Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes
Abstract
NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry ; King Abdulaziz Univ., Jeddah (Saudi Arabia)
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1387425
- Grant/Contract Number:
- SC0012702
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 11; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (heterogeneous); materials and chemistry by design; synthesis (novel materials)
Citation Formats
Madrahimov, Sherzod T., Gallagher, James R., Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J., Delferro, Massimiliano, Miller, Jeffrey T., Farha, Omar K., Hupp, Joseph T., and Nguyen, SonBinh T. Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. United States: N. p., 2015.
Web. doi:10.1021/acscatal.5b01604.
Madrahimov, Sherzod T., Gallagher, James R., Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J., Delferro, Massimiliano, Miller, Jeffrey T., Farha, Omar K., Hupp, Joseph T., & Nguyen, SonBinh T. Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. United States. https://doi.org/10.1021/acscatal.5b01604
Madrahimov, Sherzod T., Gallagher, James R., Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J., Delferro, Massimiliano, Miller, Jeffrey T., Farha, Omar K., Hupp, Joseph T., and Nguyen, SonBinh T. Mon .
"Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes". United States. https://doi.org/10.1021/acscatal.5b01604. https://www.osti.gov/servlets/purl/1387425.
@article{osti_1387425,
title = {Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes},
author = {Madrahimov, Sherzod T. and Gallagher, James R. and Zhang, Guanghui and Meinhart, Zachary and Garibay, Sergio J. and Delferro, Massimiliano and Miller, Jeffrey T. and Farha, Omar K. and Hupp, Joseph T. and Nguyen, SonBinh T.},
abstractNote = {NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.},
doi = {10.1021/acscatal.5b01604},
journal = {ACS Catalysis},
number = 11,
volume = 5,
place = {United States},
year = {Mon Oct 12 00:00:00 EDT 2015},
month = {Mon Oct 12 00:00:00 EDT 2015}
}
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