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Title: Continuous Flow Processing of ZIF-8 Membranes on Polymeric Porous Hollow Fiber Supports for CO2 Capture

Abstract

We have utilized an environmentally friendly synthesis approach for the accelerated growth of a selective inorganic membrane on a polymeric hollow fiber support for postcombustion carbon capture. Specifically, continuous defect-free ZIF-8 thin films were grown and anchored using continuous flow synthesis on the outer surface of porous supports using water as solvent. These membranes demonstrated CO2 permeance of 22 GPU and the highest reported CO2/N2 selectivity of 52 for a continuous flow synthesized ZIF-8 membrane.

Authors:
 [1];  [2];  [2];  [2];  [3];  [4]; ORCiD logo [3]
  1. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Oak Ridge Inst. for Science and Education (ORISE), Pittsburgh, PA (United States)
  2. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Oak Ridge Inst. for Science and Education (ORISE), Pittsburgh, PA (United States)
  3. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); AECOM Pittsburgh, PA (United States)
  4. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1388091
Grant/Contract Number:  
SC0001015
Resource Type:
Accepted Manuscript
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 9; Journal Issue: 7; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)

Citation Formats

Marti, Anne M., Wickramanayake, Wasala, Dahe, Ganpat, Sekizkardes, Ali, Bank, Tracy L., Hopkinson, David P., and Venna, Surendar R. Continuous Flow Processing of ZIF-8 Membranes on Polymeric Porous Hollow Fiber Supports for CO2 Capture. United States: N. p., 2017. Web. doi:10.1021/acsami.6b16297.
Marti, Anne M., Wickramanayake, Wasala, Dahe, Ganpat, Sekizkardes, Ali, Bank, Tracy L., Hopkinson, David P., & Venna, Surendar R. Continuous Flow Processing of ZIF-8 Membranes on Polymeric Porous Hollow Fiber Supports for CO2 Capture. United States. https://doi.org/10.1021/acsami.6b16297
Marti, Anne M., Wickramanayake, Wasala, Dahe, Ganpat, Sekizkardes, Ali, Bank, Tracy L., Hopkinson, David P., and Venna, Surendar R. Thu . "Continuous Flow Processing of ZIF-8 Membranes on Polymeric Porous Hollow Fiber Supports for CO2 Capture". United States. https://doi.org/10.1021/acsami.6b16297. https://www.osti.gov/servlets/purl/1388091.
@article{osti_1388091,
title = {Continuous Flow Processing of ZIF-8 Membranes on Polymeric Porous Hollow Fiber Supports for CO2 Capture},
author = {Marti, Anne M. and Wickramanayake, Wasala and Dahe, Ganpat and Sekizkardes, Ali and Bank, Tracy L. and Hopkinson, David P. and Venna, Surendar R.},
abstractNote = {We have utilized an environmentally friendly synthesis approach for the accelerated growth of a selective inorganic membrane on a polymeric hollow fiber support for postcombustion carbon capture. Specifically, continuous defect-free ZIF-8 thin films were grown and anchored using continuous flow synthesis on the outer surface of porous supports using water as solvent. These membranes demonstrated CO2 permeance of 22 GPU and the highest reported CO2/N2 selectivity of 52 for a continuous flow synthesized ZIF-8 membrane.},
doi = {10.1021/acsami.6b16297},
journal = {ACS Applied Materials and Interfaces},
number = 7,
volume = 9,
place = {United States},
year = {Thu Feb 09 00:00:00 EST 2017},
month = {Thu Feb 09 00:00:00 EST 2017}
}

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Works referenced in this record:

Global carbon dioxide levels near worrisome milestone
journal, April 2013


Addressing Climate Change with Clean Energy Technology
journal, May 2016


Status and progress of membrane contactors in post-combustion carbon capture: A state-of-the-art review of new developments
journal, August 2016


Power plant post-combustion carbon dioxide capture: An opportunity for membranes
journal, September 2010

  • Merkel, Tim C.; Lin, Haiqing; Wei, Xiaotong
  • Journal of Membrane Science, Vol. 359, Issue 1-2, p. 126-139
  • DOI: 10.1016/j.memsci.2009.10.041

The upper bound revisited
journal, July 2008


Multilayer polymer/zeolite Y composite membrane structure for CO2 capture from flue gas
journal, January 2016


Metal−organic framework composite membranes: Synthesis and separation applications
journal, October 2015


Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles
journal, January 2015

  • Venna, Surendar R.; Lartey, Michael; Li, Tao
  • Journal of Materials Chemistry A, Vol. 3, Issue 9
  • DOI: 10.1039/C4TA05225K

Enhanced permeation arising from dual transport pathways in hybrid polymer–MOF membranes
journal, January 2016

  • Su, Norman C.; Sun, Daniel T.; Beavers, Christine M.
  • Energy & Environmental Science, Vol. 9, Issue 3
  • DOI: 10.1039/C5EE02660A

In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes
journal, June 2015

  • Denny, Michael S.; Cohen, Seth M.
  • Angewandte Chemie International Edition, Vol. 54, Issue 31
  • DOI: 10.1002/anie.201504077

Metal–organic framework nanosheets in polymer composite materials for gas separation
journal, November 2014

  • Rodenas, Tania; Luz, Ignacio; Prieto, Gonzalo
  • Nature Materials, Vol. 14, Issue 1
  • DOI: 10.1038/nmat4113

Fabrication of hybrid polymer/metal organic framework membranes: mixed matrix membranes versus in situ growth
journal, January 2014

  • Campbell, James; Székely, György; Davies, R. P.
  • J. Mater. Chem. A, Vol. 2, Issue 24
  • DOI: 10.1039/C4TA00628C

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Stiff metal–organic framework–polyacrylonitrile hollow fiber composite membranes with high gas permeability
journal, January 2014

  • Li, Wanbin; Yang, Zhihong; Zhang, Guoliang
  • J. Mater. Chem. A, Vol. 2, Issue 7
  • DOI: 10.1039/C3TA13781C

Metal–organic framework membranes fabricated via reactive seeding
journal, January 2011

  • Hu, Yaoxin; Dong, Xueliang; Nan, Jiangpu
  • Chem. Commun., Vol. 47, Issue 2
  • DOI: 10.1039/C0CC03927F

An Unconventional Rapid Synthesis of High Performance Metal–Organic Framework Membranes
journal, June 2013

  • Shah, Miral N.; Gonzalez, Mariel A.; McCarthy, Michael C.
  • Langmuir, Vol. 29, Issue 25
  • DOI: 10.1021/la4014637

Continuous flow production of metal-organic frameworks
journal, May 2015

  • Batten, Michael P.; Rubio-Martinez, Marta; Hadley, Trevor
  • Current Opinion in Chemical Engineering, Vol. 8
  • DOI: 10.1016/j.coche.2015.02.001

Continuous synthesis of NaA zeolite membranes
journal, April 2009


In situ fabrication of high-permeance ZIF-8 tubular membranes in a continuous flow system
journal, November 2014


Interfacial microfluidic processing of metal-organic framework hollow fiber membranes
journal, July 2014


Fluidic Processing of High-Performance ZIF-8 Membranes on Polymeric Hollow Fibers: Mechanistic Insights and Microstructure Control
journal, June 2016

  • Eum, Kiwon; Rownaghi, Ali; Choi, Dalsu
  • Advanced Functional Materials, Vol. 26, Issue 28
  • DOI: 10.1002/adfm.201601550

Metal-organic framework membranes on the inner-side of a polymeric hollow fiber by microfluidic synthesis
journal, February 2015

  • Cacho-Bailo, Fernando; Catalán-Aguirre, Silvia; Etxeberría-Benavides, Miren
  • Journal of Membrane Science, Vol. 476
  • DOI: 10.1016/j.memsci.2014.11.016

High selectivity ZIF-93 hollow fiber membranes for gas separation
journal, January 2015

  • Cacho-Bailo, Fernando; Caro, Guillermo; Etxeberría-Benavides, Miren
  • Chemical Communications, Vol. 51, Issue 56
  • DOI: 10.1039/C5CC03937A

MOF–polymer enhanced compatibility: post-annealed zeolite imidazolate framework membranes inside polyimide hollow fibers
journal, January 2016

  • Cacho-Bailo, Fernando; Caro, Guillermo; Etxeberría-Benavides, Miren
  • RSC Advances, Vol. 6, Issue 7
  • DOI: 10.1039/C5RA26076K

A ZIF-71 Hollow Fiber Membrane Fabricated by Contra-Diffusion
journal, July 2015

  • Huang, Kang; Li, Qianqian; Liu, Gongping
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 30
  • DOI: 10.1021/acsami.5b04991

Formation of Ultrathin, Continuous Metal-Organic Framework Membranes on Flexible Polymer Substrates
journal, February 2016

  • Hou, Jingwei; Sutrisna, Putu D.; Zhang, Yatao
  • Angewandte Chemie International Edition, Vol. 55, Issue 12
  • DOI: 10.1002/anie.201511340

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Continuous Polycrystalline Zeolitic Imidazolate Framework-90 Membranes on Polymeric Hollow Fibers
journal, September 2012

  • Brown, Andrew J.; Johnson, J. R.; Lydon, Megan E.
  • Angewandte Chemie International Edition, Vol. 51, Issue 42
  • DOI: 10.1002/anie.201206640

Works referencing / citing this record:

Electroforming of a metal–organic framework on porous copper hollow fibers
journal, January 2019

  • Demirel, Özlem H.; Rijnaarts, Timon; de Wit, Patrick
  • Journal of Materials Chemistry A, Vol. 7, Issue 20
  • DOI: 10.1039/c8ta11296g

Zeolitic imidazolate framework membranes for gas and water purification
journal, October 2019

  • Mirqasemi, Marzieh S.; Homayoonfal, Maryam; Rezakazemi, Mashallah
  • Environmental Chemistry Letters, Vol. 18, Issue 1
  • DOI: 10.1007/s10311-019-00933-6

Hydrothermally Reduced Graphene Oxide Interfaces for Synthesizing High-Performance Metal-Organic Framework Hollow Fiber Membranes
journal, May 2018

  • Li, Wanbin; Shi, Jiali; Li, Zhanjun
  • Advanced Materials Interfaces, Vol. 5, Issue 14
  • DOI: 10.1002/admi.201800032

Emerging porous materials in confined spaces: from chromatographic applications to flow chemistry
journal, January 2019

  • Zhang, Jianyong; Chen, Junxing; Peng, Sheng
  • Chemical Society Reviews, Vol. 48, Issue 9
  • DOI: 10.1039/c8cs00657a

Cotton candy driven chitosan and gelatin coated poly(styrene-co-acrylonitrile) microfibers for anti-microbial wound dressing applications
journal, December 2019

  • Ashok, Mahalingam; Deepika, Shanmuga; Sowndharya, Pitchai
  • Materials Research Express, Vol. 6, Issue 12
  • DOI: 10.1088/2053-1591/ab5b2e

New strategies based on microfluidics for the synthesis of metal–organic frameworks and their membranes
journal, January 2018

  • Echaide-Górriz, Carlos; Clément, Coralie; Cacho-Bailo, Fernando
  • Journal of Materials Chemistry A, Vol. 6, Issue 14
  • DOI: 10.1039/c8ta01232f

Zeolitic Imidazolate Framework Membranes for Light Olefin/Paraffin Separation
journal, December 2018


Green Synthesis of Hierarchical Metal–Organic Framework/Wood Functional Composites with Superior Mechanical Properties
journal, February 2020

  • Tu, Kunkun; Puértolas, Begoña; Adobes‐Vidal, Maria
  • Advanced Science, Vol. 7, Issue 7
  • DOI: 10.1002/advs.201902897