High pressure polymorphs and amorphization of upconversion host material NaY(WO4)2
Abstract
The pressure effect on the structural change of upconversion host material NaY(WO4)2 was studied in this paper by using in-situ synchrotron X-ray diffraction. A transition from the initial scheelite phase to the M-fergusonite phase occurs near 10 GPa, and another phase transition is found near 27.5 GPa, which could be an isostructural transition without symmetry change. The sample becomes amorphous when the pressure is fully released from high pressure. Finally, this work demonstrates the possibility of synthesizing various polymorph structures for non-linear optical applications with a high pressure, chemical doping, or strained thin-film nanostructure process.
- Authors:
-
- Center for High Pressure Science and Technology Advanced Research, Shanghai (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of Wollongong, NSW (Australia)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
- Center for High Pressure Science and Technology Advanced Research, Shanghai (China); Carnegie Inst. of Washington, Washington, DC (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE; National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1379527
- Grant/Contract Number:
- AC02-05CH11231; U1530402
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 109; Journal Issue: 4; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; High pressure; Crystal structure; X-ray diffraction; Phase transitions; Laser materials
Citation Formats
Hong, Fang, Yue, Binbin, Cheng, Zhenxiang, Kunz, Martin, Chen, Bin, and Mao, Ho-Kwang. High pressure polymorphs and amorphization of upconversion host material NaY(WO4)2. United States: N. p., 2016.
Web. doi:10.1063/1.4960104.
Hong, Fang, Yue, Binbin, Cheng, Zhenxiang, Kunz, Martin, Chen, Bin, & Mao, Ho-Kwang. High pressure polymorphs and amorphization of upconversion host material NaY(WO4)2. United States. https://doi.org/10.1063/1.4960104
Hong, Fang, Yue, Binbin, Cheng, Zhenxiang, Kunz, Martin, Chen, Bin, and Mao, Ho-Kwang. Fri .
"High pressure polymorphs and amorphization of upconversion host material NaY(WO4)2". United States. https://doi.org/10.1063/1.4960104. https://www.osti.gov/servlets/purl/1379527.
@article{osti_1379527,
title = {High pressure polymorphs and amorphization of upconversion host material NaY(WO4)2},
author = {Hong, Fang and Yue, Binbin and Cheng, Zhenxiang and Kunz, Martin and Chen, Bin and Mao, Ho-Kwang},
abstractNote = {The pressure effect on the structural change of upconversion host material NaY(WO4)2 was studied in this paper by using in-situ synchrotron X-ray diffraction. A transition from the initial scheelite phase to the M-fergusonite phase occurs near 10 GPa, and another phase transition is found near 27.5 GPa, which could be an isostructural transition without symmetry change. The sample becomes amorphous when the pressure is fully released from high pressure. Finally, this work demonstrates the possibility of synthesizing various polymorph structures for non-linear optical applications with a high pressure, chemical doping, or strained thin-film nanostructure process.},
doi = {10.1063/1.4960104},
journal = {Applied Physics Letters},
number = 4,
volume = 109,
place = {United States},
year = {Fri Jul 29 00:00:00 EDT 2016},
month = {Fri Jul 29 00:00:00 EDT 2016}
}
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