A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries
Abstract
Abstract The development of all‐solid‐state rechargeable batteries is plagued by a large interfacial resistance between a solid cathode and a solid electrolyte that increases with each charge–discharge cycle. The introduction of a plastic–crystal electrolyte interphase between a solid electrolyte and solid cathode particles reduces the interfacial resistance, increases the cycle life, and allows a high rate performance. Comparison of solid‐state sodium cells with 1) solid electrolyte Na 3 Zr 2 (Si 2 PO 4 ) particles versus 2) plastic–crystal electrolyte in the cathode composites shows that the former suffers from a huge irreversible capacity loss on cycling whereas the latter exhibits a dramatically improved electrochemical performance with retention of capacity for over 100 cycles and cycling at 5 C rate. The application of a plastic–crystal electrolyte interphase between a solid electrolyte and a solid cathode may be extended to other all‐solid‐state battery cells.
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1379982
- Grant/Contract Number:
- SC0005397
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 129 Journal Issue: 20; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries. Germany: N. p., 2017.
Web. doi:10.1002/ange.201702003.
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, & Goodenough, John B. A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries. Germany. https://doi.org/10.1002/ange.201702003
Gao, Hongcai, Xue, Leigang, Xin, Sen, Park, Kyusung, and Goodenough, John B. Wed .
"A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries". Germany. https://doi.org/10.1002/ange.201702003.
@article{osti_1379982,
title = {A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries},
author = {Gao, Hongcai and Xue, Leigang and Xin, Sen and Park, Kyusung and Goodenough, John B.},
abstractNote = {Abstract The development of all‐solid‐state rechargeable batteries is plagued by a large interfacial resistance between a solid cathode and a solid electrolyte that increases with each charge–discharge cycle. The introduction of a plastic–crystal electrolyte interphase between a solid electrolyte and solid cathode particles reduces the interfacial resistance, increases the cycle life, and allows a high rate performance. Comparison of solid‐state sodium cells with 1) solid electrolyte Na 3 Zr 2 (Si 2 PO 4 ) particles versus 2) plastic–crystal electrolyte in the cathode composites shows that the former suffers from a huge irreversible capacity loss on cycling whereas the latter exhibits a dramatically improved electrochemical performance with retention of capacity for over 100 cycles and cycling at 5 C rate. The application of a plastic–crystal electrolyte interphase between a solid electrolyte and a solid cathode may be extended to other all‐solid‐state battery cells.},
doi = {10.1002/ange.201702003},
journal = {Angewandte Chemie},
number = 20,
volume = 129,
place = {Germany},
year = {Wed Apr 12 00:00:00 EDT 2017},
month = {Wed Apr 12 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201702003
https://doi.org/10.1002/ange.201702003
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Fast Na+-ion transport in skeleton structures
journal, February 1976
- Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A.
- Materials Research Bulletin, Vol. 11, Issue 2
Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016
- van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
- Advanced Energy Materials, Vol. 6, Issue 19
The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors
journal, June 2004
- Alarco, Pierre-Jean; Abu-Lebdeh, Yaser; Abouimrane, Ali
- Nature Materials, Vol. 3, Issue 7
Conductive Organic Plastic Crystals Based on Pyrazolium Imides
journal, September 2003
- Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel
- Angewandte Chemie International Edition, Vol. 42, Issue 37
Investigation on diffusion behavior of Li+ in LiFePO4 by capacity intermittent titration technique (CITT)
journal, March 2009
- Tang, Xin-Cun; Li, Lian-Xing; Lai, Qiong-Lin
- Electrochimica Acta, Vol. 54, Issue 8
Enhanced electrochemical properties of PEO-based composite polymer electrolyte with shape-selective molecular sieves
journal, June 2006
- Xi, Jingyu; Qiu, Xinping; Cui, Mengzhong
- Journal of Power Sources, Vol. 156, Issue 2
Spark Plasma Sintering (SPS) of NASICON Ceramics
journal, February 2004
- Lee, Ji-Sun; Chang, Chae-Myung; Lee, Young IL
- Journal of the American Ceramic Society, Vol. 87, Issue 2
Static and dynamic wetting behaviour of ionic liquids
journal, August 2015
- Delcheva, Iliana; Ralston, John; Beattie, David A.
- Advances in Colloid and Interface Science, Vol. 222
Application of quasi-solid-state silica nanoparticles–ionic liquid composite electrolytes to all-solid-state lithium secondary battery
journal, June 2012
- Ito, Seitaro; Unemoto, Atsushi; Ogawa, Hideyuki
- Journal of Power Sources, Vol. 208
Development of Sulfide Solid Electrolytes and Interface Formation Processes for Bulk-Type All-Solid-State Li and Na Batteries
journal, July 2016
- Hayashi, Akitoshi; Sakuda, Atsushi; Tatsumisago, Masahiro
- Frontiers in Energy Research, Vol. 4
Sodium and sodium-ion energy storage batteries
journal, August 2012
- Ellis, Brian L.; Nazar, Linda F.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
Dielectric Modification of 5V-Class Cathodes for High-Voltage All-Solid-State Lithium Batteries
journal, March 2014
- Yada, Chihiro; Ohmori, Akihiro; Ide, Kazuto
- Advanced Energy Materials, Vol. 4, Issue 9
Ionic conductivity in crystalline polymer electrolytes
journal, August 2001
- Gadjourova, Zlatka; Andreev, Yuri G.; Tunstall, David P.
- Nature, Vol. 412, Issue 6846
Evaluation of the wetting time of porous electrodes in electrolytic solutions containing ionic liquid
journal, May 2013
- Kühnel, Ruben-Simon; Obeidi, Shahmahmood; Lübke, Mechthild
- Journal of Applied Electrochemistry, Vol. 43, Issue 7
Electrochemical energy storage in a sustainable modern society
journal, January 2014
- Goodenough, John B.
- Energy Environ. Sci., Vol. 7, Issue 1
Relaxation dynamics and ionic conductivity in a fragile plastic crystal
journal, October 2010
- Bauer, Th.; Köhler, M.; Lunkenheimer, P.
- The Journal of Chemical Physics, Vol. 133, Issue 14
Phase Transitions in Plastic Crystals
journal, October 1962
- Staveley, L. A. K.
- Annual Review of Physical Chemistry, Vol. 13, Issue 1
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012
- Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi
- Nature Communications, Vol. 3, Issue 1
Review—Solid Electrolytes in Rechargeable Electrochemical Cells
journal, January 2015
- Goodenough, John B.; Singh, Preetam
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Inorganic solid/organic liquid hybrid electrolyte for use in Li-ion battery
journal, September 2012
- Asl, Nina Mahootcheian; Keith, Joshua; Lim, Cheolwoong
- Electrochimica Acta, Vol. 79
Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO 2 and Garnet-Li 7 La 3 Zr 2 O 12
journal, October 2016
- Park, Kyusung; Yu, Byeong-Chul; Jung, Ji-Won
- Chemistry of Materials, Vol. 28, Issue 21
An All-solid-state and All-organic Sodium-ion Battery based on Redox-active Polymers and Plastic Crystal Electrolyte
journal, October 2015
- Zhu, Xiaoming; Zhao, Ruirui; Deng, Wenwen
- Electrochimica Acta, Vol. 178
Characterization of NaX (X: TFSI, FSI) – PEO based solid polymer electrolytes for sodium batteries
journal, September 2015
- Boschin, Andrea; Johansson, Patrik
- Electrochimica Acta, Vol. 175
Reduction of charge-transfer resistance at the solid electrolyte – electrode interface by pulsed laser deposition of films from a crystalline Li2PO2N source
journal, April 2016
- West, William C.; Hood, Zachary D.; Adhikari, Shiba P.
- Journal of Power Sources, Vol. 312
Novel technique to form electrode–electrolyte nanointerface in all-solid-state rechargeable lithium batteries
journal, December 2008
- Hayashi, Akitoshi; Nishio, Yusuke; Kitaura, Hirokazu
- Electrochemistry Communications, Vol. 10, Issue 12
A ceramic/polymer composite solid electrolyte for sodium batteries
journal, January 2016
- Zhang, Zhizhen; Zhang, Qiangqiang; Ren, Cheng
- Journal of Materials Chemistry A, Vol. 4, Issue 41
Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries
journal, January 2015
- Guin, M.; Tietz, F.
- Journal of Power Sources, Vol. 273
In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries
journal, May 2015
- Zhou, Dong; He, Yan-Bing; Liu, Ruliang
- Advanced Energy Materials, Vol. 5, Issue 15
Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy †
journal, February 2010
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Chemistry of Materials, Vol. 22, Issue 3
The use of protic ionic liquids with cathodes for sodium-ion batteries
journal, January 2016
- Vogl, T.; Vaalma, C.; Buchholz, D.
- Journal of Materials Chemistry A, Vol. 4, Issue 27
Charge transfer kinetics at the solid–solid interface in porous electrodes
journal, April 2014
- Bai, Peng; Bazant, Martin Z.
- Nature Communications, Vol. 5, Issue 1
A Battery Made from a Single Material
journal, April 2015
- Han, Fudong; Gao, Tao; Zhu, Yujie
- Advanced Materials, Vol. 27, Issue 23
A hybrid solid electrolyte for flexible solid-state sodium batteries
journal, January 2015
- Kim, Jae-Kwang; Lim, Young Jun; Kim, Hyojin
- Energy & Environmental Science, Vol. 8, Issue 12
Point contacts in solid state ionics: finite element calculations and local conductivity measurements
journal, July 1996
- Fleig, J.
- Solid State Ionics, Vol. 86-88
A Sodium-Ion Battery with a Low-Cost Cross-Linked Gel-Polymer Electrolyte
journal, June 2016
- Gao, Hongcai; Zhou, Weidong; Park, Kyusung
- Advanced Energy Materials, Vol. 6, Issue 18
Routes to High Energy Cathodes of Sodium-Ion Batteries
journal, December 2015
- Fang, Chun; Huang, Yunhui; Zhang, Wuxing
- Advanced Energy Materials, Vol. 6, Issue 5
Impedance Characterization of Li Ion Transport at the Interface between Laminated Ceramic and Polymeric Electrolytes
journal, January 2012
- Tenhaeff, W. E.; Perry, K. A.; Dudney, N. J.
- Journal of The Electrochemical Society, Vol. 159, Issue 12
Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016
- Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan
- Nature Energy, Vol. 1, Issue 9
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance
journal, January 2010
- Smart, M. C.; Ratnakumar, B. V.; Chin, K. B.
- Journal of The Electrochemical Society, Vol. 157, Issue 12
Electrochemical Polarization
journal, January 1957
- Stern, M.; Geaby, A. L.
- Journal of The Electrochemical Society, Vol. 104, Issue 1
Solid state thin-film lithium battery systems
journal, October 1999
- Dudney, N. J.; Neudecker, B. J.
- Current Opinion in Solid State and Materials Science, Vol. 4, Issue 5
Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries
journal, December 1999
- MacFarlane, Douglas R.; Huang, Junhua; Forsyth, Maria
- Nature, Vol. 402, Issue 6763
Conductive Organic Plastic Crystals Based on Pyrazolium Imides
journal, September 2003
- Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel
- Angewandte Chemie, Vol. 115, Issue 37
Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte
journal, March 2012
- Ohta, Shingo; Kobayashi, Tetsuro; Seki, Juntaro
- Journal of Power Sources, Vol. 202
Modification of Interface Between LiCoO[sub 2] Electrode and Li[sub 2]S–P[sub 2]S[sub 5] Solid Electrolyte Using Li[sub 2]O–SiO[sub 2] Glassy Layers
journal, January 2009
- Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
- Journal of The Electrochemical Society, Vol. 156, Issue 1
Importance of Coulombic Efficiency Measurements in R&D Efforts to Obtain Long-Lived Li-Ion Batteries
journal, January 2016
- Dahn, J. R.; Burns, J. C.; Stevens, D. A.
- Interface magazine, Vol. 25, Issue 3
Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery
journal, January 2011
- Kim, Ki Hyun; Iriyama, Yasutoshi; Yamamoto, Kazuo
- Journal of Power Sources, Vol. 196, Issue 2
Preparation and performance of a non-ionic plastic crystal electrolyte with the addition of polymer for lithium ion batteries
journal, December 2013
- Wang, Qiujun; Fan, Huanhuan; Fan, Li-Zhen
- Electrochimica Acta, Vol. 114
In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries
journal, May 2016
- Wang, Ziying; Santhanagopalan, Dhamodaran; Zhang, Wei
- Nano Letters, Vol. 16, Issue 6
Hierarchical Carbon Framework Wrapped Na 3 V 2 (PO 4 ) 3 as a Superior High-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries
journal, August 2015
- Fang, Yongjin; Xiao, Lifen; Ai, Xinping
- Advanced Materials, Vol. 27, Issue 39
Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems
journal, January 2016
- Wu, Bingbin; Wang, Shanyu; Evans IV, Willie J.
- Journal of Materials Chemistry A, Vol. 4, Issue 40
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
journal, December 2015
- Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis
- Chemical Reviews, Vol. 116, Issue 1
Preparation and Electrical Properties of Dense Ceramics with NASICON Composition Sintered at Reduced Temperatures
journal, July 2004
- Sch�f, O.; Weibel, A.; Llewellyn, P. L.
- Journal of Electroceramics, Vol. 13, Issue 1-3