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Title: A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

A complete series of Ir(iv) diastereomers coordinated with chlorides and bidentate pyridine-alkoxide ligands was prepared, revealing a number of significant unusual properties.
Authors:
 [1] ;  [2] ;  [3] ;  [4] ;  [2] ;  [2] ;  [2]
  1. Yale Univ., New Haven, CT (United States)
  2. Yale Univ., New Haven, CT (United States); Yale Univ., West Haven, CT (United States). Energy Sciences Inst.
  3. Yale Univ., New Haven, CT (United States); Consejo Superior de Investigaciones Cientificas (CSIC), Sevilla (Spain)
  4. Yale Univ., New Haven, CT (United States); Louisiana State Univ., Baton Rouge, LA (United States)
Publication Date:
Grant/Contract Number:
SC0001059
Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 2; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Research Org:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER); Northwestern Univ., Evanston, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1388146

Shopov, Dimitar Y., Rudshteyn, Benjamin, Campos, Jesús, Vinyard, David J., Batista, Victor S., Brudvig, Gary W., and Crabtree, Robert H.. A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties. United States: N. p., Web. doi:10.1039/c6sc03758e.
Shopov, Dimitar Y., Rudshteyn, Benjamin, Campos, Jesús, Vinyard, David J., Batista, Victor S., Brudvig, Gary W., & Crabtree, Robert H.. A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties. United States. doi:10.1039/c6sc03758e.
Shopov, Dimitar Y., Rudshteyn, Benjamin, Campos, Jesús, Vinyard, David J., Batista, Victor S., Brudvig, Gary W., and Crabtree, Robert H.. 2017. "A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties". United States. doi:10.1039/c6sc03758e. https://www.osti.gov/servlets/purl/1388146.
@article{osti_1388146,
title = {A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties},
author = {Shopov, Dimitar Y. and Rudshteyn, Benjamin and Campos, Jesús and Vinyard, David J. and Batista, Victor S. and Brudvig, Gary W. and Crabtree, Robert H.},
abstractNote = {A complete series of Ir(iv) diastereomers coordinated with chlorides and bidentate pyridine-alkoxide ligands was prepared, revealing a number of significant unusual properties.},
doi = {10.1039/c6sc03758e},
journal = {Chemical Science},
number = 2,
volume = 8,
place = {United States},
year = {2017},
month = {11}
}

Works referenced in this record:

Correlations between the ligand electrochemical parameter, EL(L), and the Hammett substituent parameter, .sigma.
journal, May 1993
  • Masui, Hitoshi; Lever, A. B. P.
  • Inorganic Chemistry, Vol. 32, Issue 10, p. 2199-2201
  • DOI: 10.1021/ic00062a052