A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries
Abstract
Abstract The development of all‐solid‐state rechargeable batteries is plagued by a large interfacial resistance between a solid cathode and a solid electrolyte that increases with each charge–discharge cycle. The introduction of a plastic–crystal electrolyte interphase between a solid electrolyte and solid cathode particles reduces the interfacial resistance, increases the cycle life, and allows a high rate performance. Comparison of solid‐state sodium cells with 1) solid electrolyte Na 3 Zr 2 (Si 2 PO 4 ) particles versus 2) plastic–crystal electrolyte in the cathode composites shows that the former suffers from a huge irreversible capacity loss on cycling whereas the latter exhibits a dramatically improved electrochemical performance with retention of capacity for over 100 cycles and cycling at 5 C rate. The application of a plastic–crystal electrolyte interphase between a solid electrolyte and a solid cathode may be extended to other all‐solid‐state battery cells.
- Authors:
-
- Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1379982
- Grant/Contract Number:
- SC0005397
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 129 Journal Issue: 20; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries. Germany: N. p., 2017.
Web. doi:10.1002/ange.201702003.
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, & Goodenough, John B. A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries. Germany. https://doi.org/10.1002/ange.201702003
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. Wed .
"A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries". Germany. https://doi.org/10.1002/ange.201702003.
@article{osti_1379982,
title = {A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries},
author = {Gao, Hongcai and Xue, Leigang and Xin, Sen and Park, Kyusung and Goodenough, John B.},
abstractNote = {Abstract The development of all‐solid‐state rechargeable batteries is plagued by a large interfacial resistance between a solid cathode and a solid electrolyte that increases with each charge–discharge cycle. The introduction of a plastic–crystal electrolyte interphase between a solid electrolyte and solid cathode particles reduces the interfacial resistance, increases the cycle life, and allows a high rate performance. Comparison of solid‐state sodium cells with 1) solid electrolyte Na 3 Zr 2 (Si 2 PO 4 ) particles versus 2) plastic–crystal electrolyte in the cathode composites shows that the former suffers from a huge irreversible capacity loss on cycling whereas the latter exhibits a dramatically improved electrochemical performance with retention of capacity for over 100 cycles and cycling at 5 C rate. The application of a plastic–crystal electrolyte interphase between a solid electrolyte and a solid cathode may be extended to other all‐solid‐state battery cells.},
doi = {10.1002/ange.201702003},
journal = {Angewandte Chemie},
number = 20,
volume = 129,
place = {Germany},
year = {Wed Apr 12 00:00:00 EDT 2017},
month = {Wed Apr 12 00:00:00 EDT 2017}
}
https://doi.org/10.1002/ange.201702003
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