoltaics: Charge-Carrier Recombination, Diffusion, and Radiative Efficiencies
journal, December 2015

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014

  • Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
  • Nature Materials, Vol. 13, Issue 9, p. 897-903
  • DOI: 10.1038/nmat4014

Lewis Acid–Base Adduct Approach for High Efficiency Perovskite Solar Cells
journal, January 2016

A Fast Deposition-Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells
journal, July 2014

  • Xiao, Manda; Huang, Fuzhi; Huang, Wenchao
  • Angewandte Chemie International Edition, Vol. 53, Issue 37
  • DOI: 10.1002/anie.201405334

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

  • Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03874J

Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide
journal, July 2015

  • Ahn, Namyoung; Son, Dae-Yong; Jang, In-Hyuk
  • Journal of the American Chemical Society, Vol. 137, Issue 27
  • DOI: 10.1021/jacs.5b04930

Understanding the formation and evolution of interdiffusion grown organolead halide perovskite thin films by thermal annealing
journal, January 2014

  • Bi, Cheng; Shao, Yuchuan; Yuan, Yongbo
  • J. Mater. Chem. A, Vol. 2, Issue 43
  • DOI: 10.1039/C4TA04007D

Chemical Pathways Connecting Lead(II) Iodide and Perovskite via Polymeric Plumbate(II) Fiber
journal, December 2015

  • Guo, Yunlong; Shoyama, Kazutaka; Sato, Wataru
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10599

Evolution of Iodoplumbate Complexes in Methylammonium Lead Iodide Perovskite Precursor Solutions
journal, January 2017

Investigation of CH 3 NH 3 PbI 3 Degradation Rates and Mechanisms in Controlled Humidity Environments Using in Situ Techniques
journal, January 2015

  • Yang, Jinli; Siempelkamp, Braden D.; Liu, Dianyi
  • ACS Nano, Vol. 9, Issue 2
  • DOI: 10.1021/nn506864k

Uncovering the Veil of the Degradation in Perovskite CH 3 NH 3 PbI 3 upon Humidity Exposure: A First-Principles Study
journal, July 2015

  • Tong, Chuan-Jia; Geng, Wei; Tang, Zhen-Kun
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 16
  • DOI: 10.1021/acs.jpclett.5b01544

Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells
journal, February 2014

  • Dualeh, Amalie; Tétreault, Nicolas; Moehl, Thomas
  • Advanced Functional Materials, Vol. 24, Issue 21, p. 3250-3258
  • DOI: 10.1002/adfm.201304022

Multi-step slow annealing perovskite films for high performance planar perovskite solar cells
journal, October 2015

Rapid processing of perovskite solar cells in under 2.5 seconds
journal, January 2015

  • Troughton, Joel; Charbonneau, Cécile; Carnie, Matthew J.
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C5TA00568J

Intense Pulsed Light Sintering of CH 3 NH 3 PbI 3 Solar Cells
journal, March 2016

  • Lavery, Brandon W.; Kumari, Sudesh; Konermann, Hannah
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 13
  • DOI: 10.1021/acsami.5b10166

Thermal engineering of FAPbI3 perovskite material via radiative thermal annealing and in situ XRD
journal, January 2017

  • Pool, Vanessa L.; Dou, Benjia; Van Campen, Douglas G.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14075

Laser Crystallization of Organic–Inorganic Hybrid Perovskite Solar Cells
journal, July 2016

Influence of Thermal Processing Protocol upon the Crystallization and Photovoltaic Performance of Organic–Inorganic Lead Trihalide Perovskites
journal, April 2014

  • Saliba, Michael; Tan, Kwan Wee; Sai, Hiroaki
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp500717w

Crystallization Kinetics of Organic–Inorganic Trihalide Perovskites and the Role of the Lead Anion in Crystal Growth
journal, February 2015

  • Moore, David T.; Sai, Hiroaki; Tan, Kwan W.
  • Journal of the American Chemical Society, Vol. 137, Issue 6
  • DOI: 10.1021/ja512117e

Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells
journal, April 2014

  • Tan, Kwan Wee; Moore, David T.; Saliba, Michael
  • ACS Nano, Vol. 8, Issue 5
  • DOI: 10.1021/nn500526t

Chloride in Lead Chloride-Derived Organo-Metal Halides for Perovskite-Absorber Solar Cells
journal, December 2014

  • Unger, Eva L.; Bowring, Andrea R.; Tassone, Christopher J.
  • Chemistry of Materials, Vol. 26, Issue 24
  • DOI: 10.1021/cm503828b

Monitoring the Formation of a CH 3 NH 3 PbI 3- x Cl x Perovskite during Thermal Annealing Using X-Ray Scattering
journal, May 2016

  • Barrows, Alexander T.; Lilliu, Samuele; Pearson, Andrew J.
  • Advanced Functional Materials, Vol. 26, Issue 27
  • DOI: 10.1002/adfm.201601309

Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases
journal, November 2016

  • Munir, Rahim; Sheikh, Arif D.; Abdelsamie, Maged
  • Advanced Materials, Vol. 29, Issue 2
  • DOI: 10.1002/adma.201604113

Photonic flash-annealing of lead halide perovskite solar cells in 1 ms
journal, January 2016

  • Troughton, Joel; Carnie, Matthew J.; Davies, Matthew L.
  • Journal of Materials Chemistry A, Vol. 4, Issue 9
  • DOI: 10.1039/C5TA09431C

Rapid thermal processing chamber for in-situ x-ray diffraction
journal, January 2015

  • Ahmad, Md. Imteyaz; Van Campen, Douglas G.; Fields, Jeremy D.
  • Review of Scientific Instruments, Vol. 86, Issue 1
  • DOI: 10.1063/1.4904848

Vacuum-Assisted Thermal Annealing of CH 3 NH 3 PbI 3 for Highly Stable and Efficient Perovskite Solar Cells
journal, January 2015

  • Xie, Feng Xian; Zhang, Di; Su, Huimin
  • ACS Nano, Vol. 9, Issue 1
  • DOI: 10.1021/nn505978r

A Universal Deposition Protocol for Planar Heterojunction Solar Cells with High Efficiency Based on Hybrid Lead Halide Perovskite Families
journal, October 2016

  • Conings, Bert; Babayigit, Aslihan; Klug, Matthew T.
  • Advanced Materials, Vol. 28, Issue 48
  • DOI: 10.1002/adma.201603747

Metal-Oxide-Free Methylammonium Lead Iodide Perovskite-Based Solar Cells: the Influence of Organic Charge Transport Layers
journal, June 2014

  • Malinkiewicz, Olga; Roldán-Carmona, Cristina; Soriano, Alejandra
  • Advanced Energy Materials, Vol. 4, Issue 15
  • DOI: 10.1002/aenm.201400345

Best Practices in Perovskite Solar Cell Efficiency Measurements. Avoiding the Error of Making Bad Cells Look Good
journal, February 2015

  • Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
  • DOI: 10.1021/acs.jpclett.5b00289

Transformation of Sintered CsPbBr 3 Nanocrystals to Cubic CsPbI 3 and Gradient CsPbBr x I 3– x through Halide Exchange
journal, June 2016

  • Hoffman, Jacob B.; Schleper, A. Lennart; Kamat, Prashant V.
  • Journal of the American Chemical Society, Vol. 138, Issue 27
  • DOI: 10.1021/jacs.6b04661

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells
journal, January 2014

  • Unger, E. L.; Hoke, E. T.; Bailie, C. D.
  • Energy Environ. Sci., Vol. 7, Issue 11
  • DOI: 10.1039/C4EE02465F

Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
journal, January 2013

  • Baikie, Tom; Fang, Yanan; Kadro, Jeannette M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10518k

Identification and characterization of the intermediate phase in hybrid organic–inorganic MAPbI 3 perovskite
journal, January 2016

  • Guo, Xin; McCleese, Christopher; Kolodziej, Charles
  • Dalton Transactions, Vol. 45, Issue 9
  • DOI: 10.1039/C5DT04420K

Determination of Thermal Expansion Coefficients and Locating the Temperature-Induced Phase Transition in Methylammonium Lead Perovskites Using X-ray Diffraction
journal, October 2015

Monitoring a Silent Phase Transition in CH 3 NH 3 PbI 3 Solar Cells via Operando X-ray Diffraction
journal, October 2016

Anomalous Hysteresis in Perovskite Solar Cells
journal, April 2014

  • Snaith, Henry J.; Abate, Antonio; Ball, James M.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500113x

Parameters Affecting I – V Hysteresis of CH 3 NH 3 PbI 3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO 2 Layer
journal, August 2014

  • Kim, Hui-Seon; Park, Nam-Gyu
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 17
  • DOI: 10.1021/jz501392m

Molecular ferroelectric contributions to anomalous hysteresis in hybrid perovskite solar cells
journal, August 2014

  • Frost, Jarvist M.; Butler, Keith T.; Walsh, Aron
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4890246

Emergence of Hysteresis and Transient Ferroelectric Response in Organo-Lead Halide Perovskite Solar Cells
journal, December 2014

  • Chen, Hsin-Wei; Sakai, Nobuya; Ikegami, Masashi
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 1
  • DOI: 10.1021/jz502429u

The Interface between FTO and the TiO 2 Compact Layer Can Be One of the Origins to Hysteresis in Planar Heterojunction Perovskite Solar Cells
journal, May 2015

  • Jena, Ajay Kumar; Chen, Hsin-Wei; Kogo, Atsushi
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 18
  • DOI: 10.1021/acsami.5b01789

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
journal, March 2013

  • Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck
  • Nano Letters, Vol. 13, Issue 4, p. 1764-1769
  • DOI: 10.1021/nl400349b

Transformation of the Excited State and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite upon Controlled Exposure to Humidified Air
journal, January 2015

  • Christians, Jeffrey A.; Miranda Herrera, Pierre A.; Kamat, Prashant V.
  • Journal of the American Chemical Society, Vol. 137, Issue 4
  • DOI: 10.1021/ja511132a

Interface engineering of highly efficient perovskite solar cells
journal, July 2014

Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping
journal, May 2015

  • Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
  • DOI: 10.1021/acs.jpclett.5b00594

The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers
journal, May 2015

  • Aristidou, Nicholas; Sanchez-Molina, Irene; Chotchuangchutchaval, Thana
  • Angewandte Chemie International Edition, Vol. 54, Issue 28
  • DOI: 10.1002/anie.201503153

Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
journal, January 2016

  • Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C6EE00409A

Moisture assisted perovskite film growth for high performance solar cells
journal, November 2014

  • You, Jingbi; Yang, Yang (Michael); Hong, Ziruo
  • Applied Physics Letters, Vol. 105, Issue 18
  • DOI: 10.1063/1.4901510

Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells
journal, May 2017

  • Aristidou, Nicholas; Eames, Christopher; Sanchez-Molina, Irene
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15218

Reversible Hydration of CH 3 NH 3 PbI 3 in Films, Single Crystals, and Solar Cells
journal, April 2015

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    Works referencing / citing this record:

    Rapid thermal annealing of CH 3 NH 3 PbI 3 perovskite thin films by intense pulsed light with aid of diiodomethane additive
    journal, January 2018

    • Ankireddy, Krishnamraju; Ghahremani, Amir H.; Martin, Blake
    • Journal of Materials Chemistry A, Vol. 6, Issue 20
    • DOI: 10.1039/c8ta01237g

    Improvement of perovskite crystallinity by omnidirectional heat transfer via radiative thermal annealing
    journal, January 2019

    • Park, Jiyoon; Choi, Jin Woo; Kim, Woochul
    • RSC Advances, Vol. 9, Issue 26
    • DOI: 10.1039/c9ra01309a
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