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Title: An Operando Investigation of (Ni–Fe–Co–Ce)O x System as Highly Efficient Electrocatalyst for Oxygen Evolution Reaction

The oxygen evolution reaction (OER) is a critical component of industrial processes such as electrowinning of metals and the chlor-alkali process. It also plays a central role in the development of a renewable energy field for generation a solar fuels by providing both the protons and electrons needed to generate fuels such as H 2 or reduced hydrocarbons from CO 2. To improve these processes, it is necessary to expand the fundamental understanding of catalytically active species at low overpotential, which will further the development of electrocatalysts with high activity and durability. In this context, performing experimental investigations of the electrocatalysts under realistic working regimes (i.e., under operando conditions) is of crucial importance. In this paper, we study a highly active quinary transition-metal-oxide-based OER electrocatalyst by means of operando ambient-pressure X-ray photoelectron spectroscopy and X-ray absorption spectroscopy performed at the solid/liquid interface. We observe that the catalyst undergoes a clear chemical-structural evolution as a function of the applied potential with Ni, Fe, and Co oxyhydroxides comprising the active catalytic species. Finally, while CeO 2 is redox inactive under catalytic conditions, its influence on the redox processes of the transition metals boosts the catalytic activity at low overpotentials, introducing an importantmore » design principle for the optimization of electrocatalysts and tailoring of high-performance materials.« less
Authors:
 [1] ;  [1] ;  [1] ; ORCiD logo [2] ;  [1] ;  [2] ; ORCiD logo [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. California Inst. of Technology (CalTech), Pasadena, CA (United States)
Publication Date:
Grant/Contract Number:
AC02-05CH11231; AC02-76SF00515; SC0004993
Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; ambient pressure; catalytic conditions; electron spectroscopies; operando techniques; oxygen evolution reaction (OER); synchrotron radiation; transiton metal oxides
OSTI Identifier:
1379720

Favaro, Marco, Drisdell, Walter S., Marcus, Matthew A., Gregoire, John M., Crumlin, Ethan J., Haber, Joel A., and Yano, Junko. An Operando Investigation of (Ni–Fe–Co–Ce)Ox System as Highly Efficient Electrocatalyst for Oxygen Evolution Reaction. United States: N. p., Web. doi:10.1021/acscatal.6b03126.
Favaro, Marco, Drisdell, Walter S., Marcus, Matthew A., Gregoire, John M., Crumlin, Ethan J., Haber, Joel A., & Yano, Junko. An Operando Investigation of (Ni–Fe–Co–Ce)Ox System as Highly Efficient Electrocatalyst for Oxygen Evolution Reaction. United States. doi:10.1021/acscatal.6b03126.
Favaro, Marco, Drisdell, Walter S., Marcus, Matthew A., Gregoire, John M., Crumlin, Ethan J., Haber, Joel A., and Yano, Junko. 2016. "An Operando Investigation of (Ni–Fe–Co–Ce)Ox System as Highly Efficient Electrocatalyst for Oxygen Evolution Reaction". United States. doi:10.1021/acscatal.6b03126. https://www.osti.gov/servlets/purl/1379720.
@article{osti_1379720,
title = {An Operando Investigation of (Ni–Fe–Co–Ce)Ox System as Highly Efficient Electrocatalyst for Oxygen Evolution Reaction},
author = {Favaro, Marco and Drisdell, Walter S. and Marcus, Matthew A. and Gregoire, John M. and Crumlin, Ethan J. and Haber, Joel A. and Yano, Junko},
abstractNote = {The oxygen evolution reaction (OER) is a critical component of industrial processes such as electrowinning of metals and the chlor-alkali process. It also plays a central role in the development of a renewable energy field for generation a solar fuels by providing both the protons and electrons needed to generate fuels such as H2 or reduced hydrocarbons from CO2. To improve these processes, it is necessary to expand the fundamental understanding of catalytically active species at low overpotential, which will further the development of electrocatalysts with high activity and durability. In this context, performing experimental investigations of the electrocatalysts under realistic working regimes (i.e., under operando conditions) is of crucial importance. In this paper, we study a highly active quinary transition-metal-oxide-based OER electrocatalyst by means of operando ambient-pressure X-ray photoelectron spectroscopy and X-ray absorption spectroscopy performed at the solid/liquid interface. We observe that the catalyst undergoes a clear chemical-structural evolution as a function of the applied potential with Ni, Fe, and Co oxyhydroxides comprising the active catalytic species. Finally, while CeO2 is redox inactive under catalytic conditions, its influence on the redox processes of the transition metals boosts the catalytic activity at low overpotentials, introducing an important design principle for the optimization of electrocatalysts and tailoring of high-performance materials.},
doi = {10.1021/acscatal.6b03126},
journal = {ACS Catalysis},
number = 2,
volume = 7,
place = {United States},
year = {2016},
month = {12}
}