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Title: High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks

Simulations demonstrate the critical roles of π-conjugation and large magnetic anisotropy in realizing high-temperature ferromagnetic 2D metal–organic framework, which is also half-metallic.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1] ; ORCiD logo [1]
  1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Publication Date:
Grant/Contract Number:
SC0001088
Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 4; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Research Org:
Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; solar (photovoltaic), solid state lighting, photosynthesis (natural and artificial), charge transport, optics, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)
OSTI Identifier:
1388515

Li, Wenbin, Sun, Lei, Qi, Jingshan, Jarillo-Herrero, Pablo, Dincă, Mircea, and Li, Ju. High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks. United States: N. p., Web. doi:10.1039/c6sc05080h.
Li, Wenbin, Sun, Lei, Qi, Jingshan, Jarillo-Herrero, Pablo, Dincă, Mircea, & Li, Ju. High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks. United States. doi:10.1039/c6sc05080h.
Li, Wenbin, Sun, Lei, Qi, Jingshan, Jarillo-Herrero, Pablo, Dincă, Mircea, and Li, Ju. 2017. "High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks". United States. doi:10.1039/c6sc05080h. https://www.osti.gov/servlets/purl/1388515.
@article{osti_1388515,
title = {High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks},
author = {Li, Wenbin and Sun, Lei and Qi, Jingshan and Jarillo-Herrero, Pablo and Dincă, Mircea and Li, Ju},
abstractNote = {Simulations demonstrate the critical roles of π-conjugation and large magnetic anisotropy in realizing high-temperature ferromagnetic 2D metal–organic framework, which is also half-metallic.},
doi = {10.1039/c6sc05080h},
journal = {Chemical Science},
number = 4,
volume = 8,
place = {United States},
year = {2017},
month = {2}
}

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