Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
Abstract
Applications of porous metal–organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical conductivity. Here, we describe the use of conductive two-dimensional (2D) MOFs as a new class of materials for chemiresistive sensing of volatile organic compounds (VOCs). We demonstrate that a family of structurally analogous 2D MOFs can be used to construct a cross-reactive sensor array that allows for clear discrimination between different categories of VOCs. Lastly, experimental data show that multiple sensing mechanisms are operative with high degrees of orthogonality, establishing that the 2D MOFs used here are mechanistically unique and offer advantages relative to other known chemiresistor materials.
- Authors:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1386738
- Grant/Contract Number:
- SC0001088
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 137; Journal Issue: 43; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; solar (photovoltaic); solid state lighting; photosynthesis (natural and artificial); charge transport; optics; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)
Citation Formats
Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., and Dinca, Mircea. Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks. United States: N. p., 2015.
Web. doi:10.1021/jacs.5b09600.
Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., & Dinca, Mircea. Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks. United States. doi:10.1021/jacs.5b09600.
Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., and Dinca, Mircea. Sun .
"Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks". United States. doi:10.1021/jacs.5b09600. https://www.osti.gov/servlets/purl/1386738.
@article{osti_1386738,
title = {Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks},
author = {Campbell, Michael G. and Liu, Sophie F. and Swager, Timothy M. and Dinca, Mircea},
abstractNote = {Applications of porous metal–organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical conductivity. Here, we describe the use of conductive two-dimensional (2D) MOFs as a new class of materials for chemiresistive sensing of volatile organic compounds (VOCs). We demonstrate that a family of structurally analogous 2D MOFs can be used to construct a cross-reactive sensor array that allows for clear discrimination between different categories of VOCs. Lastly, experimental data show that multiple sensing mechanisms are operative with high degrees of orthogonality, establishing that the 2D MOFs used here are mechanistically unique and offer advantages relative to other known chemiresistor materials.},
doi = {10.1021/jacs.5b09600},
journal = {Journal of the American Chemical Society},
number = 43,
volume = 137,
place = {United States},
year = {2015},
month = {10}
}
Web of Science
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A Calixarene-Based Metal-Organic Framework for Highly Selective NO 2 Detection
journal, August 2018
- Schulz, Marcel; Gehl, Adrian; Schlenkrich, Jakob
- Angewandte Chemie International Edition, Vol. 57, Issue 39
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journal, March 2018
- Bumstead, Alice M.; Cordes, David B.; Dawson, Daniel M.
- Chemistry - A European Journal, Vol. 24, Issue 23
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journal, June 2018
- Sun, Zhibing; Yu, Shihang; Zhao, Lili
- Chemistry - A European Journal, Vol. 24, Issue 42
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journal, April 2017
- Li, Gao-Peng; Zhang, Kun; Zhao, Hai-Yan
- ChemPlusChem, Vol. 82, Issue 5
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journal, August 2017
- Yan, Yong; Zhang, Ning-Ning; Li, Rong
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 32
A Novel Chemiresistive Trimethylamine Gas Sensor Based on Copper Coordination Polymer Microrods: A Novel Chemiresistive Trimethylamine Gas Sensor Based on Copper Coordination Polymer Microrods
journal, October 2018
- Yin, Yan-Yan; Li, Ting; Li, Ya-Ning
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 644, Issue 23
Chiral self-sorted multifunctional supramolecular biocoordination polymers and their applications in sensors
journal, September 2018
- Shang, Xiaobo; Song, Inho; Jung, Gwan Yeong
- Nature Communications, Vol. 9, Issue 1
Fingerprint Detection and Differentiation of Gas-phase Amines Using a Fluorescent Sensor Array Assembled from Asymmetric Perylene Diimides
journal, July 2018
- Hu, Yanyong; Zhou, Zichao; Zhao, Feiping
- Scientific Reports, Vol. 8, Issue 1
Lanthanide metal–organic frameworks assembled from a fluorene-based ligand: selective sensing of Pb 2+ and Fe 3+ ions
journal, January 2016
- Li, Liang; Chen, Qiang; Niu, Zhigang
- Journal of Materials Chemistry C, Vol. 4, Issue 9
A mixed-valent Cu I /Cu II metal–organic framework with selective chemical sensing properties
journal, January 2016
- Jiao, Chengli; Jiang, Xia; Chu, Hailiang
- CrystEngComm, Vol. 18, Issue 44
A viologen-based coordination polymer exhibiting high sensitivity towards various light sources
journal, January 2017
- Li, Wen-Bo; Yao, Qing-Xia; Sun, Li
- CrystEngComm, Vol. 19, Issue 4
Syntheses, structures and luminescence properties of five coordination polymers based on designed 2,7-bis(4-benzoic acid)-N-(4-benzoic acid) carbazole
journal, January 2017
- Chen, Dong-Hui; Lin, Ling; Sheng, Tian-Lu
- CrystEngComm, Vol. 19, Issue 19
The development of a promising photosensitive Schottky barrier diode using a novel Cd( ii ) based coordination polymer
journal, January 2017
- Ghorai, Pravat; Dey, Arka; Brandão, Paula
- Dalton Trans., Vol. 46, Issue 39
Syntheses, structures, luminescence and magnetic properties of seven isomorphous metal–organic frameworks based on 2,7-bis(4-benzoic acid)- N -(4-benzoic acid)carbazole
journal, January 2018
- Chen, Dong-Hui; Lin, Ling; Sheng, Tian-Lu
- New Journal of Chemistry, Vol. 42, Issue 4
Discrimination of saturated alkanes and relevant volatile compounds via the utilization of a conceptual fluorescent sensor array based on organoboron-containing polymers
journal, January 2018
- Qi, Yanyu; Xu, Wenjun; Kang, Rui
- Chemical Science, Vol. 9, Issue 7
Nanopore-induced host–guest charge transfer phenomena in a metal–organic framework
journal, January 2018
- Yamamoto, S.; Pirillo, J.; Hijikata, Y.
- Chemical Science, Vol. 9, Issue 13
Two novel multichromic coordination polymers based on a new flexible viologen ligand exhibiting photocontrolled luminescence properties and sensitive detection for ammonia
journal, January 2019
- Wang, Hai Yu; Liu, Shuang; Fu, Chen
- CrystEngComm, Vol. 21, Issue 10
STA-27, a porous Lewis acidic scandium MOF with an unexpected topology type prepared with 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine
journal, January 2019
- Prasad, Ram R. R.; Seidner, Sarah E.; Cordes, David B.
- Journal of Materials Chemistry A, Vol. 7, Issue 10
Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal–organic framework with a porphyrinic skeleton
journal, January 2019
- Niu, Ru-Jie; Zhou, Wen-Fa; Liu, Yan
- Chemical Communications, Vol. 55, Issue 33
Photo-exfoliation of a highly photo-responsive two-dimensional metal–organic framework
journal, January 2019
- Xie, Jian; Wang, Yaxing; Zhang, Duo
- Chemical Communications, Vol. 55, Issue 78
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journal, January 2019
- Meher, Niranjan; Iyer, Parameswar Krishnan
- Nanoscale, Vol. 11, Issue 28
A new paradigm of ultrathin 2D nanomaterial adsorbents in aqueous media: graphene and GO, MoS 2 , MXenes, and 2D MOFs
journal, January 2019
- Zhao, Pin; Jian, Meipeng; Zhang, Qi
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Competitive formation between 2D and 3D metal-organic frameworks: insights into the selective formation and lamination of a 2D MOF
journal, June 2019
- Oh, Sojin; Park, Jeehyun; Oh, Moonhyun
- IUCrJ, Vol. 6, Issue 4