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Title: Fast-responding bio-based shape memory thermoplastic polyurethanes

Fast response shape-memory polyurethanes were prepared from bio-based polyols, diphenyl methane diisocyanate and butane diol. The bio-based polyester polyols were synthesized from 9-hydroxynonanoic acid, a product obtained by ozonolysis of fatty acids extracted from soy oil and castor oil. The morphology of polyurethanes was investigated by synchrotron ultra-small angle X-ray scattering, which revealed the inter-domain spacing between the hard and soft phases, the degree of phase separation, and the level of intermixing between the hard and soft phases. We also conducted thorough investigations of the thermal, mechanical, and dielectric properties of the polyurethanes, and found that high crystallization rate of the soft segment gives these polyurethanes unique properties suitable for shapememory applications, such as adjustable transition temperatures, high degree of elastic elongations, and good mechanical strength. In conclusion, these materials are also potentially biodegradable and biocompatible, therefore suitable for biomedical and environmental applications.
Authors:
 [1] ;  [1] ;  [2] ;  [3]
  1. Pittsburg State Univ. Pittsburg, KS (United States)
  2. National Inst. of Standards and Technology, Gaithersburg, MD (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Polymer
Additional Journal Information:
Journal Volume: 121; Journal Issue: C; Journal ID: ISSN 0032-3861
Publisher:
Elsevier
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF), Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); Directorate for Mathematical and Physical Sciences Division of Chemistry (MPS/CHE); U.S. Department of Agriculture (USDA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; polyurethane; properties; shape-memory; synthesis
OSTI Identifier:
1389618