Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses

Wilding, Martin C.; Delaizir, Gaelle; Benmore, Chris J.; Gueguen, Yann; Dolhen, Morgane; Duclère, Jean-René; Chenu, Sébastien; Sukenaga, Sohei; McMillan, Paul F.

doi:10.1016/j.jnoncrysol.2016.07.004

Title: Structural studies of Bi ₂ O ₃ -Nb ₂ O ₅ -TeO ₂ glasses

Journal Article · 25 July 2016 · Journal of Non-Crystalline Solids

DOI: https://doi.org/10.1016/j.jnoncrysol.2016.07.004 · OSTI ID:1389309

Wilding, Martin C. ^[1]; Delaizir, Gaelle ^[2]; Benmore, Chris J. ^[3]; Gueguen, Yann ^[4]; Dolhen, Morgane ^[2]; Duclère, Jean-René ^[2]; Chenu, Sébastien ^[2]; Sukenaga, Sohei ^[5]; McMillan, Paul F. ^[6]

Univ. College London (United Kingdom). Dept. of Chemistry; Univ. of Bath (United Kingdom). Dept. of Physics
Univ. of Limoges (France)
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Univ. of Rennes (France)
Tohoku Univ., Sendai (Japan). Inst. of Multidisciplinary Research for Advanced Materials (IMRAM)
Univ. College London (United Kingdom). Dept. of Chemistry

Bi₂O₃-Nb₂O₅-TeO₂ glasses show unusual annealing behavior with appearance of spherulites within the matrix glass structure for the Bi_0.5Nb_0.5Te₃O₈ composition. The textures resemble those found previously among polyamorphic Al₂O₃-Y₂O₃ glasses containing metastably co-existing high- and low-density phases produced during quenching. However the spherulites produced within the Bi₂O₃-Nb₂O₅-TeO₂ glass are crystalline and can be identified as an “anti-glass” phase related to β-Bi₂Te₄O₁₁. Here, we used high energy synchrotron X-ray diffraction data to study structures of binary and ternary glasses quenched from liquids within the Bi₂O₃-Nb₂O₅-TeO₂ system. These reveal a glassy network based on interconnected TeO₄ and TeO₃ units that is related to TeO₂ crystalline materials but with larger Te…Te separations due to the presence of TeO₃ groups and non-bridging oxygens linked to modifier (Bi^{3 +}, Nb^{5 +}) cations. Analysis of the viscosity-temperature relations indicates that the glass-forming liquids are “fragile” and there is no evidence for a LLPT occurring in the supercooled liquid. The glasses obtained by quenching likely correspond to a high-density amorphous (HDA) state. Subsequent annealing above T_g shows mainly evidence for direct crystallization of the “anti-glass” tellurite phase. But, some evidence may exist for simultaneous formation of nanoscale amorphous spherulites that could correspond to the LDA polyamorph. The quenching and annealing behavior of Bi₂O₃-Nb₂O₅-TeO₂ supercooled liquids and glasses is compared with similar materials in the Al₂O₃-Y₂O₃ system.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1389309

Alternate ID(s):: OSTI ID: 1396667

Journal Information:: Journal of Non-Crystalline Solids, Vol. 451, Issue C; ISSN 0022-3093

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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36 MATERIALS SCIENCE
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Title: Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses

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Title: Structural studies of Bi ₂ O ₃ -Nb ₂ O ₅ -TeO ₂ glasses