Catalysis by framework zinc in silica-based molecular sieves

doi:10.1039/c5sc03889h

Title: Catalysis by framework zinc in silica-based molecular sieves

Abstract

Adjustable Zn Lewis acid site distributions in crystalline, microporous zincosilicates were studied spectroscopically and explored for catalytic applications.

Authors:

Orazov, Marat ^[1]; Davis, Mark E. ^[1]

Chemical Engineering; California Institute of Technology; Pasadena; USA

Publication Date:: 2016-01-01

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1387609

Grant/Contract Number:: SC0001004

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Science

Additional Journal Information:: Journal Volume: 7; Journal Issue: 3; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 2041-6520

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats


                    Orazov, Marat, and Davis, Mark E. Catalysis by framework zinc in silica-based molecular sieves.  United States: N. p., 2016. 
        Web.  doi:10.1039/c5sc03889h.

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                    Orazov, Marat, & Davis, Mark E. Catalysis by framework zinc in silica-based molecular sieves.  United States.  doi:10.1039/c5sc03889h.

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                    Orazov, Marat, and Davis, Mark E. Fri .  
        "Catalysis by framework zinc in silica-based molecular sieves".  United States.  doi:10.1039/c5sc03889h.  https://www.osti.gov/servlets/purl/1387609.

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@article{osti_1387609,

  title        = {Catalysis by framework zinc in silica-based molecular sieves},

  author       = {Orazov, Marat and Davis, Mark E.},

  abstractNote = {Adjustable Zn Lewis acid site distributions in crystalline, microporous zincosilicates were studied spectroscopically and explored for catalytic applications.},

  doi          = {10.1039/c5sc03889h},

  journal      = {Chemical Science},

  number       = 3,

  volume       = 7,

  place        = {United States},

  year         = {2016},

  month        = {1}

}

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DOI: 10.1039/c5sc03889h

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Cited by: 12 works

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Works referenced in this record:

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction)
journal, April 2002

Corma, Avelino; Domine, Marcelo E.; Nemeth, Laszlo
Journal of the American Chemical Society, Vol. 124, Issue 13, p. 3194-3195
DOI: 10.1021/ja012297m

Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose
journal, May 2014

Bermejo-Deval, Ricardo; Orazov, Marat; Gounder, Rajamani
ACS Catalysis, Vol. 4, Issue 7, p. 2288-2297
DOI: 10.1021/cs500466j

Tin-containing silicates: structure-activity relations
journal, February 2012

Osmundsen, C. M.; Holm, M. S.; Dahl, S.
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 468, Issue 2143, p. 2000-2016
DOI: 10.1098/rspa.2012.0047

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
journal, April 2010

Holm, Martin Spangsberg; Saravanamurugan, Shunmugavel; Taarning, Esben
Science, Vol. 328, Issue 5978, p. 602-605
DOI: 10.1126/science.1183990

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
DOI: 10.1073/pnas.1002358107

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Similar Records

Title: Catalysis by framework zinc in silica-based molecular sieves

Abstract

Citation Formats

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction) journal, April 2002

Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose journal, May 2014

Tin-containing silicates: structure-activity relations journal, February 2012

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts journal, April 2010

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water journal, March 2010

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction)
journal, April 2002

Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose
journal, May 2014

Tin-containing silicates: structure-activity relations
journal, February 2012

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
journal, April 2010

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010