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Title: Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks

Abstract

Applications of porous metal–organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical conductivity. Here, we describe the use of conductive two-dimensional (2D) MOFs as a new class of materials for chemiresistive sensing of volatile organic compounds (VOCs). We demonstrate that a family of structurally analogous 2D MOFs can be used to construct a cross-reactive sensor array that allows for clear discrimination between different categories of VOCs. Lastly, experimental data show that multiple sensing mechanisms are operative with high degrees of orthogonality, establishing that the 2D MOFs used here are mechanistically unique and offer advantages relative to other known chemiresistor materials.

Authors:
 [1];  [1];  [1];  [1]
  1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1386738
Grant/Contract Number:  
SC0001088
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 137; Journal Issue: 43; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; solar (photovoltaic); solid state lighting; photosynthesis (natural and artificial); charge transport; optics; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)

Citation Formats

Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., and Dinca, Mircea. Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks. United States: N. p., 2015. Web. doi:10.1021/jacs.5b09600.
Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., & Dinca, Mircea. Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks. United States. doi:https://doi.org/10.1021/jacs.5b09600
Campbell, Michael G., Liu, Sophie F., Swager, Timothy M., and Dinca, Mircea. Sun . "Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks". United States. doi:https://doi.org/10.1021/jacs.5b09600. https://www.osti.gov/servlets/purl/1386738.
@article{osti_1386738,
title = {Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks},
author = {Campbell, Michael G. and Liu, Sophie F. and Swager, Timothy M. and Dinca, Mircea},
abstractNote = {Applications of porous metal–organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical conductivity. Here, we describe the use of conductive two-dimensional (2D) MOFs as a new class of materials for chemiresistive sensing of volatile organic compounds (VOCs). We demonstrate that a family of structurally analogous 2D MOFs can be used to construct a cross-reactive sensor array that allows for clear discrimination between different categories of VOCs. Lastly, experimental data show that multiple sensing mechanisms are operative with high degrees of orthogonality, establishing that the 2D MOFs used here are mechanistically unique and offer advantages relative to other known chemiresistor materials.},
doi = {10.1021/jacs.5b09600},
journal = {Journal of the American Chemical Society},
number = 43,
volume = 137,
place = {United States},
year = {2015},
month = {10}
}

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  • Materials Chemistry Frontiers, Vol. 2, Issue 11
  • DOI: 10.1039/c8qm00368h

A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework
journal, January 2018

  • Goswami, Subhadip; Ray, Debmalya; Otake, Ken-ichi
  • Chemical Science, Vol. 9, Issue 19
  • DOI: 10.1039/c8sc00961a

Rational design W-doped Co-ZIF-9 based Co 3 S 4 composite photocatalyst for efficient visible-light-driven photocatalytic H 2 evolution
journal, January 2019

  • Wang, Haiyu; jin, Zhiliang
  • Sustainable Energy & Fuels, Vol. 3, Issue 1
  • DOI: 10.1039/c8se00445e

Recent progress in two-dimensional polymers for energy storage and conversion: design, synthesis, and applications
journal, January 2018

  • Xiao, Peitao; Xu, Yuxi
  • Journal of Materials Chemistry A, Vol. 6, Issue 44
  • DOI: 10.1039/c8ta02820f

Predicting performance limits of methane gas storage in zeolites with an artificial neural network
journal, January 2019

  • Lee, Sangwon; Kim, Baekjun; Kim, Jihan
  • Journal of Materials Chemistry A, Vol. 7, Issue 6
  • DOI: 10.1039/c8ta12208c

Simultaneous laser-induced synthesis and micro-patterning of a metal organic framework
journal, January 2019

  • Armon, Nina; Greenberg, Ehud; Edri, Eitan
  • Chemical Communications, Vol. 55, Issue 85
  • DOI: 10.1039/c9cc05990c

Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis
journal, January 2020

  • Zhao, Kuangmin; Zhu, Weiwei; Liu, Suqin
  • Nanoscale Advances, Vol. 2, Issue 2
  • DOI: 10.1039/c9na00719a

Sensing organic analytes by metal–organic frameworks: a new way of considering the topic
journal, January 2020

  • Hu, Mao-Lin; Razavi, Sayed Ali Akbar; Piroozzadeh, Maryam
  • Inorganic Chemistry Frontiers, Vol. 7, Issue 7
  • DOI: 10.1039/c9qi01617a

A new post-synthetic polymerization strategy makes metal–organic frameworks more stable
journal, January 2019

  • Yang, Shuliang; Peng, Li; Sun, Daniel T.
  • Chemical Science, Vol. 10, Issue 17
  • DOI: 10.1039/c9sc00135b

Two-dimensional magnetic metal–organic frameworks with the Shastry-Sutherland lattice
journal, January 2019

  • Zhang, Li-Chuan; Zhang, Lizhi; Qin, Guangzhao
  • Chemical Science, Vol. 10, Issue 44
  • DOI: 10.1039/c9sc03816g

2D molecular crystal lattices: advances in their synthesis, characterization, and application
journal, January 2019

  • Solomos, Marina A.; Claire, F. James; Kempa, Thomas J.
  • Journal of Materials Chemistry A, Vol. 7, Issue 41
  • DOI: 10.1039/c9ta06534b

2D coordination polymers: Design guidelines and materials perspective
journal, December 2019

  • Tran, Michael; Kline, Katelyn; Qin, Ying
  • Applied Physics Reviews, Vol. 6, Issue 4
  • DOI: 10.1063/1.5110895

Efficient fluorescence detection of aromatic toxicants and toxicant metabolites in human breast milk
journal, July 2017


Electronic and spin–orbit properties of the kagome MOF family M 3 (1,2,5,6,9, 10-triphenylenehexathiol) 2 (M  =  Ni, Pt, Cu and Au)
journal, January 2017

  • Silveira, Orlando J.; Chacham, Helio
  • Journal of Physics: Condensed Matter, Vol. 29, Issue 9
  • DOI: 10.1088/1361-648x/aa530e

Origin of metallicity in 2D multilayer nickel bis(dithiolene) sheets
journal, June 2018


Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst
journal, January 2019

  • Ayoub, Ghada; Arhangelskis, Mihails; Zhang, Xuan
  • Beilstein Journal of Nanotechnology, Vol. 10
  • DOI: 10.3762/bjnano.10.232