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Title: A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

A complete series of Ir(iv) diastereomers coordinated with chlorides and bidentate pyridine-alkoxide ligands was prepared, revealing a number of significant unusual properties.
Authors:
 [1] ;  [2] ;  [3] ;  [4] ;  [2] ;  [2] ;  [2]
  1. Yale Univ., New Haven, CT (United States)
  2. Yale Univ., New Haven, CT (United States); Yale Univ., West Haven, CT (United States). Energy Sciences Inst.
  3. Yale Univ., New Haven, CT (United States); Consejo Superior de Investigaciones Cientificas (CSIC), Sevilla (Spain)
  4. Yale Univ., New Haven, CT (United States); Louisiana State Univ., Baton Rouge, LA (United States)
Publication Date:
Grant/Contract Number:
SC0001059
Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 2; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Research Org:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER); Northwestern Univ., Evanston, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1388146