Construction of hierarchically porous metal–organic frameworks through linker labilization
Abstract
One major goal of metal–organic framework (MOF) research is the expansion of pore size and volume. Although many approaches have been attempted to increase the pore size of MOF materials, it is still a challenge to construct MOFs with precisely customized pore apertures for specific applications. W present a new method, namely linker labilization, to increase the MOF porosity and pore size, giving rise to hierarchical-pore architectures. Microporous MOFs with robust metal nodes and pro-labile linkers were initially synthesized. The mesopores were subsequently created as crystal defects through the splitting of a pro-labile-linker and the removal of the linker fragments by acid treatment. We also demonstrate that linker labilization method can create controllable hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption process of guest molecules to improve the performances of MOFs in adsorption and catalysis.
- Authors:
-
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.
- Texas A & M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering
- King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.
- Texas A & M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering, Artie McFerrin Dept. of Chemical Engineering
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry, Dept. of Materials Science and Engineering; King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.
- Publication Date:
- Research Org.:
- Univ. of California, Berkeley, CA (United States); Texas A & M Univ., College Station, TX (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1389292
- Grant/Contract Number:
- SC0001015; FE0026472
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; metal-organic frameworks; solid-state chemistry
Citation Formats
Yuan, Shuai, Zou, Lanfang, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Wang, Xuan, Bosch, Mathieu, Alsalme, Ali, Cagin, Tahir, and Zhou, Hong-Cai. Construction of hierarchically porous metal–organic frameworks through linker labilization. United States: N. p., 2017.
Web. doi:10.1038/ncomms15356.
Yuan, Shuai, Zou, Lanfang, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Wang, Xuan, Bosch, Mathieu, Alsalme, Ali, Cagin, Tahir, & Zhou, Hong-Cai. Construction of hierarchically porous metal–organic frameworks through linker labilization. United States. https://doi.org/10.1038/ncomms15356
Yuan, Shuai, Zou, Lanfang, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Wang, Xuan, Bosch, Mathieu, Alsalme, Ali, Cagin, Tahir, and Zhou, Hong-Cai. Thu .
"Construction of hierarchically porous metal–organic frameworks through linker labilization". United States. https://doi.org/10.1038/ncomms15356. https://www.osti.gov/servlets/purl/1389292.
@article{osti_1389292,
title = {Construction of hierarchically porous metal–organic frameworks through linker labilization},
author = {Yuan, Shuai and Zou, Lanfang and Qin, Jun-Sheng and Li, Jialuo and Huang, Lan and Feng, Liang and Wang, Xuan and Bosch, Mathieu and Alsalme, Ali and Cagin, Tahir and Zhou, Hong-Cai},
abstractNote = {One major goal of metal–organic framework (MOF) research is the expansion of pore size and volume. Although many approaches have been attempted to increase the pore size of MOF materials, it is still a challenge to construct MOFs with precisely customized pore apertures for specific applications. W present a new method, namely linker labilization, to increase the MOF porosity and pore size, giving rise to hierarchical-pore architectures. Microporous MOFs with robust metal nodes and pro-labile linkers were initially synthesized. The mesopores were subsequently created as crystal defects through the splitting of a pro-labile-linker and the removal of the linker fragments by acid treatment. We also demonstrate that linker labilization method can create controllable hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption process of guest molecules to improve the performances of MOFs in adsorption and catalysis.},
doi = {10.1038/ncomms15356},
journal = {Nature Communications},
number = ,
volume = 8,
place = {United States},
year = {Thu May 25 00:00:00 EDT 2017},
month = {Thu May 25 00:00:00 EDT 2017}
}
Web of Science
Figures / Tables:
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An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks
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A Two-Dimensional Iron(II) Coordination Polymer with Synergetic Spin-Crossover and Luminescent Properties
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Generation of Hierarchical Porosity in Metal-Organic Frameworks by the Modulation of Cation Valence
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Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption
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Transition Metal–organic Coordination Polymers Containing 6‐(1H‐imidazol‐1‐yl)‐2(1H)‐Pyridinone: Synthesis, Structure and Fluorescent Sensing for Enoxacin
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Design and preparation of stable CPO/HRP@H-MOF(Zr) composites for efficient bio-catalytic degradation of organic toxicants in wastewater: Design and preparation of stable CPO/HRP@H-MOF(Zr)
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Hierarchical Micro‐ and Mesoporous Zn‐Based Metal–Organic Frameworks Templated by Hydrogels: Their Use for Enzyme Immobilization and Catalysis of Knoevenagel Reaction
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Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks
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Integration of mesopores and crystal defects in metal-organic frameworks via templated electrosynthesis
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Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategy
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Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements
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A gel-like/freeze-drying strategy to construct hierarchically porous polyoxometalate-based metal–organic framework catalysts
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Rapid room temperature conversion of hydroxy double salt to MOF-505 for CO 2 capture
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Chiral coordination polymers based on d 10 metals and 2-aminonicotinate with blue fluorescent/green phosphorescent anisotropic emissions
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Templated fabrication of hierarchically porous metal–organic frameworks and simulation of crystal growth
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Fine-tuning of nano-traps in a stable metal–organic framework for highly efficient removal of propyne from propylene
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Zinc/itaconate coordination polymers as first examples with long-lasting phosphorescence based on acyclic ligands
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Constructing new metal–organic frameworks with complicated ligands from “One-Pot” in situ reactions
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A multifunctional Zr( iv )-based metal–organic framework for highly efficient elimination of Cr( vi ) from the aqueous phase
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Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission
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Highly Mesoporous Metal‐Organic Frameworks as Synergistic Multimodal Catalytic Platforms for Divergent Cascade Reactions
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Tracking the Formation of a Series of Co n (n=2, 6, 8) Clusters from Linear Co 3 Precursor Clusters by Optimizing the Reaction Conditions
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Hierarchical Micro‐ and Mesoporous Zn‐Based Metal–Organic Frameworks Templated by Hydrogels: Their Use for Enzyme Immobilization and Catalysis of Knoevenagel Reaction
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Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations
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Uncovering Two Principles of Multivariate Hierarchical Metal–Organic Framework Synthesis via Retrosynthetic Design
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Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks
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Integration of mesopores and crystal defects in metal-organic frameworks via templated electrosynthesis
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Novel Hierarchical Fe(III)-Doped Cu-MOFs With Enhanced Adsorption of Benzene Vapor
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Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategy
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