High Surface Area Antimony-Doped Tin Oxide Electrodes Templated by Graft Copolymerization. Applications in Electrochemical and Photoelectrochemical Catalysis
Abstract
Mesoporous ATO nanocrystalline electrodes of micrometer thicknesses have been prepared from ATO nanocrystals and the grafted copolymer templating agents poly vinyl chloride-g-poly(oxyethylene methacrylate). As-obtained electrodes have high interfacial surface areas, large pore volumes, and rapid intraoxide electron transfer. The resulting high surface area materials are useful substrates for electrochemically catalyzed water oxidation. With thin added shells of TiO2 deposited by atomic layer deposition (ALD) and a surface-bound Ru(II) polypyridyl chromophore, they become photoanodes for hydrogen generation in the presence of a reductive scavenger.
- Authors:
-
- Department of Chemistry and ‡Department of Physics and Astronomy, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, United States
- Publication Date:
- Research Org.:
- University of North Carolina, Chapel Hill, NC (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1224936
- Alternate Identifier(s):
- OSTI ID: 1386308
- Grant/Contract Number:
- SC0001011
- Resource Type:
- Published Article
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Name: ACS Applied Materials and Interfaces Journal Volume: 7 Journal Issue: 45; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; antimony doped tin oxide; graft copolymer template; water oxidation; atomic layer deposition; photoanode
Citation Formats
Luo, Hanlin, Fang, Zhen, Song, Na, Garvey, Timothy, Lopez, Rene, and Meyer, Thomas J. High Surface Area Antimony-Doped Tin Oxide Electrodes Templated by Graft Copolymerization. Applications in Electrochemical and Photoelectrochemical Catalysis. United States: N. p., 2015.
Web. doi:10.1021/acsami.5b06348.
Luo, Hanlin, Fang, Zhen, Song, Na, Garvey, Timothy, Lopez, Rene, & Meyer, Thomas J. High Surface Area Antimony-Doped Tin Oxide Electrodes Templated by Graft Copolymerization. Applications in Electrochemical and Photoelectrochemical Catalysis. United States. https://doi.org/10.1021/acsami.5b06348
Luo, Hanlin, Fang, Zhen, Song, Na, Garvey, Timothy, Lopez, Rene, and Meyer, Thomas J. Tue .
"High Surface Area Antimony-Doped Tin Oxide Electrodes Templated by Graft Copolymerization. Applications in Electrochemical and Photoelectrochemical Catalysis". United States. https://doi.org/10.1021/acsami.5b06348.
@article{osti_1224936,
title = {High Surface Area Antimony-Doped Tin Oxide Electrodes Templated by Graft Copolymerization. Applications in Electrochemical and Photoelectrochemical Catalysis},
author = {Luo, Hanlin and Fang, Zhen and Song, Na and Garvey, Timothy and Lopez, Rene and Meyer, Thomas J.},
abstractNote = {Mesoporous ATO nanocrystalline electrodes of micrometer thicknesses have been prepared from ATO nanocrystals and the grafted copolymer templating agents poly vinyl chloride-g-poly(oxyethylene methacrylate). As-obtained electrodes have high interfacial surface areas, large pore volumes, and rapid intraoxide electron transfer. The resulting high surface area materials are useful substrates for electrochemically catalyzed water oxidation. With thin added shells of TiO2 deposited by atomic layer deposition (ALD) and a surface-bound Ru(II) polypyridyl chromophore, they become photoanodes for hydrogen generation in the presence of a reductive scavenger.},
doi = {10.1021/acsami.5b06348},
journal = {ACS Applied Materials and Interfaces},
number = 45,
volume = 7,
place = {United States},
year = {Tue Nov 03 00:00:00 EST 2015},
month = {Tue Nov 03 00:00:00 EST 2015}
}
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https://doi.org/10.1021/acsami.5b06348
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Cited by: 20 works
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Figures / Tables:
Figure 1: (a) Illustrating morphology and size of 8% ATO nanoparticles. Upper: TEM of ATO nanoparticles at low and high magnification (inset) after dispersion in THF on a copper grid. Below: size distribution of the ATO nanoparticles in THF from a DLS measurement. (b): X-ray diffraction diagrams with varying antimonymore »
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