Yolk-shell structured Sb@C anodes for high energy Na-ion batteries
Abstract
Despite great advances in sodium-ion battery developments, the search for high energy and stable anode materials remains a challenge. Alloy or conversion-typed anode materials are attractive candidates of high specific capacity and low voltage potential, yet their applications are hampered by the large volume expansion and hence poor electrochemical reversibility and fast capacity fade. Here in this paper, we use antimony (Sb) as an example to demonstrate the use of yolk-shell structured anodes for high energy Na-ion batteries. The Sb@C yolk-shell structure prepared by controlled reduction and selective removal of Sb2O3 from carbon coated Sb2O3 nanoparticles can accommodate the Sb swelling upon sodiation and improve the structural/electrical integrity against pulverization. It delivers a high specific capacity of ~ 554 mAh g-1, good rate capability (315 mhA g-1 at 10 C rate) and long cyclability (92% capacity retention over 200 cycles). Full-cells of O3-Na0.9[Cu0.22Fe0.30Mn0.48]O2 cathodes and Sb@C-hard carbon composite anodes demonstrate a high specific energy of ~ 130 Wh kg-1 (based on the total mass of cathode and anode) in the voltage range of 2.0–4.0 V, ~ 1.5 times energy of full-cells with similar design using hard carbon anodes.
- Authors:
-
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences (CAS), Beijing (China)
- Washington State Univ., Pullman, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Electricity (OE); USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1379956
- Alternate Identifier(s):
- OSTI ID: 1549973
- Report Number(s):
- PNNL-SA-127468
Journal ID: ISSN 2211-2855; PII: S2211285517305293; TRN: US1801210
- Grant/Contract Number:
- AC05-76RL01830; 57558; 2016YFB0901504
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Energy
- Additional Journal Information:
- Journal Volume: 40; Journal Issue: C; Journal ID: ISSN 2211-2855
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Song, Junhua, Yan, Pengfei, Luo, Langli, Qi, Xingguo, Rong, Xiaohui, Zheng, Jianming, Xiao, Biwei, Feng, Shuo, Wang, Chongmin, Hu, Yong-Sheng, Lin, Yuehe, Sprenkle, Vincent L., and Li, Xiaolin. Yolk-shell structured Sb@C anodes for high energy Na-ion batteries. United States: N. p., 2017.
Web. doi:10.1016/j.nanoen.2017.08.051.
Song, Junhua, Yan, Pengfei, Luo, Langli, Qi, Xingguo, Rong, Xiaohui, Zheng, Jianming, Xiao, Biwei, Feng, Shuo, Wang, Chongmin, Hu, Yong-Sheng, Lin, Yuehe, Sprenkle, Vincent L., & Li, Xiaolin. Yolk-shell structured Sb@C anodes for high energy Na-ion batteries. United States. https://doi.org/10.1016/j.nanoen.2017.08.051
Song, Junhua, Yan, Pengfei, Luo, Langli, Qi, Xingguo, Rong, Xiaohui, Zheng, Jianming, Xiao, Biwei, Feng, Shuo, Wang, Chongmin, Hu, Yong-Sheng, Lin, Yuehe, Sprenkle, Vincent L., and Li, Xiaolin. Mon .
"Yolk-shell structured Sb@C anodes for high energy Na-ion batteries". United States. https://doi.org/10.1016/j.nanoen.2017.08.051. https://www.osti.gov/servlets/purl/1379956.
@article{osti_1379956,
title = {Yolk-shell structured Sb@C anodes for high energy Na-ion batteries},
author = {Song, Junhua and Yan, Pengfei and Luo, Langli and Qi, Xingguo and Rong, Xiaohui and Zheng, Jianming and Xiao, Biwei and Feng, Shuo and Wang, Chongmin and Hu, Yong-Sheng and Lin, Yuehe and Sprenkle, Vincent L. and Li, Xiaolin},
abstractNote = {Despite great advances in sodium-ion battery developments, the search for high energy and stable anode materials remains a challenge. Alloy or conversion-typed anode materials are attractive candidates of high specific capacity and low voltage potential, yet their applications are hampered by the large volume expansion and hence poor electrochemical reversibility and fast capacity fade. Here in this paper, we use antimony (Sb) as an example to demonstrate the use of yolk-shell structured anodes for high energy Na-ion batteries. The Sb@C yolk-shell structure prepared by controlled reduction and selective removal of Sb2O3 from carbon coated Sb2O3 nanoparticles can accommodate the Sb swelling upon sodiation and improve the structural/electrical integrity against pulverization. It delivers a high specific capacity of ~ 554 mAh g-1, good rate capability (315 mhA g-1 at 10 C rate) and long cyclability (92% capacity retention over 200 cycles). Full-cells of O3-Na0.9[Cu0.22Fe0.30Mn0.48]O2 cathodes and Sb@C-hard carbon composite anodes demonstrate a high specific energy of ~ 130 Wh kg-1 (based on the total mass of cathode and anode) in the voltage range of 2.0–4.0 V, ~ 1.5 times energy of full-cells with similar design using hard carbon anodes.},
doi = {10.1016/j.nanoen.2017.08.051},
journal = {Nano Energy},
number = C,
volume = 40,
place = {United States},
year = {2017},
month = {9}
}
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