skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework

 [1];  [2];  [1];  [1];  [1]
  1. Materials Science and Engineering Program and Texas Materials Institute, The University of Texas at Austin, Austin TX 78712 USA
  2. Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge TN 37831 USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
SC0005397; AC0206CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Additional Journal Information:
Journal Name: Small Journal Volume: 13 Journal Issue: 34; Journal ID: ISSN 1613-6810
Wiley Blackwell (John Wiley & Sons)
Country of Publication:

Citation Formats

Kaveevivitchai, Watchareeya, Huq, Ashfia, Wang, Shaofei, Park, Min Je, and Manthiram, Arumugam. Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework. Germany: N. p., 2017. Web. doi:10.1002/smll.201701296.
Kaveevivitchai, Watchareeya, Huq, Ashfia, Wang, Shaofei, Park, Min Je, & Manthiram, Arumugam. Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework. Germany. doi:10.1002/smll.201701296.
Kaveevivitchai, Watchareeya, Huq, Ashfia, Wang, Shaofei, Park, Min Je, and Manthiram, Arumugam. Mon . "Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework". Germany. doi:10.1002/smll.201701296.
title = {Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework},
author = {Kaveevivitchai, Watchareeya and Huq, Ashfia and Wang, Shaofei and Park, Min Je and Manthiram, Arumugam},
abstractNote = {},
doi = {10.1002/smll.201701296},
journal = {Small},
number = 34,
volume = 13,
place = {Germany},
year = {2017},
month = {7}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/smll.201701296

Citation Metrics:
Cited by: 9 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

High-capacity zinc-ion storage in an open-tunnel oxide for aqueous and nonaqueous Zn-ion batteries
journal, January 2016

  • Kaveevivitchai, Watchareeya; Manthiram, Arumugam
  • Journal of Materials Chemistry A, Vol. 4, Issue 48
  • DOI: 10.1039/C6TA07747A

In Situ Mitigation of First-Cycle Anode Irreversibility in a New Spinel/FeSb Lithium-Ion Cell Enabled via a Microwave-Assisted Chemical Lithiation Process
journal, October 2014

  • Moorhead-Rosenberg, Zachary; Allcorn, Eric; Manthiram, Arumugam
  • Chemistry of Materials, Vol. 26, Issue 20
  • DOI: 10.1021/cm5024426

Retracted Article: Black mesoporous anatase TiO 2 nanoleaves: a high capacity and high rate anode for aqueous Al-ion batteries
journal, January 2014

  • He, Ying Juan; Peng, Jun Fang; Chu, Wei
  • Journal of Materials Chemistry A, Vol. 2, Issue 6
  • DOI: 10.1039/C3TA13906A

A Novel Aluminum-Ion Battery: Al/AlCl 3 -[EMIm]Cl/Ni 3 S 2 @Graphene
journal, April 2016

Copper hexacyanoferrate nanoparticles as cathode material for aqueous Al-ion batteries
journal, January 2015

  • Liu, S.; Pan, G. L.; Li, G. R.
  • Journal of Materials Chemistry A, Vol. 3, Issue 3
  • DOI: 10.1039/C4TA04644G

Mg Intercalation in Layered and Spinel Host Crystal Structures for Mg Batteries
journal, April 2015

Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations
journal, January 2015

  • Liu, Miao; Rong, Ziqin; Malik, Rahul
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE03389B

On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials
journal, February 2010

  • Levi, E.; Gofer, Y.; Aurbach, D.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm9016497

An ultrafast rechargeable aluminium-ion battery
journal, April 2015

  • Lin, Meng-Chang; Gong, Ming; Lu, Bingan
  • Nature, Vol. 520, Issue 7547
  • DOI: 10.1038/nature14340

Polyol Synthesis of Uniform Silver Nanowires:  A Plausible Growth Mechanism and the Supporting Evidence
journal, July 2003

  • Sun, Yugang; Mayers, Brian; Herricks, Thurston
  • Nano Letters, Vol. 3, Issue 7
  • DOI: 10.1021/nl034312m

Reversible Electrochemical Intercalation of Aluminum in Mo 6 S 8
journal, July 2015

High Capacity Rechargeable Magnesium-Ion Batteries Based on a Microporous Molybdenum–Vanadium Oxide Cathode
journal, June 2016

The Roles of V 2 O 5 and Stainless Steel in Rechargeable Al–Ion Batteries
journal, January 2013

  • Reed, Luke D.; Menke, Erik
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.114306jes

Amorphous Vanadium Oxide/Carbon Composite Positive Electrode for Rechargeable Aluminum Battery
journal, October 2015

  • Chiku, Masanobu; Takeda, Hiroki; Matsumura, Shota
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 44
  • DOI: 10.1021/acsami.5b06420

3D Graphitic Foams Derived from Chloroaluminate Anion Intercalation for Ultrafast Aluminum-Ion Battery
journal, August 2016

Chemical intercalation of magnesium into solid hosts
journal, January 1991

  • Bruce, Peter G.; Krok, Franciszek; Nowinski, Jan
  • Journal of Materials Chemistry, Vol. 1, Issue 4
  • DOI: 10.1039/jm9910100705

Toward Rapid, “Green”, Predictable Microwave-Assisted Synthesis
journal, August 2005

  • Roberts, Brett A.; Strauss, Christopher R.
  • Accounts of Chemical Research, Vol. 38, Issue 8
  • DOI: 10.1021/ar040278m

An Overview and Future Perspectives of Aluminum Batteries
journal, June 2016

  • Elia, Giuseppe Antonio; Marquardt, Krystan; Hoeppner, Katrin
  • Advanced Materials, Vol. 28, Issue 35
  • DOI: 10.1002/adma.201601357

Hexagonal NiS nanobelts as advanced cathode materials for rechargeable Al-ion batteries
journal, January 2016

  • Yu, Zhijing; Kang, Zepeng; Hu, Zongqian
  • Chemical Communications, Vol. 52, Issue 68
  • DOI: 10.1039/C6CC05974K

Aluminum storage behavior of anatase TiO2 nanotube arrays in aqueous solution for aluminum ion batteries
journal, January 2012

  • Liu, S.; Hu, J. J.; Yan, N. F.
  • Energy & Environmental Science, Vol. 5, Issue 12
  • DOI: 10.1039/c2ee22987k

Fluorinated Graphites as Energetic Cathodes for Nonaqueous Al Batteries
journal, January 2002

  • Levitin, Galit; Yarnitzky, Chaim; Licht, Stuart
  • Electrochemical and Solid-State Letters, Vol. 5, Issue 7
  • DOI: 10.1149/1.1481797

Anion-effects on electrochemical properties of ionic liquid electrolytes for rechargeable aluminum batteries
journal, January 2015

  • Wang, Huali; Gu, Sichen; Bai, Ying
  • Journal of Materials Chemistry A, Vol. 3, Issue 45
  • DOI: 10.1039/C5TA06187C

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

  • Gifford, P. R.; Palmisano, J. B.
  • Journal of The Electrochemical Society, Vol. 135, Issue 3, p. 650-654
  • DOI: 10.1149/1.2095685

An Ambient Temperature Secondary Aluminum Electrode: Its Cycling Rates and Its Cycling Efficiencies
journal, January 1985

  • Auborn, J. J.
  • Journal of The Electrochemical Society, Vol. 132, Issue 3
  • DOI: 10.1149/1.2113913

Advanced rechargeable aluminium ion battery with a high-quality natural graphite cathode
journal, February 2017

  • Wang, Di-Yan; Wei, Chuan-Yu; Lin, Meng-Chang
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14283

Cathode materials for magnesium and magnesium-ion based batteries
journal, March 2015

  • Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S.
  • Coordination Chemistry Reviews, Vol. 287
  • DOI: 10.1016/j.ccr.2014.11.005

Mg rechargeable batteries: an on-going challenge
journal, January 2013

  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

The Organic Phase for Aluminum Batteries
journal, January 1999

  • Licht, S.
  • Electrochemical and Solid-State Letters, Vol. 2, Issue 6
  • DOI: 10.1149/1.1390805

Sulfone-based electrolytes for aluminium rechargeable batteries
journal, January 2015

  • Nakayama, Yuri; Senda, Yui; Kawasaki, Hideki
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 8
  • DOI: 10.1039/C4CP02183E

The challenge of developing rechargeable magnesium batteries
journal, May 2014

  • Shterenberg, Ivgeni; Salama, Michael; Gofer, Yossi
  • MRS Bulletin, Vol. 39, Issue 5
  • DOI: 10.1557/mrs.2014.61

Ethylene glycol-mediated synthesis of metal oxide nanowires
journal, January 2004

  • Jiang, Xuchuan; Wang, Yuliang; Herricks, Thurston
  • Journal of Materials Chemistry, Vol. 14, Issue 4, p. 695-703
  • DOI: 10.1039/b313938g

Rechargeable lithium batteries and beyond: Progress, challenges, and future directions
journal, May 2014

  • Amine, Khalil; Kanno, Ryoji; Tzeng, Yonhua
  • MRS Bulletin, Vol. 39, Issue 5
  • DOI: 10.1557/mrs.2014.62

High-Performance Aluminum-Ion Battery with CuS@C Microsphere Composite Cathode
journal, December 2016

Microwave chemistry for inorganic nanomaterials synthesis
journal, January 2010

  • Bilecka, Idalia; Niederberger, Markus
  • Nanoscale, Vol. 2, Issue 8
  • DOI: 10.1039/b9nr00377k

The rechargeable aluminum-ion battery
journal, January 2011

  • Jayaprakash, N.; Das, S. K.; Archer, L. A.
  • Chemical Communications, Vol. 47, Issue 47
  • DOI: 10.1039/c1cc15779e

A new aluminium-ion battery with high voltage, high safety and low cost
journal, January 2015

  • Sun, Haobo; Wang, Wei; Yu, Zhijing
  • Chemical Communications, Vol. 51, Issue 59
  • DOI: 10.1039/C5CC00542F

A new cathode material for super-valent battery based on aluminium ion intercalation and deintercalation
journal, November 2013

  • Wang, Wei; Jiang, Bo; Xiong, Weiyi
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep03383

Chloroaluminate-Doped Conducting Polymers as Positive Electrodes in Rechargeable Aluminum Batteries
journal, March 2014

  • Hudak, Nicholas S.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 10
  • DOI: 10.1021/jp500593d

Graphene Nanoribbons on Highly Porous 3D Graphene for High-Capacity and Ultrastable Al-Ion Batteries
journal, November 2016

Characterization and Kinetic Studies on the Highly Active Ammoxidation Catalyst MoVNbTeOx
journal, September 2000

  • Asakura, Kiyotaka; Nakatani, Kaori; Kubota, Takeshi
  • Journal of Catalysis, Vol. 194, Issue 2
  • DOI: 10.1006/jcat.2000.2937

Intercalation of Polyvalent Cations into V2O5 Aerogels
journal, March 1998

  • Le, D. B.; Passerini, S.; Coustier, F.
  • Chemistry of Materials, Vol. 10, Issue 3, p. 682-684
  • DOI: 10.1021/cm9705101

A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries
journal, December 2007

Physics of electron and lithium-ion transport in electrode materials for Li-ion batteries
journal, January 2016

Ellipsometry and XPS comparative studies of thermal and plasma enhanced atomic layer deposited Al 2 O 3 -films
journal, January 2013

  • Haeberle, Jörg; Henkel, Karsten; Gargouri, Hassan
  • Beilstein Journal of Nanotechnology, Vol. 4
  • DOI: 10.3762/bjnano.4.83

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Amorphous V 2 O 5 –P 2 O 5 as high-voltage cathodes for magnesium batteries
journal, January 2015

  • Arthur, Timothy S.; Kato, Keiko; Germain, Jason
  • Chemical Communications, Vol. 51, Issue 86
  • DOI: 10.1039/C5CC07161E

High Coulombic efficiency aluminum-ion battery using an AlCl 3 -urea ionic liquid analog electrolyte
journal, January 2017

  • Angell, Michael; Pan, Chun-Jern; Rong, Youmin
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 5
  • DOI: 10.1073/pnas.1619795114

Preparation of Elemental Cu and Ni Nanoparticles by the Polyol Method: An Experimental and Theoretical Approach
journal, January 2011

  • Carroll, Kyler J.; Reveles, J. Ulises; Shultz, Michael D.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 6
  • DOI: 10.1021/jp1104196

Binder-Free V 2 O 5 Cathode for Greener Rechargeable Aluminum Battery
journal, December 2014

  • Wang, Huali; Bai, Ying; Chen, Shi
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 1
  • DOI: 10.1021/am508001h

High Capacity Microporous Molybdenum–Vanadium Oxide Electrodes for Rechargeable Lithium Batteries
journal, June 2013

  • Kaveevivitchai, Watchareeya; Jacobson, Allan J.
  • Chemistry of Materials, Vol. 25, Issue 13
  • DOI: 10.1021/cm401413u

Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries
journal, January 2016

  • Sun, Xiao-Guang; Fang, Youxing; Jiang, Xueguang
  • Chemical Communications, Vol. 52, Issue 2, p. 292-295
  • DOI: 10.1039/C5CC06643C

Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium?
journal, September 1999

Fluorinated Natural Graphite Cathode for Rechargeable Ionic Liquid Based Aluminum–Ion Battery
journal, January 2013

  • Rani, J. Vatsala; Kanakaiah, V.; Dadmal, Tulshiram
  • Journal of The Electrochemical Society, Vol. 160, Issue 10
  • DOI: 10.1149/2.072310jes

Todorokite-type MnO2 as a zinc-ion intercalating material
journal, December 2013

Critical Requirements for Rapid Charging of Rechargeable Al- and Li-Ion Batteries
journal, July 2015

  • Lee, Sanghan; Cho, Jaephil
  • Angewandte Chemie International Edition, Vol. 54, Issue 33
  • DOI: 10.1002/anie.201504466

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride
journal, July 1988

  • Lai, P. K.; Skyllas-Kazacos, M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 248, Issue 2, p. 431-440
  • DOI: 10.1016/0022-0728(88)85103-9

Acid−Base Characterization of Aluminum Oxide Surfaces with XPS
journal, May 2004

  • van den Brand, J.; Snijders, P. C.; Sloof, W. G.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 19
  • DOI: 10.1021/jp037877f

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte
journal, January 2015

  • Reed, L. D.; Ortiz, S. N.; Xiong, M.
  • Chemical Communications, Vol. 51, Issue 76
  • DOI: 10.1039/C5CC06053B

Shape-Controlled Synthesis of Gold and Silver Nanoparticles
journal, December 2002

Solvothermal synthesis of GO/V 2 O 5 composites as a cathode material for rechargeable magnesium batteries
journal, January 2015

  • Du, Xinchuan; Huang, Gang; Qin, Yuling
  • RSC Advances, Vol. 5, Issue 93
  • DOI: 10.1039/C5RA15284D

A Rapid Microwave-Assisted Solvothermal Approach to Lower-Valent Transition Metal Oxides
journal, November 2013

  • Moorhead-Rosenberg, Zachary; Harrison, Katharine L.; Turner, Travis
  • Inorganic Chemistry, Vol. 52, Issue 22
  • DOI: 10.1021/ic401943r

The Solvent Matters: Kinetic versus Thermodynamic Shape Control in the Polyol Synthesis of Rhodium Nanoparticles
journal, September 2011

  • Biacchi, Adam J.; Schaak, Raymond E.
  • ACS Nano, Vol. 5, Issue 10
  • DOI: 10.1021/nn2026758

Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond
journal, October 2014

  • Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500049y

Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016

Atomistic origin of superior performance of ionic liquid electrolytes for Al-ion batteries
journal, January 2014

  • Kamath, Ganesh; Narayanan, Badri; Sankaranarayanan, Subramanian K. R. S.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 38
  • DOI: 10.1039/C4CP02840F

Microwave-assisted chemical insertion: a rapid technique for screening cathodes for Mg-ion batteries
journal, January 2017

  • Kaveevivitchai, Watchareeya; Huq, Ashfia; Manthiram, Arumugam
  • Journal of Materials Chemistry A, Vol. 5, Issue 5
  • DOI: 10.1039/C6TA09497J

A long-life rechargeable Al ion battery based on molten salts
journal, January 2017

  • Song, Yang; Jiao, Shuqiang; Tu, Jiguo
  • Journal of Materials Chemistry A, Vol. 5, Issue 3
  • DOI: 10.1039/C6TA09829K

Multivalent Cationic Conduction in Crystalline Solids
journal, December 1998

  • Köhler, Joachim; Imanaka, Nobuhito; Adachi, Gin-ya
  • Chemistry of Materials, Vol. 10, Issue 12
  • DOI: 10.1021/cm980473t

Highly reduced VO x nanotube cathode materials with ultra-high capacity for magnesium ion batteries
journal, January 2014

  • Kim, Ryoung-Hee; Kim, Ju-Sik; Kim, Hyun-Jin
  • J. Mater. Chem. A, Vol. 2, Issue 48
  • DOI: 10.1039/C4TA05564K