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Title: Solution-Processed Cu 2Se Nanocrystal Films with Bulk-Like Thermoelectric Performance

Thermoelectric power generation can play a key role in a sustainable energy future by converting waste heat from power plants and other industrial processes into usable electrical power. Current thermoelectric devices, however, require energy intensive manufacturing processes such as alloying and spark plasma sintering. Here, we describe the fabrication of a p-type thermoelectric material, copper selenide (Cu 2 Se), utilizing solution-processing and thermal annealing to produce a thin film that achieves a figure of merit, ZT, which is as high as its traditionally processed counterpart, a value of 0.14 at room temperature. This is the first report of a fully solution-processed nanomaterial achieving performance equivalent to its bulk form and represents a general strategy to reduce the energy required to manufacture advanced energy conversion and harvesting materials.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ;  [4] ;  [5] ;  [6] ;  [1] ;  [7] ;  [1] ;  [5] ;  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
  2. Nanosys, Inc., Milpitas, CA (United States)
  3. California State Univ. Maritime Academy, Vallejo, CA (United States)
  4. North Carolina State Univ., Raleigh, NC (United States). Dept. of Mechanical and Aerospace Engineering
  5. Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering
  7. UBS AG, Zurich (Switzerland)
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; synthesis and processing; thermoelectric devices and materials
OSTI Identifier:
1379936

Forster, Jason D., Lynch, Jared J., Coates, Nelson E., Liu, Jun, Jang, Hyejin, Zaia, Edmond, Gordon, Madeleine P., Szybowski, Maxime, Sahu, Ayaskanta, Cahill, David G., and Urban, Jeffrey J.. Solution-Processed Cu2Se Nanocrystal Films with Bulk-Like Thermoelectric Performance. United States: N. p., Web. doi:10.1038/s41598-017-02944-1.
Forster, Jason D., Lynch, Jared J., Coates, Nelson E., Liu, Jun, Jang, Hyejin, Zaia, Edmond, Gordon, Madeleine P., Szybowski, Maxime, Sahu, Ayaskanta, Cahill, David G., & Urban, Jeffrey J.. Solution-Processed Cu2Se Nanocrystal Films with Bulk-Like Thermoelectric Performance. United States. doi:10.1038/s41598-017-02944-1.
Forster, Jason D., Lynch, Jared J., Coates, Nelson E., Liu, Jun, Jang, Hyejin, Zaia, Edmond, Gordon, Madeleine P., Szybowski, Maxime, Sahu, Ayaskanta, Cahill, David G., and Urban, Jeffrey J.. 2017. "Solution-Processed Cu2Se Nanocrystal Films with Bulk-Like Thermoelectric Performance". United States. doi:10.1038/s41598-017-02944-1. https://www.osti.gov/servlets/purl/1379936.
@article{osti_1379936,
title = {Solution-Processed Cu2Se Nanocrystal Films with Bulk-Like Thermoelectric Performance},
author = {Forster, Jason D. and Lynch, Jared J. and Coates, Nelson E. and Liu, Jun and Jang, Hyejin and Zaia, Edmond and Gordon, Madeleine P. and Szybowski, Maxime and Sahu, Ayaskanta and Cahill, David G. and Urban, Jeffrey J.},
abstractNote = {Thermoelectric power generation can play a key role in a sustainable energy future by converting waste heat from power plants and other industrial processes into usable electrical power. Current thermoelectric devices, however, require energy intensive manufacturing processes such as alloying and spark plasma sintering. Here, we describe the fabrication of a p-type thermoelectric material, copper selenide (Cu 2 Se), utilizing solution-processing and thermal annealing to produce a thin film that achieves a figure of merit, ZT, which is as high as its traditionally processed counterpart, a value of 0.14 at room temperature. This is the first report of a fully solution-processed nanomaterial achieving performance equivalent to its bulk form and represents a general strategy to reduce the energy required to manufacture advanced energy conversion and harvesting materials.},
doi = {10.1038/s41598-017-02944-1},
journal = {Scientific Reports},
number = 1,
volume = 7,
place = {United States},
year = {2017},
month = {6}
}

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